Hostname: page-component-586b7cd67f-dlnhk Total loading time: 0 Render date: 2024-11-26T23:10:37.642Z Has data issue: false hasContentIssue false

Thermodynamic modeling and experimental study on the microstructure of laser clad Ni–base alloy coatings on 45 steel

Published online by Cambridge University Press:  12 April 2013

Yiwen Lei*
Affiliation:
Department of Materials Engineering, School of Mechanical Engineering, Tianjin Polytechnic University, Tianjin 300387, China; and Tianjin Key Laboratory of Advanced Mechatronics Equipment Technology; Tianjin 300387, China
Ronglu Sun
Affiliation:
Department of Materials Engineering, School of Mechanical Engineering, Tianjin Polytechnic University, Tianjin 300387, China
Ying Tang
Affiliation:
Department of Materials Engineering, School of Mechanical Engineering, Tianjin Polytechnic University, Tianjin 300387, China
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

Ni–base alloy coatings were fabricated on 45 steel by laser cladding using a CW-CO2 laser system. The microstructure of the coatings was analyzed using optical microscope (OM), scanning electronic microscope (SEM), and x-ray diffractometer (XRD). The phase fractions, phase compositions, and solidification process in the coatings were calculated using Thermo-Calc software and compared with experimental results. The results show that a dense crack- and porous-free coating with good metallurgical bond is obtained under optimal process parameters. The coatings can be divided into three regions: clad zone (CZ), bonding zone, and heat-affected zone of the substrate. The CZ consists of γ-Ni, M7C3, CrB, and Ni3B phases. Based on the calculated results, the solidification process and reaction scheme in the coatings were discussed. The calculated results obtained from Thermo-Calc software agree with the experimental data well. It is beneficial to the coating design for a desirable microstructure and mechanical properties.

Type
Articles
Copyright
Copyright © Materials Research Society 2013 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Yan, M. and Zhu, W-Z.: Surface treatment of 45 steel by plasma-arc melting. Surf. Coat. Technol. 91, 183 (1997).CrossRefGoogle Scholar
Yang, S., Chen, N., Liu, W-J., Zhong, M-L., Wang, Z-J., and Kokawa, H.: Fabrication of nickel composite coatings reinforced with TiC particles by laser cladding. Surf. Coat. Technol. 183, 254 (2004).CrossRefGoogle Scholar
Ma, S-L., Li, Y-H., and Xu, K-W.: The composite of nitrided steel of H13 and TiN coatings by plasma duplex treatment and the effect of pre-nitriding. Surf. Coat. Technol. 137, 116 (2001).CrossRefGoogle Scholar
Zlatanovic, M., Gredic, T., Kunosic, A., Backovic, N., and Whittle, N.: Substrate-induced changes of TiN and (Ti, Al)N coatings due to plasma nitriding. Surf. Coat. Technol. 63, 35 (1994).CrossRefGoogle Scholar
Lei, Y-W., Sun, R-L., Lei, J-B., Tang, Y., and Niu, W.: A new theoretical model for high power laser clad TiC/NiCrBSiC composite coatings on Ti6Al4V alloys. Opt. Lasers Eng. 48, 899 (2010).CrossRefGoogle Scholar
Pei, Y-T. and Zuo, T-C.: Gradient microstructure in laser clad TiC-reinforced Ni-alloy composite coating. Mater. Sci. Eng., A 241, 259 (1998).CrossRefGoogle Scholar
Zhang, D-W., Li, T., and Lei, T-C.: Laser cladding of Ni-Cr3C2/(Ni+Cr) composite coating. Surf. Coat. Technol. 110, 81 (1998).Google Scholar
Zhang, D-W., Lei, T-C., and Li, F-J.: Laser cladding of stainless steel with Ni-Cr3C2 for improved wear performance. Wear 251, 1372 (2001).CrossRefGoogle Scholar
Li, Q., Lei, T-C., and Chen, W-Z.: Microstructural characterization of laser-clad TiCp-reinforced Ni-Cr-B-Si-C composite coatings on steel. Surf. Coat. Technol. 114, 278 (1999).CrossRefGoogle Scholar
Tobar, M-J., Álvarez, C., Amado, J-M., Rodríguez, G., and Yáñez, A.: Morphology and characterization of laser clad composite NiCrBSi-WC coatings on stainless steel. Surf. Coat. Technol. 200, 6313 (2006).CrossRefGoogle Scholar
Sun, R-L., Wang, Y-S., Tang, Y., and Yang, X-C.: Microstructure and microhardness of NiCrBSi alloy laser cladding layer on 45 steel substrate. Tianjin Gongye Daxue Xuebao 22, 79 (2003).Google Scholar
Tam, K-F., Cheng, F-T., and Man, H-C.: Cavitation erosion behavior of laser-clad Ni-Cr-Fe-WC on brass. Mater. Res. Bull. 37, 1341 (2002).CrossRefGoogle Scholar
Viswanathan, A., Sastikumar, D., Rajarajan, P., Kumar, H., and Nath, A-K.: Laser irradiation of AISI 316L stainless steel coated with Si3N4 and Ti. Opt. Laser Technol. 39, 1504 (2007).CrossRefGoogle Scholar
Chen, Y. and Wang, H-M.: Growth morphology and mechanism of primary TiC carbide in laser clad TiC/FeAl composite coating. Mater. Lett. 57, 1233 (2003).CrossRefGoogle Scholar
Sundman, B., Jansson, B., and Andersson, J-O.: The thermo-calc databank system. Calphad 9, 153 (1985).CrossRefGoogle Scholar
Hillert, M. and Staffansson, L.I.: Regular solution model for stoi-chiometric phases and ionic. Melts. Acta Chem. Scand. 24, 3618 (1970).CrossRefGoogle Scholar
Hu, S-L., Guo, Y., Dong, Y-G., Yang, J-L., Liu, J., and Cao, S-R.: Understanding the effects of the structures on the energy gaps in carbon nanoparticles from laser synthesis. J. Mater. Chem. 22, 12053 (2012).CrossRefGoogle Scholar
Hu, S-L., Tian, F., Bai, P-K., Cao, S-R., Sun, J., and Yang, J.: Synthesis and luminescence of nanodiamonds from carbon black. Mater. Sci. Eng., B 157, 11 (2009).CrossRefGoogle Scholar