Hostname: page-component-586b7cd67f-2plfb Total loading time: 0 Render date: 2024-11-26T22:20:23.535Z Has data issue: false hasContentIssue false
  • English
  • Français

Temperature-dependent broadband near-infrared luminescence in silicate glass ceramics containing Li2MgSiO4: Cr4+ nanocrystals

Published online by Cambridge University Press:  31 January 2011

Yixi Zhuang ,
Jiajia Zhou ,
Junhua Xie ,
Yu Teng  and
Jianrong Qiu
Jianrong Qiu*
Affiliation:
State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027, People's Republic of China
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

Transparent glass ceramics containing Li2MgSiO4: Cr4+ nanocrystallites were prepared. Intense broadband near-infrared emission with full width at half-maximum larger than 200 nm and long fluorescence lifetime (τ > 100 μs) were observed. The temperature-dependent optical characteristics of the glass ceramics containing Li2MgSiO4: Cr4+ crystallites were compared to those of Li2MgSiO4: Cr4+ single crystals. The reason for extra-long near-infrared fluorescence lifetime was illuminated by the mixed effect between 3T2 and 1E levels. The crystal-filed-induced particular energy-level scheme makes the fluorescence lifetime of the glass ceramics containing Li2MgSiO4: Cr4+ crystallites one order longer than those of other Cr4+-doped glass ceramics.

Keywords

Optical PropertiesInfrared (IR) SpectroscopyCr
Type
Articles
Information
Journal of Materials Research , Volume 25 , Issue 9 , September 2010 , pp. 1833 - 1837
Copyright
Copyright © Materials Research Society 2010

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Ohishi, Y., Kananmori, T., Kitagawa, T., Takahashi, S.Pr3+-doped fluoride fiber amplifier operating at 1.31 μm. Opt. Lett. 16, 1747 (1991)CrossRefGoogle Scholar
2.Mori, A., Ohishi, Y., Sudo, S.Erbium-doped tellurite glass fibre laser and amplifier. Electron. Lett. 33, 863 (1997)CrossRefGoogle Scholar
3.Kück, S.Laser-related spectroscopy of ion-doped crystals for tunable solid-state lasers. Appl. Phys. B: Lasers Opt. 72, 515 (2001)CrossRefGoogle Scholar
4.Pinckney, L.R., Beall, G.H.Transition element-doped crystals in glass. Proc. SPIE 4452, 93 (2001)CrossRefGoogle Scholar
5.Petričević, V., Gayen, S.K., Alfano, R.R.Laser action in chromium-activated forsterite for near-infrared excitation: Is Cr4+ the lasing ion? Appl. Phys. Lett. 53, 2590 (1988)CrossRefGoogle Scholar
6.Lo, C., Huang, K., Chen, J., Tu, S., Huang, S.Glass-clad Cr4+: YAG crystal fiber for the generation of superwideband amplified spontaneous emission. Opt. Lett. 29, 439 (2004)CrossRefGoogle ScholarPubMed
7.Avanesov, A.G., Lebedev, V.A.Room temperature laser action of Y2SiO5: Cr4+ crystal. OSA Tech Digest Series 20, 185 (1994)Google Scholar
8.Anino, C., Thery, J., Vivien, D.Cr4+ doped Li2MgSiO4, a new potential tunable laser material with room temperature fluorescence lifetime >100 μs. Proc. SPIE 3176, 38 (1997)CrossRefGoogle Scholar
9.Jousseaume, C., Kahn-Harari, A., Vivien, D., Derouet, J., Ribotb, F., Villainc, F.Structural and spectroscopic characterization of Cr: Li2MgSiO4 (γ0). J. Mater. Chem. 12, 1525 (2002)CrossRefGoogle Scholar
10.Jousseaume, C., Vivien, D., Kahn-Harari, A., Malkin, B.Z.Long-lifetime fluorescence and crystal field calculation in Cr4+-doped Li2MSiO4, M = Mg, Zn. Opt. Mater. 24, 143 (2003)CrossRefGoogle Scholar
11.Yamazaki, , Tanabe, S.Transparent Cr4+-doped gehlenite (Ca2Al2SiO7) glass-ceramics for broadband amplifierOptical Amplifiers and Their Applications: OSA Technical Digest Series (Optical Society of America, Washington, DC 2003)Google Scholar
12.Sharonov, M.Yu., Bykov, A.B., Owen, S., Petričević, V., Alfano, R.R.Spectroscopic study of transparent forsterite nanocrystalline glass-ceramics doped with chromium. J. Opt. Soc. Am. B 21, 2046 (2004)CrossRefGoogle Scholar
13.Zhuang, Y., Teng, Y., Luo, J., Zhu, B., Chi, Y., Wu, E., Zeng, H., Qiu, J.Broadband optical amplification in silicate glass ceramics containing Li2ZnSiO4:Cr4+ nanocrystals. Appl. Phys. Lett. 95, 111913 (2009)CrossRefGoogle Scholar
14.Iskhakova, L.D., Rybakov, V.B.Crystal structure of Li2MgSiO4. Crystallogr. Rep. 48, 39 (2003)CrossRefGoogle Scholar
15.Russell, D.L., Holliday, K., Grinberg, M., Hollis, D.B.Broadening of optical transitions in Cr3+-doped aluminosilicate glasses. Phys. Rev. B 59, 13712 (1999)CrossRefGoogle Scholar
16.Tanabe, S., Feng, X.Temperature variation of near-infrared emission from Cr4+ in aluminate glass for broadband telecommunication. Appl. Phys. Lett. 77, 818 (2000)CrossRefGoogle Scholar
17.Demos, S.G., Han, B.Y., Petričević, V., Alfano, R.R.Upconverted hot luminescence of Cr4+ ions in Mg2GeO4. J. Opt. Soc. Am. B 13, 2396 (1996)CrossRefGoogle Scholar
18.Kück, S., Petermann, K., Pohlmann, U., Huber, G.Near-infrared emission of Cr4+-doped garnets lifetimes, quantum efficiencies, and emission cross sections. Phys. Rev. B 51, 17323 (1995)CrossRefGoogle ScholarPubMed
19.Sharonov, M.Yu., Bykov, A.B., Myint, T., Petričević, V., Alfano, R.R.Spectroscopic study of chromium-doped transparent calcium germanate glass-ceramics. Opt. Commun. 275, 123 (2007)CrossRefGoogle Scholar
20.Tanabe, Y., Sugano, S.On the absorption spectra of complex ions II. J. Phys. Soc. Jpn. 9, 766 (1954)CrossRefGoogle Scholar
21.Powell, R.C., Xi, L., Gang, X., Quarles, G.J., Walling, J.C.Spectroscopic properties of alexandrite crystals. Phys. Rev. B 32, 2788 (1985)CrossRefGoogle ScholarPubMed