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Synthesis and nitrogen stability of ultrafine titanium carbonitride particles

Published online by Cambridge University Press:  03 March 2011

Dong-Won Lee ,
Jae-Hwan Ahn  and
Hyungsik Chung
Dong-Won Lee*
Affiliation:
Powder Materials Center, Korea Institute of Machinery and Materials (KIMM), Changwon, Kyungnam 641-010, Korea
Jae-Hwan Ahn
Affiliation:
Division of Chemical & Materials Engineering, Ajou University, Suwon, Kyoungki 443-749, Korea
Hyungsik Chung
Affiliation:
Division of Chemical & Materials Engineering, Ajou University, Suwon, Kyoungki 443-749, Korea
*
a) Address all correspondence to this author. e-mail: [email protected]
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Abstract

The ultrafine titanium carbonitride particles (TiC0.5N0.5) with 100 nm in mean size was successfully synthesized by nitridation treatment at ordinary temperatures, 1373∼1473 K of the nanostructured half-stoichiometric titanium carbide (TiC0.5) particles, which were produced by the magnesium reduction of gaseous TiCl4+1/4C2Cl4. In addition, the nitrogen stability for the produced titanium carbonitride particles at various temperatures and vacuum conditions was investigated experimentally and compared with values calculated by an ideal solution model.

Keywords

Chemical synthesisNanostructurePowder
Type
Articles
Information
Journal of Materials Research , Volume 22 , Issue 1 , January 2007 , pp. 233 - 237
Copyright
Copyright © Materials Research Society 2007

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References

REFERENCES

1Richter, V. and Ruthendorf, M.V.: On hardness and toughness of ultrafine and nanocrystalline hard materials. J. Ref. Met. Mater. 17, 141 (1999).Google Scholar
2Bergmann, E., Kaufmann, H., Schmid, R., and Vogel, J.: Ion-plated titanium carbonitride films. Surf. Coat. Technol. 42, 237 (1990).Google Scholar
3Zhang, S.: Titanium carbonitride-based ceramics: Processes and properties. Mater. Sci. Eng., A 163, 141 (1993).Google Scholar
4Alexeev, N.V., Balikhin, I.L., Kurkhin, E.N., Samokhin, A.V., Troiskaya, E.V., and Troiskij, V.N.: Synthesis of titanium nitride and carbonitride ultra-fine powders from titanium hydride in nitrogen arc discharge plasma jet. Fiz. Khim. Obrab. Mater. 1, 247 (1995).Google Scholar
5Licko, T., Figusch, V., and Puchyiva, J.: Carbothermal reduction and nitriding of TiO2. J. Eur. Ceram. Soc. 5(4), 257 (1989).Google Scholar
6Xiang, J., Xie, Z., Huang, Y., and Xiao, H.: Synthesis of Ti(C,N) ultrafine powders by carbothermal reduction of TiO2. J. Eur. Ceram. Soc. 20, 933 (2000).Google Scholar
7Parkhomenko, V.D., Serdyuk, G.N., and Kransnokutskii, Yu.I.: Kinetics of formation of titanium carbonitride at high temperatures. Phys. Chem. Mater. Treat. 20(5), 429 (1986).Google Scholar
8Rauschenbach, B.: Formation of compounds by high-flux nitrogen implantation in titanium. J. Mater. Sci. 21(2), 395 (1986).Google Scholar
9Eslamloo-Grami, M. and Munir, Z.A.: Mechanism of combustion synthesis of titanium carbonitride. J. Mater. Res. 11(12), 2968 (1996).Google Scholar
10Elger, G.W., Traut, D.E., Slavens, G.J., and Gerdemann, S.J.: Preparation of submicron titanium nitride by vapor-phase reactions. Metall. Trans. B 20, 493 (1989).Google Scholar
11Preiss, H., Berger, L-M., and Schultze, D.: Studies on the carbothermal preparation of titanium carbide from different gel precursors. J. Eur. Ceram. Soc. 19, 195 (1999).Google Scholar
12Lee, D.W., Ahnm, J.H., and Kim, B.K.: Preparation of nanostructured titanium carbonitride particles by Mg-thermal reduction. J. Mater. Res. 20(4), 844 (2005).Google Scholar
13Lee, D.W., Alexandrovskii, S., and Kim, B.K.: Mg-thermal reduction of TiCl4+CxCl4 solution for producing ultrafine titanium carbide. Mater. Chem. Phys. 88, 23 (2004).Google Scholar
14Paster, H.: Titanium-carbonitride-based hard alloys for cutting tools. Mater. Sci. Eng., A 105(106), 401 (1988).Google Scholar
15Kang, S.: Stability of N in Ti(CN) solid solutions for cermet applications. Powder Metall. 40(2), 139 (1997).Google Scholar
16Fernandes, J.C., Anjinho, C., Amaral, P.M., Rosa, L.G., Rodriguez, J., Martinez, D., Oliveira, F.A.C., and Shohoji, N.: Characterization of solar-synthesized TiCx (x = 0.50, 0.625, 0.75, 0.85, 0.90 and 1.0) by x-ray diffraction, density and Vickers microhardness. Mater. Chem. Phys. 77, 711 (2002).Google Scholar
17Jung, I.J., Kang, S.H., Jhi, S.H., and Ihm, J.S.: A study of the formation of Ti(CN) solid solutions. Acta Mater. 47(11), 3241 (1999).Google Scholar