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Ultrahigh strength Al-based amorphous alloys containing Sc

Published online by Cambridge University Press:  03 March 2011

Akihisa Inoue
Affiliation:
Institute for Materials Research, Tohoku University, Katahira 2-1-1, Aoba-Ku,Sendai 980-8577, Japan
Shintaro Sobu
Affiliation:
Institute for Materials Research, Tohoku University, Katahira 2-1-1, Aoba-Ku,Sendai 980-8577, Japan
Dmitri V. Louzguine*
Affiliation:
Institute for Materials Research, Tohoku University, Katahira 2-1-1, Aoba-Ku,Sendai 980-8577, Japan
Hisamichi Kimura
Affiliation:
Institute for Materials Research, Tohoku University, Katahira 2-1-1, Aoba-Ku,Sendai 980-8577, Japan
Kenichiro Sasamori
Affiliation:
Institute for Materials Research, Tohoku University, Katahira 2-1-1, Aoba-Ku,Sendai 980-8577, Japan
*
a)Address all correspondence to this author. e-mail: [email protected]Family name can also be spelled Luzgin
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Abstract

Amorphous metallic alloys possess high strength characteristics, which are superior to crystalline materials. Here we report an influence of Sc addition on glass-forming ability, glass-transition behavior, supercooled liquid region, and mechanical properties of an Al84Y9Ni5Co2 glassy alloy. This paper also aims to present a promising (Al0.84Y0.09Ni0.05Co0.02)95Sc5 amorphous alloy. This alloy has an ultrahigh tensile fracture strength exceeding 1500 MPa, which surpasses those for all the other Al-based fully crystalline and amorphous alloys reported to date, in addition to high Young’s modulus of 78 GPa. The fracture surface of this new alloy exhibited vein pattern typical for amorphous alloys with good ductility, and multiple shear bandswere observed on the lateral surface. The ultrahigh tensile strength of the (Al0.84Y0.09Ni0.05Co0.02)95Sc5 amorphous alloy results from an increase in the interatomic constraint force by the addition of Sc, an element having highly negative enthalpy of mixing with Al, Ni, and Co and the highest chemical affinity with Al among the alloying elements.

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Articles
Copyright
Copyright © Materials Research Society 2004

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References

REFERENCES

1Inoue, A., Ohtera, K. and Masumoto, T., New amorphous Al–Y, Al–La and Al–Ce alloys prepared by melt spinning. Jpn. J. Appl. Phys. 27 L736 (1988).CrossRefGoogle Scholar
2Inoue, A., Ohtera, K., Tsai, A.P. and Masumoto, T., New amorphous alloys with good ductility in Al–Y–M and Al–La–M (M=Fe, Co, Ni or Cu) systems. Jpn. J. Appl. Phys. 27, L280 (1988).CrossRefGoogle Scholar
3Inoue, A., Ohtera, K., Kita, K. and Masumoto, T., New amorphous alloys with good ductility in Al–Ce–M (M=Nb, Fe, Co, Ni or Cu) systems. Jpn. J. Appl. Phys. 27 L1796 (1988).CrossRefGoogle Scholar
4He, Y., Poon, S.J. and Shiflet, G.J., Synthesis and properties of metallic glasses that contain aluminum. Science 241, 1640 (1988).CrossRefGoogle ScholarPubMed
5Inoue, A., Ohtera, K., Tsai, A.P. and Masumoto, T., Aluminum-based amorphous alloys with tensile strength above 980 MPa (100 kg/mm2). Jpn. J. Appl. Phys. 27,L479 (1988).CrossRefGoogle Scholar
6Shiflet, G.J., He, Y. and Poon, S.J., Mechanical properties of a new class of metallic glasses based on aluminum. J. Appl. Phys. 64, 6863 (1988).CrossRefGoogle Scholar
7Kim, Y-H., Inoue, A. and Masumoto, T., Ultrahigh mechanical strengths of Al88Y2Ni10–xMx (M=Mn, Fe, Co) amorphous alloys containing nanoscale fcc–Al particles. Mater. Trans. JIM 32, 599 (1991).CrossRefGoogle Scholar
8Louzguine, D.V. and Inoue, A., Strong influence of supercooled liquid on crystallization of the Al85Ni5Y4Nd4Co2 metallic glass. Appl. Phys. Lett. 78, 3061 (2001).CrossRefGoogle Scholar
9Louzguine, D.V. and Inoue, A., Full or partial replacement of Y by rare-earth and some other elements in the Al85Y8Ni5Co2 alloy. J. Light Met. 1,105 (2001).Google Scholar
10Louzguine, D.V. and Inoue, A., Crystallization behaviour of Al-based metallic glasses below and above the glass-transition temperature. J. Non-Cryst. Solids 311,281 (2002).CrossRefGoogle Scholar
11Pauling, L. in The Nature of the Chemical Bond, 3rd ed. (Cornell University, Ithaca, NY, 1960), pp. 8190Google Scholar
12Louzguine, D.V. and Inoue, A., Electronegativity of the constituent rare-earth metals as a factor stabilizing the supercooled liquid region in Al-based metallic glasses. Appl. Phys. Lett. 79, 3410 (2001).Google Scholar
13Inoue, A. and Kimura, H., Fabrications and mechanical properties of bulk amorphous, nanocrystalline, nanoquasicrystalline alloys in aluminum-based system. J. Light Met. 1, 31 (2001).CrossRefGoogle Scholar
14Inoue, A., Stabilization of metallic supercooled liquid and bulk amorphous alloys. Acta Mater . 48,279 (2000).CrossRefGoogle Scholar
15De Boer, F.R., Boom, R., Mattens, W.C.M., Miedema, A.R. and Niessen, A.K. in Cohesion in Metals (Elsevier Science Publishers, North-Holland, The Netherlands, 1988), pp. 3135Google Scholar
16Takeuchi, A. and Inoue, A., Calculations of mixing enthalpy and mismatch entropy for ternary amorphous alloys. Mater. Trans. JIM 41, 1372 (2000).Google Scholar
17James, A.M. and Lord, M.P. in Macmillan’s Chemical and Physical Data, 1020 (Macmillan’s, London, U.K., 1992), pp. 5560Google Scholar
18Greer, A.L., Partially or fully devitrified alloys for mechanical properties. Mater. Sci. Eng. A 304–306, 68 (2001).CrossRefGoogle Scholar
19Perepezko, J.H., Hebert, R.J. and Tong, W.S., Amorphous and nanostructure synthesis in Al alloys. Intermetallics 10,1079 (2002).CrossRefGoogle Scholar
20Zhang, Z.F., Eckert, J. and Schultz, L., Difference in compressive and tensile fracture mechanisms of Zr59Cu20Al10Ni8Ti3 bulk metallic glass. Acta Metall. 51, 1167 (2003).Google Scholar
21Beaudry, B.J. and Daane, A.H., The scandium-yttrium and scandium-zirconium system. Trans. Metall. Soc. AIME 227, 865 (1963).Google Scholar
22Hong, S.J., Warren, P.J. and Chun, B.S., Nanocrystallization behaviour of Al–Y–Ni with Cu additions. Mater. Sci. Eng. A 304– 306, 362 (2001).Google Scholar
23Louzguine, D.V. and Inoue, A., Investigation of structure and properties of the Al–Y–Ni–Co–Cu metallic glasses. J. Mater. Res. 17, 1014 (2002).CrossRefGoogle Scholar