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Synthesis, characterization, and base–catalytic performance of ordered mesoporous aluminophosphate oxynitride materials

Published online by Cambridge University Press:  31 January 2011

Jiacheng Wang  and
Qian Liu
Jiacheng Wang
Affiliation:
State key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Shanghai 200050, People’s Republic of China; and Graduate School of the Chinese Academy of Sciences, Beijing 100039, People’s Republic of China
Qian Liu*
Affiliation:
State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Shanghai 20050, People’s Republic of China
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

The synthesis, physicochemical characterization, and catalytic evaluation of ordered mesoporous aluminophosphate oxynitride (MAPN) materials are presented here. The solid-base materials were prepared through treating aluminophosphate with an ordered mesostructure with ammonia at high temperatures. The MAPNs are well ordered, and possess high surface and pore volume. The amount of nitrogen incorporated increased with prolonged nitridation times. At the same time, the intensity of basicity is consistent with the nitrogen content, which is affirmed by Knoevenagel condensation reaction. The obtained ordered MAPN materials also possess acidity. The easy preparation and control of the nitrogen content of ordered MAPN materials, providing acidity and basicity, make them attractive as alternatives to a solid-base or acid-base catalyst, especially for the interactions of large molecules.

Keywords

CatalyticEnvironmentally benignPowder
Type
Articles
Information
Journal of Materials Research , Volume 22 , Issue 12 , December 2007 , pp. 3330 - 3337
Copyright
Copyright © Materials Research Society 2007

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