Hostname: page-component-586b7cd67f-tf8b9 Total loading time: 0 Render date: 2024-11-26T00:51:29.461Z Has data issue: false hasContentIssue false
  • English
  • Français

Theoretical analysis of ozone generation by pulsed dielectric barrier discharge in oxygen

Published online by Cambridge University Press:  01 August 2007

L. S. WEI ,
J. H. ZHOU ,
Z. H. WANG  and
K. F. CEN
L. S. WEI
Affiliation:
State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou, 310027, People's Republic of China
J. H. ZHOU
Affiliation:
State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou, 310027, People's Republic of China
Z. H. WANG
Affiliation:
State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou, 310027, People's Republic of China
K. F. CEN
Affiliation:
State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou, 310027, People's Republic of China
Get access Rights & Permissions [Opens in a new window]

Abstract

The use of very short high-voltage pulses combined with a dielectric layer results in high-energy electrons that dissociate oxygen molecules into atoms, which are a prerequisite for the subsequent production of ozone by collisions with oxygen molecules and third particles. The production of ozone depends on both the electrical and the physical parameters. For ozone generation by pulsed dielectric barrier discharge in oxygen, a mathematical model, which describes the relation between ozone concentration and these parameters that are of importance in its design, is developed according to dimensional analysis theory. A formula considering the ozone destruction factor is derived for predicting the characteristics of the ozone generation, within the range of the corona inception voltage to the gap breakdown voltage. The trend showing the dependence of the concentration of ozone in oxygen on these parameters generally agrees with the experimental results, thus confirming the validity of the mathematical model.

Type
Papers
Information
Journal of Plasma Physics , Volume 73 , Issue 4 , August 2007 , pp. 427 - 432
Copyright
Copyright © Cambridge University Press 2006

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

[1]Chang, J. S., Lawless, P. A. and Yamamoto, T. 1991 Corona discharge processes. IEEE Trans. on Plasma. Sci. 19 (6), 1152.CrossRefGoogle Scholar
[2]Samaranayake, W. J. W., Hackam, R. and Akiyama, H. 2003 Ozone synthesis in a cylindrical dry air-fed ozonizer by nonthermal gas discharges. In: Proc. 7th Int. Conf. on Properties and Application of Dielectric Materials, Nagoya. 2, 547–550.Google Scholar
[3]Ryo, O. and Tetsuji, O. 2003 Formation and structure of primary and secondary streamers in positive pulsed corona discharge—effect of oxygen concentration and applied voltage. J. Phys. D: Appl. Phys. 36, 1952–1958.Google Scholar
[4]Milan, S. and Martin, C. 2002 Efficiency of ozone production by pulsed positive corona discharge in synthetic air. J. Phys. D: Appl. Phys. 35, 1171–1175.Google Scholar
[5]Ma, H. B. and Qiu, Y. C. 2003 A study of ozone synthesis in coaxial cylinder pulsed streamer corona discharge reactors. Ozone Sci. Eng. 25, 127–135.Google Scholar
[6]Chalmers, I. D., Zanella, L. and MacGregor, S. J. 1995 Ozone synthesis in oxygen in a dielectric barrier free configuration. IEEE Int. Pulsed Power Conf., Albuquerque, 2, 1249–1254.Google Scholar
[7]Samaranayake, W. J. W., Namihira, T. and Katsuki, S. 2001 Pulsed power production of ozone using nonthermal gas discharges. IEEE Trans. Electr. Insul. Mag. 17 (4), 17–25.Google Scholar
[8]Samaranayake, W. J. W. et al. 2000 Ozone production using pulsed dielectric barrier discharge in oxygen. IEEE Trans. Dielectr. Electr. Insul. 7 (6), 849–854.CrossRefGoogle Scholar
[9]Buntat, Z., Harry, J. E. and Smith, I. R. 2003 Application of dimensional analysis to ozone production by pulsed streamer discharge in oxygen. J. Phys. D: Appl. Phys. 36, 1553–1557.Google Scholar
[10]Langhaar, H. L. 1951 Dimensional Analysis and Theory of Models. New York: Wiley.Google Scholar
[11]Szirtes, T. 1997 Applied Dimensional Analysis and Modeling. New York: McGraw-Hill.Google Scholar
[12]Yehia, A., Abdel-Salam, M. and Mizuno, A. 2000 On assessment of ozone generation in dc coronas. J. Phys. D: Appl. Phys. 33, 831–835.Google Scholar