Hostname: page-component-78c5997874-j824f Total loading time: 0 Render date: 2024-11-19T02:16:28.777Z Has data issue: false hasContentIssue false
  • English
  • Français

Two-step preparation of AlON transparent ceramics with powder synthesized by aluminothermic reduction and nitridation method

Published online by Cambridge University Press:  12 September 2014

Ying Wang ,
Xiumin Xie ,
Jianqi Qi ,
Jun Wang ,
Di Wu ,
Xiaofeng Guo ,
Nian Wei  and
Tiecheng Lu
Ying Wang
Affiliation:
College of Physical Science and Technology, Sichuan University, Chengdu 610064, Sichuan, People's Republic of China; and Key Laboratory of High Energy Density Physics of Ministry of Education, Sichuan University, Chengdu 610064, Sichuan, People's Republic of China
Xiumin Xie
Affiliation:
College of Physical Science and Technology, Sichuan University, Chengdu 610064, Sichuan, People's Republic of China; and Key Laboratory of Radiation Physics and Technology of Ministry of Education, Sichuan University, Chengdu 610064, Sichuan, People's Republic of China
Jianqi Qi*
Affiliation:
College of Physical Science and Technology, Sichuan University, Chengdu 610064, Sichuan, People's Republic of China; and Key Laboratory of High Energy Density Physics of Ministry of Education, Sichuan University, Chengdu 610064, Sichuan, People's Republic of China
Jun Wang
Affiliation:
School of Science, Sichuan University of Science and Engineering, Zigong 643000, Sichuan, People's Republic of China
Di Wu
Affiliation:
Peter A. Rock Thermochemistry Laboratory and NEAT ORU, University of California, Davis, California 95616, USA
Xiaofeng Guo
Affiliation:
Peter A. Rock Thermochemistry Laboratory and NEAT ORU, University of California, Davis, California 95616, USA
Nian Wei
Affiliation:
College of Physical Science and Technology, Sichuan University, Chengdu 610064, Sichuan, People's Republic of China; and Key Laboratory of High Energy Density Physics of Ministry of Education, Sichuan University, Chengdu 610064, Sichuan, People's Republic of China
Tiecheng Lu*
Affiliation:
College of Physical Science and Technology, Sichuan University, Chengdu 610064, Sichuan, People's Republic of China; and International Center for Material Physics, Chinese Academy of Sciences, Shenyang 110015, Liaoning, People's Republic of China
*
a)Address all correspondence to these authors. e-mail: [email protected]
b)e-mail: [email protected]
Get access

Abstract

The aluminothermic reduction and nitridation method using microsized Al powder and nanosized alumina powder was employed to fabricate AlON powder under N2 atmosphere. Single-phase aluminum oxynitride (AlON) can be prepared at a relatively low temperature (1700 °C) with a holding time of 3 h. The powder is ball milled, doped with different amounts of Y2O3 (0.1–0.9 wt%) as a sintering additive, and then shaped into pellets. The pellet sintering is carried out at two relatively low temperatures (1860 and 1880 °C) for 10 h. The transmittance and hardness of the obtained samples varies as the amount of Y2O3 varies. The sample sintered under optimal conditions can reach an ultimate transmittance of 65% with 2 mm thickness. The Vickers hardness of highly transparent AlON ceramic is about 15.95 ± 0.17 GPa, indicating that our method has a promising future in transparent AlON ceramic production. The sintering promoting mechanisms of Y2O3 are also discussed in detail.

Keywords

AlON single-phase powderaluminothermic reduction and nitridation methodY2O3 sintering additive
Type
Articles
Information
Journal of Materials Research , Volume 29 , Issue 19: Focus Issue: Optical Ceramics Science , 14 October 2014 , pp. 2325 - 2331
Copyright
Copyright © Materials Research Society 2014 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

McCauley, J.W.: A simple model for aluminum oxynitride spinels. J. Am. Ceram. Soc. 61, 372 (1978).Google Scholar
Corbin, N.D.: Aluminum oxynitride spinel: A review. J. Eur. Ceram. Soc. 5, 143 (1989).Google Scholar
Boey, F.Y.C., Song, X.L., Gu, Z., and Tok, A.I.Y.: AlON phase formation in a tape-cast Al2O3/AlN composite. J. Mater. Process. Technol. 90, 478 (1999).Google Scholar
Bachelard, R., Disson, J., and Morlhon, B.: Optically transparent gamma-aluminum oxynitride powders and ceramic articles shaped therefrom. US Patent 5688730, 1997.Google Scholar
McCauley, J.W., Patel, P., Chen, M.W., Gilde, G., Strassburger, E., Paliwal, B., Ramesh, K.T., and Dandekar, D.P.: AlON: A brief history of its emergence and evolution. J. Eur. Ceram. Soc. 29, 223 (2008).CrossRefGoogle Scholar
Willems, H.X., Hendrix, M.M.R.M., Metselaar, R., and de With, G.: Thermodynamics of Alon I: Stability at lower temperatures. J. Eur. Ceram. Soc. 10, 327 (1992).Google Scholar
Bandyopadhyay, S., Rixecker, G., Aldinger, F., Pal, S., Mukherjee, K., and Maiti, H.S.: Effect of reaction parameters on γ-AlON formation from Al2O3 and AlN. J. Am. Ceram. Soc. 85, 1010 (2002).CrossRefGoogle Scholar
Wang, Y.Z., Lu, T.C., Gong, L., Qi, J.Q., Wen, J.S., Yu, J., Pan, L., Yu, Y., and Wei, N.: Light extinction by pores in AlON ceramics: The transmission properties. J. Phys. D: Appl. Phys. 43, 275403 (2010).CrossRefGoogle Scholar
Zheng, J. and Forslund, B.: Carbothermal synthesis of aluminum oxynitride(ALON) powder: Influence of starting materials and synthesis parameters. J. Eur. Ceram. Soc. 15, 1087 (1995).Google Scholar
Ish-Shalom, M.: Formation of aluminium oxynitride by carbothermal reduction of aluminium oxide in nitrogen. J. Mater. Sci. Lett. 1, 147 (1982).Google Scholar
Li, Y., Li, N., and Yuan, R.: Effect of raw materials on carbothermal reduction synthesis of γ-aluminum oxynitride spinel powder. J. Mater. Sci. 34, 2547 (1999).Google Scholar
Wang, Y.Z., Lu, T.C., Yu, Y., Qi, J.Q., Wen, J.S., Wang, H.P., Xiao, L., Yang, Z.L., Yu, J., Wen, Y., and Wei, N.: Synthesis of AlON powder by aluminothermic reduction and nitridation reaction and its thermodynamic analysis. Rare Met. Mater. Eng. 38, S48 (2009).Google Scholar
Fukuyama, H., Nakao, W., Susa, M., and Nagata, K.: New synthetic method of forming aluminum oxynitride by plasma arc melting. J. Am. Ceram. Soc. 82, 1381 (1999).Google Scholar
Kikkawa, S., Hatta, N., and Takeda, T.: Preparation of aluminum oxynitride by nitridation of a precursor derived from aluminum-glycine gel and the effects of the presence of europium. J. Am. Ceram. Soc. 91, 924 (2008).Google Scholar
Miao, W.: Method for manufacturing aluminum oxynitride (AlON) powder and other nitrogen-containing powders. US Patent 6955798, 2005.Google Scholar
Zientara, D., Bucko, M., and Lis, J.: Alon-based materials prepared by SHS technique. J. Eur. Ceram. Soc. 27, 775 (2007).Google Scholar
Gromov, A., Ilyin, A., Ditts, A., and Vereshchagin, V.: Combustion of Al-Al2O3 mixtures in air. J. Eur. Ceram. Soc. 25, 1575 (2005).Google Scholar
Lee, J., Lee, I., Chung, H., Ahn, J., Kim, D., and Kim, B.: Self-propagating high-temperature synthesis for aluminum oxynitride (AlON). Mater. Sci. Forum 510–511, 662 (2006).Google Scholar
The software is copyrighted for Xu at Chemistry Department, Fudan University, China.Google Scholar
Clay, D., Poslusny, D., Flinders, M., Jacobs, S.D., and Cutler, R.A.: Effect of LiAl5O8 additions on the sintering and optical transparency of LiAlON. J. Eur. Ceram. Soc. 26, 1351 (2006).Google Scholar
Lee, J.H., Koo, B.K., Koo, K.H., and Lee, K.R.: Method for manufacturing transparent polycrystalline aluminum oxynitride. International Patent WO2008047955-A1, 2008.Google Scholar
Takahashi, H., Sato, T., Ito, S., and Akashi, K.: Reaction plasma sintering of aluminum oxynitride ceramics. J. Ceram. Soc. Jpn. 104, 614 (1996).CrossRefGoogle Scholar
Hartnett, T. and Wahl, J.: Method of making aluminum oxynitride and aluminum oxynitride prepared by the method. International Patent WO02/06156–A1, 2002.Google Scholar
Medraj, M., Baik, Y., Thompson, W.T., and Drew, R.A.L.: Understanding AlN sintering through computational thermodynamics combined with experimental investigation. J. Mater. Process Technol. 161, 415 (2005).Google Scholar
Kim, N.H., Fun, Q.D., Komeya, K., and Meguro, T., Phase reaction and sintering behavior in the pseudoternary system AlN-Y2O3-Al2O3. J. Am. Ceram. Soc. 79, 2645 (1996).CrossRefGoogle Scholar
Boey, F., Cao, L., Khor, K.A., and Tok, A.: Phase reaction and sintering behavior of a Al2O3-20wt%AlN-5wt%Y2O3 system. Acta Mater. 49, 3117 (2001).Google Scholar
Alper, A.: Phase Diagrams in Advanced Ceramics (Academic Press, New York, 1995).Google Scholar
Dong, W., Jain, H., and Harmer, M.P.: Liquid phase sintering of alumina, II. Penetration of liquid phase into model microstructures. J. Am. Ceram. Soc. 88, 1708 (2005).Google Scholar
Kim, S. and Park, Y.: Grain boundary segregation, solute drag and abnormal grain growth. Acta Mater. 56, 3739 (2008).CrossRefGoogle Scholar
Miller, L. and Kaplan, W.: Solubility limits of La and Y in aluminum oxynitride at 1870 °C. J. Am. Ceram. Soc. 91, 1693 (2008).Google Scholar
Lei, F.B., Wang, Z.S., and Zhao, B.G.: Preparation and mechanism of nanometer Al5O6N via shock wave plasma technique. Mater. Res. Bull. 44, 198 (2009).CrossRefGoogle Scholar