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Effect of Carbon Nanotubes’ Diameter on Freeze-Thaw Resistance of Cement Paste

Published online by Cambridge University Press:  30 April 2020

Wei Tian  and
Fangfang Gao Open the ORCID record for Fangfang Gao [Opens in a new window]
Wei Tian
Affiliation:
School of Civil Engineering, Chang’an University, Xi’an, China
Fangfang Gao*
Affiliation:
School of Civil Engineering, Chang’an University, Xi’an, China
*
*Corresponding author ([email protected])
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Abstract

This paper aims to investigate the freeze-thaw resistance of cement-paste containing with different diameter and content of multiwalled carbon nanotubes (MWCNTs) in terms of mechanical properties and microstructure. Three groups of cement-paste with MWCNTs diameter of 10-20 nm, 20-40 nm and 40-60 nm were prepared by incorporating 0.1 wt%, 0.2 wt%, 0.3 wt%, 0.4 wt%, 0.5 wt% MWCNTs by cement weight. Experimental results showed that the addition of 0.1 wt% MWCNTs with diameters of 10–20 nm effectively improved the freeze-thaw resistance of cement-paste. In addition, microstructural analysis of these cement-paste specimens showed that MWCNTs addition increased the materials’ initial porosity, but a proper amount of MWCNTs decreased the porosity of cement-paste after freeze-thaw cycles and effectively improved the pore size distribution. MWCNTs 10–20 nm in diameter were found to be the optimal size for improving the microstructure of these MWCNTs cement-paste

Keywords

MWCNTsMechanical propertiesFreeze-thaw cyclesPore structure
Type
Research Article
Information
Journal of Mechanics , Volume 36 , Issue 4 , August 2020 , pp. 437 - 449
Copyright
Copyright © 2020 The Society of Theoretical and Applied Mechanics

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References

REFERENCES

Xu, S. L. and Cai, X. R., “A review on the development of research and application of ultra high toughness cementitious composites,” China Civil Engineering Journal, 46, pp. 45–60 (2009).Google Scholar
Cao, M. L., Xu, L.and Zhang, C., “Review on Micromechanical Design, Performance and Development Tendency of Engineered Cementitious Composite,”, Journal of the Chinese Ceramic Society, 43, pp. 632–642 (2015).Google Scholar
Jackson, P. R., Ruggles-Wrenn, M. B., Baek, S. S., and Keller, K. A., “Compressive creep behavior of an oxide–oxide ceramic composite with monazite fiber coating at elevated temperatures,” Materials Science and Engineering: A, 454, pp. 590–601 (2007).CrossRefGoogle Scholar
Gao, J., Wang, Z., Zhang, T., and Zhou, L., “Dispersion of carbon fibers in cement-based composites with different mixing methods,” Construction and Building Materials, 134, pp. 220–227 (2017).10.1016/j.conbuildmat.2016.12.047CrossRefGoogle Scholar
Kasagani, H., and Rao, C. B. K., “Effect of graded fibers on stress strain behaviour of Glass Fiber Reinforced Concrete in tension,” Construction and Building Materials, 183, pp. 592–604 (2018).10.1016/j.conbuildmat.2018.06.193CrossRefGoogle Scholar
Guo, X., & Pan, X., “Mechanical properties and mechanisms of fiber reinforced fly ash–steel slag based geopolymer mortar,” Construction and Building Materials, 179, pp. 633–641 (2018).10.1016/j.conbuildmat.2018.05.198CrossRefGoogle Scholar
Zhu, Miaomiao, and Jianxun, Ma., “Basalt fiber modified with lanthanum-ethylenediaminetetraacetic acid as potential reinforcement of cyanate matrix composites,” Applied Surface Science, 464, pp. 636–643(2019).10.1016/j.apsusc.2018.09.129CrossRefGoogle Scholar
Liu, X., Chen, L., Liu, A., and Wang, X., “Effect of nano-CaCO3 on properties of cement-paste,” Energy Procedia, 16, pp. 991–996 (2012).10.1016/j.egypro.2012.01.158CrossRefGoogle Scholar
Li, G. S., Gao, G.Zhu, J. P., and Feng, C. H., “Research progress of nano material in cement based material,” New Chemical Material, 46, pp. 15–19 (2018).Google Scholar
Moore, V. C., Strano, M. S., Haroz, E. H., Hauge, R. H., Smalley, R. E., Schmidt, J., and Talmon, Y., “Individually suspended single-walled carbon nanotubes in various surfactants,” Nano letters, 3, pp. 1379–1382 (2003).CrossRefGoogle Scholar
Xie, X. L., Mai, Y. W., and Zhou, X. P., “Dispersion and alignment of carbon nanotubes in polymer matrix: a review,” Materials science and engineering: R: Reports, 49, pp. 89–112 (2005).10.1016/j.mser.2005.04.002CrossRefGoogle Scholar
Luo, J. L., and Duan, Z. D., “Mechanical and stress-sensitive properties of multi-walled carbon nanotubes reinforced cement matrix composites,” World Forum on Smart Materials and Smart Structures Technology, 5, pp. 22–26 (2007).Google Scholar
Li, G. Y., Wang, P. M., and Zhao, X., “Pressure-sensitive properties and microstructure of carbon nanotube reinforced cement composites,” Cement and Concrete Composites, 29, pp. 377–382 (2007).10.1016/j.cemconcomp.2006.12.011CrossRefGoogle Scholar
Makar, J. M., and Chan, G. W., “Growth of cement hydration products on single-walled carbon nanotubes,” Journal of the American Ceramic Society, 92, pp. 1303–1310 (2009).10.1111/j.1551-2916.2009.03055.xCrossRefGoogle Scholar
Tyson, B. M., Abu Al-Rub, R. K., Yazdanbakhsh, A., and Grasley, Z., “Carbon nanotubes and carbon nanofibers for enhancing the mechanical properties of nanocomposite cementitious materials,” Journal of Materials in Civil Engineering, 23, pp. 1028–1035 (2011).10.1061/(ASCE)MT.1943-5533.0000266CrossRefGoogle Scholar
Azhari, F., & Banthia, N., “Cement-based sensors with carbon fibers and carbon nanotubes for piezoresistive sensing,” Cement and Concrete Composites, 34, pp. 866–873 (2012).10.1016/j.cemconcomp.2012.04.007CrossRefGoogle Scholar
Cao, M., Zhang, C., and Wei, J., “Microscopic reinforcement for cement based composite materials,” Construction and Building Materials, 40, pp. 14–25 (2013).CrossRefGoogle Scholar
Wang, B., Han, Y., and Liu, S., “Effect of highly dispersed carbon nanotubes on the flexural toughness of cement-based composites,” Construction and Building Materials, 46, pp. 8–12 (2013).10.1016/j.conbuildmat.2013.04.014CrossRefGoogle Scholar
Hu, Y., Luo, D., Li, P., Li, Q., and Sun, G., “Fracture toughness enhancement of cement paste with multi-walled carbon nanotubes,” Construction and Building Materials, 70, pp. 332–338 (2014).10.1016/j.conbuildmat.2014.07.077CrossRefGoogle Scholar
Cui, H., Yang, S., and Memon, S., “Development of carbon nanotube modified cement paste with microencapsulated phase-change material for structural–functional integrated application,” International journal of molecular sciences, 16, pp. 8027–8039 (2015).10.3390/ijms16048027CrossRefGoogle Scholar
Al-Saleh, M. H., “Clay/carbon nanotube hybrid mixture to reduce the electrical percolation threshold of polymer nanocomposites,” Composites Science and Technology, 149, pp. 34–40 (2017).CrossRefGoogle Scholar
Carriço, A., Bogas, J. A., Hawreen, A., and Guedes, M., “Durability of multi-walled carbon nanotube reinforced concrete,” Construction and Building Materials, 164, pp. 121–133 (2018).10.1016/j.conbuildmat.2017.12.221CrossRefGoogle Scholar
Wang, B. M., Liu, S., Han, Y., and Leng, P., “Preparation and durability of cement-based composites doped with multi-walled carbon nanotubes,” Nanoscience and Nanotechnology Letters, 7, pp. 411–416 (2015).10.1166/nnl.2015.1979CrossRefGoogle Scholar
Yu, H. S., and He, J. B., “Fracture toughness and durability performance of highly dispersed multiwalled carbon nanotubes reinforced cement-based composites,” Journal of Advanced Microscopy Research, 10, pp. 14–19 (2015).10.1166/jamr.2015.1230CrossRefGoogle Scholar
Sun, G. L. Morphological., “Mechanical and Durability Properties of Cement Mortar Reinforced with Multi-Walled Carbon Nanotubes,” Journal of Advanced Microscopy Research, 10, pp. 60–64 (2015).CrossRefGoogle Scholar
Amin, M. S., El-Gamal, S. M. A., and Hashem, F. S., “Fire resistance and mechanical properties of carbon nanotubes-clay bricks wastes (Homra) composites cement,” Construction and Building Materials, 98, pp. 237–249 (2015).10.1016/j.conbuildmat.2015.08.074CrossRefGoogle Scholar
Wang, Z., Zeng, Q., Wang, L., Yao, Y., and Li, K., “Characterizing blended cement pastes under cyclic freeze-thaw actions by electrical resistivity,” Construction and Building Materials, 44, pp. 477–486 (2013).CrossRefGoogle Scholar
Wang, Z., Zeng, Q., Wang, L., Yao, Y., and Li, K., “Effect of moisture content on freeze-thaw behavior of cement paste by electrical resistance measurements,” Journal of materials science, 49, pp. 4305–4314 (2014).10.1007/s10853-014-8126-2CrossRefGoogle Scholar
Zeng, Q., Li, L., Pang, X., Gui, Q., and Li, K., “Freeze-thaw behavior of air entrained cement paste saturated with 10 wt.% NaCl solution,” Cold Regions Science and Technology, 102, pp. 21–31 (2014).10.1016/j.coldregions.2014.02.003CrossRefGoogle Scholar
Jamshidi, R. J., Lake, C. B., and Barnes, C. L., “Examining freeze/thaw cycling and its impact on the hydraulic performance of cement-treated silty sand,” Journal of Cold Regions Engineering, 29, pp. 04014014 (2014).CrossRefGoogle Scholar
Yalçınkaya , Ç., “Effect of early-age freezing-thawing exposure on the mechanical performance of self-compacting repair mortars,” Science and Engineering of Composite Materials, 23, pp. 335–344 (2016).CrossRefGoogle Scholar
Isfahani, F. T., Li, W., and Redaelli, E., “Dispersion of multi-walled carbon nanotubes and its effects on the properties of cement composites,” Cement and Concrete Composites, 74, pp. 154–163 (2016).CrossRefGoogle Scholar
Li, W. W., Ji, W. M., Wang, Y. C., Liu, Y., Shen, R. X., and Xing, F., “Investigation on the mechanical properties of a cement-based material containing carbon nanotube under drying and freeze-thaw conditions,” Materials, 8, pp. 8780–8792 (2015).10.3390/ma8125491CrossRefGoogle Scholar
Parveen, S., Rana, S., Fangueiro, R., and Paiva, M. C., “Microstructure and mechanical properties of carbon nanotube reinforced cementitious composites developed using a novel dispersion technique,” Cement and Concrete Research, 73, pp. 215–227 (2015).CrossRefGoogle Scholar
Wu, Z., “An approach to the recent trends of concrete science and technology,” Journal of the Chinese Ceramic Society, 7, pp. 262–270 (1979).Google Scholar
Liu, Q., Sun, W., Jiang, H., and Wang, C., “Effects of carbon nanotubes on mechanical and 2D-3D microstructure properties of cement mortar,” Journal of Wuhan University of Technology-Mater Sci Ed, 29, pp. 513–517 (2014).CrossRefGoogle Scholar
Sobolkina, A., Mechtcherine, V., Khavrus, V., Maier, D., Mende, M., Ritschel, M., and Leonhardt, A., “Dispersion of carbon nanotubes and its influence on the mechanical properties of the cement matrix,” Cement and Concrete Composites, 34, pp. 1104–1113 (2012).CrossRefGoogle Scholar