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Synthesis of MgAl2O4 spinel nanoparticles via polymer-gel and isolation-medium-assisted calcination

Published online by Cambridge University Press:  25 November 2014

Xuelian Du ,
Yaqiang Liu ,
Liqiang Li ,
Wencong Chen  and
Yuting Cui
Xuelian Du*
Affiliation:
Physics Department, Shangqiu Normal University, Shangqiu 476000, China
Yaqiang Liu
Affiliation:
Physics Department, Shangqiu Normal University, Shangqiu 476000, China
Liqiang Li*
Affiliation:
Physics Department, Shangqiu Normal University, Shangqiu 476000, China
Wencong Chen
Affiliation:
Physics Department, Shangqiu Normal University, Shangqiu 476000, China
Yuting Cui*
Affiliation:
Physics Department, Chongqing Normal University, Chongqing 404100, China
*
a)Address all correspondence to these authors. e-mail: [email protected]
b)e-mail: [email protected]
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Abstract

Magnesium aluminate (MgAl2O4) spinel nanoparticles with an average crystalline size of 35 nm were synthesized by polymer-gel and isolation-medium-assisted calcination. In the process, a large excess of MgO, 40 times the stoichiometric amount of spinel, is added to the precursor mixture to separate the spinel particles as they are nucleated to prevent their agglomeration and coarsening during calcination. Well-dispersed MgAl2O4 nanoparticles with a single-crystal structure were obtained after acid washing of calcined product. The microstructures of the as-prepared samples were characterized by differential thermal and thermogravimetric analysis, x-ray diffractometry, Fourier transform infrared spectroscopy, nitrogen adsorption–desorption isotherms, scanning electron microscopy, energy-dispersive x-ray spectroscopy, and transmission electron microscopy. The results indicate that MgO acting as the isolation medium is effective in preventing the agglomeration of MgAl2O4 nanoparticles, and it also prevents their contamination by introducing an isolation medium during the preparation process. The nanopowder was sintered up to 95% of the theoretical density but with parallel grain growth.

Keywords

powder processingnanocrystallinepolymer-gelisolation-medium-assisted calcinationmicrostructuremorphology
Type
Articles
Information
Journal of Materials Research , Volume 29 , Issue 24 , 28 December 2014 , pp. 2921 - 2927
Copyright
Copyright © Materials Research Society 2014 

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References

REFERENCES

Tokariev, O., Schnetter, L., Beck, T., and Malzbender, J.: Grain size effect on the mechanical properties of transparent spinel ceramics. J. Eur. Ceram. Soc. 33, 749–757 (2013).CrossRefGoogle Scholar
Khasanov, O., Dvilis, E., Khasanov, A., Polisadova, E., and Kachaev, A.: Optical and mechanical properties of transparent polycrystalline MgAl2O4 spinel depending on SPS conditions. Phys. Status Solidi C 10, 918−920 (2013).Google Scholar
Rothman, A., Kalabukhov, S., Sverdlov, N., Dariel, M., and Frage, N.: The effect of grain size on the mechanical and optical properties of spark plasma sintering-processed magnesium aluminate spinel MgAl2O4. Int. J. Appl. Ceram. Technol. 11, 146–153 (2014).Google Scholar
Morita, K., Kim, B., Yoshida, H., and Hiraga, K.: Spark-plasma-sintering condition optimization for producing transparent MgAl2O4 spinel polycrystal. J. Am. Ceram. Soc. 92, 1208–1216 (2009).Google Scholar
Saha, S., Das, S., Ghorai, U.K., Mazumder, N., Gupta, B.K., and Chattopadhyay, K.K.: Charge compensation assisted enhanced photoluminescence derived from Li-codoped MgAl2O4:Eu3+ nanophosphors for solid state lighting applications. Dalton Trans. 42, 12965−12974 (2013).Google Scholar
Ikesue, A. and Aung, Y.L.: Ceramic laser materials. Nat. Photonics 2, 721–727 (2008).Google Scholar
Roy, D.W. and Hastert, J.L.: Polycrystalline MgAl2O4 use as windows and domes from 0.3 to 6.0 micrometer. In 1983 International Techincal Conference/Europe (International Society for Optics and Photonics), pp. 37−43.Google Scholar
Cook, R., Kochis, M., Reimanis, I., and Kleebe, H.J.: A new powder production route for transparent spinel windows: Powder synthesis and window properties. In 2005 Defense and Security (International Society for Optics and Photonics), pp. 41–47.Google Scholar
Tokariev, O., Steinbrech, R.W., Schnetter, L., and Malzbender, J.: Micro- and macro-mechanical testing of transparent MgAl2O4 spinel. J. Mater. Sci. 47, 4821–4826 (2012).Google Scholar
Ganesh, I., Srinivas, B., Johnson, R., Saha, B.P., and Mahajan, Y.R.: Microwave assisted solid state reaction synthesis of MgAl2O4 spinel powders. J. Eur. Ceram. Soc. 24, 201–207 (2004).Google Scholar
Rashad, M.M., Zaki, Z.I., and EI-Shall, H.: A novel approach for synthesis of nanocrystalline MgAl2O4 powders by co-precipitation method. J. Mater. Sci. 44, 2992–2998 (2009).Google Scholar
Zhang, H.J., Jia, X.L., Liu, Z.J., and Li, Z.Z.: The low temperature preparation of nanocrystalline MgAl2O4 spinel by citrate sol-gel process. Mater. Lett. 58, 1625–1628 (2004).Google Scholar
Ye, G. and Troczynski, T.: Mechanical activation of heterogeneous sol-gel precursors for synthesis of MgAl2O4 spinel. J. Am. Ceram. Soc. 88, 2970–2974 (2005).Google Scholar
Goldstein, A.: Correlation between MgAl2O4-spinel structure, processing factors and functional properties of transparent parts. J. Eur. Ceram. Soc. 32, 2869–2886 (2012).Google Scholar
Reimanis, I. and Kleebe, H.J.: A review on the sintering and microstructure development of transparent spinel (MgAl2O4). J. Am. Ceram. Soc. 92, 1472–1480 (2009).Google Scholar
Du, X., Zhao, S., Liu, Y., Li, J., Chen, W., and Cui, Y.: Facile synthesis of monodisperse α-alumina nanoparticles via an isolation-medium-assisted calcinations method. Appl. Phys. A 116, 1963–1969 (2014).CrossRefGoogle Scholar
Vu, M., Haber, R., and Gocmez, H.: Preparation and sintering of Al2O3-doped magnesium aluminate spinel. In Advances in Ceramic Armor VIII: Ceramic Engineering and Science Proceedings, edited by Swab, J.J., Halbig, M. and Mathur, S.. Vol. 573, (John Wiley & Sons, Inc., Hoboken, NJ, 2012) pp. 93–103.Google Scholar
Lee, P.Y., Suematsu, H., Yano, T., and Yatsui, K.: Synthesis and characterization of nanocrystalline MgAl2O4 spinel by polymerized complex method. J. Nanopart. Res. 8, 911–917 (2006).Google Scholar
Naskar, M.K. and Chatterjee, M.: Magnesium aluminate (MgAl2O4) spinel powders from water-based sols. J. Am. Ceram. Soc. 88, 38–44 (2005).CrossRefGoogle Scholar
Tahmasebpour, M., Babaluo, A.A., Shafiei, S., and Pipelzadeh, E.: Studies on the synthesis of α-Al2O3 nanopowders by the polyacrylamide gel method. Powder Technol. 191, 91–97 (2009).Google Scholar
Li, G.J., Sun, Z.R., Chen, C.H., Cui, X.J., and Ren, R.M.: Synthesis of nanocrystalline MgAl2O4 spinel powders by a novel chemical method. Mater. Lett. 61, 3585–3588 (2007).Google Scholar
Pati, R.K. and Pramanik, P.: Low-temperature chemical synthesis of nanocrystalline MgAl2O4 spinel powder. J. Am. Ceram. Soc. 83, 1822–1824 (2000).Google Scholar
Montouillout, V., Massiot, D., Douy, A., and Couturesl, J.P.: Characterization of MgAl2O4 precursor powders prepared by aqueous route. J. Am. Ceram. Soc. 82, 3299–3304 (1999).Google Scholar
Su, X., Du, X., Li, S., and Li, J.: Synthesis of MgAl2O4 spinel nanoparticles using a mixture of bayerite and magnesium sulfate. J. Nanopart. Res. 12, 1813–1819 (2010).Google Scholar
Silverstein, R.M. and Webster, F.X.: Spectrometric Identification of Organic Compounds, 6th ed. (John Wiley & Sons, Inc., New York, 1996).Google Scholar
Xian, T., Yang, H., Shen, X., Jiang, J.L., Wei, Z.Q., and Feng, W.J.: Preparation of high quality BiFeO3 nanopowders via a polyacrylamide gel route. J. Alloys Compd. 480, 889–892 (2009).Google Scholar
Kurajica, S., Tkalcec, E., Sipusic, J., Matijasic, G., and Brnardic, I.: Synthesis and characterization of nanocrystalline zinc aluminate spinel by sol-gel technique using modified alkoxide precursor. J. Sol-Gel Sci. Technol. 46, 152–160 (2008).Google Scholar
Du, X., Wang, Y., Su, X., and Li, J.: Influences of pH value on the microstructure and phase transformation of aluminum hydroxide. Powder Technol. 192, 40–46 (2009).Google Scholar
Kloprogge, J.T., Hickey, L., and Frost, R.L.: FT-Raman and FT-IR spectroscopic study of synthetic Mg/Zn/Al-hydrotalcites. J. Raman Spectrosc. 35, 967–974 (2004).Google Scholar
Park, I.S., Choi, M., Kim, T.W., and Ryoo, R.: Synthesis of magnetically separable ordered mesoporous carbons using furfuryl alcohol and cobalt nitrate in a silica template. J. Mater. Chem. 16, 3409–3416 (2006).Google Scholar
Li, J.G., Ikegami, T., Lee, J.H., Mori, T., and Yajima, Y.: A wet-chemical process yielding reactive magnesium aluminate spinel (MgAl2O4) powder. Ceram. Int. 27, 481–487 (2001).Google Scholar