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Supramolecular functionalization of single-walled carbon nanotubes with poly(2,5-dihexyl-1,4-phenylene-alt-2-amino-4,6-pyrimidine) and their electrochemical performance

Published online by Cambridge University Press:  06 November 2014

Sayyare Sidik  and
Xirali Mamtimin
Sayyare Sidik
Affiliation:
Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education and Xinjiang Uyghur Autonomous Region, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi, Xinjiang 830046, China
Xirali Mamtimin*
Affiliation:
Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education and Xinjiang Uyghur Autonomous Region, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi, Xinjiang 830046, China
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

The conjugated polymer poly(2,5-dihexyl-1,4-phenylene-alt-2-amino-4,6-pyrimidine) was synthesized and used in the supramolecular functionalization of single-walled carbon nanotubes (SWNTs). It was found that this polymer can form strong supramolecular polymer–nanotube assembly and produce a stable composite in solution. The resulting polymerized nanotubes were analyzed by UV–Vis absorption and emission spectroscopy, thermogravimetry, transmission electron microscopy and scanning electron microscopy. It was found that the noncovalent functionalization did not damage the nanotube structure. The polymer content in the polymer–nanotube composite could be calculated to be 41% by thermogravimetry analysis. The composite exhibited certain solubility in dimethylacetamide (DMAc), where the solubility in the absence of excess free polymer solution is 78.7 mg L−1. The composite exhibited a conductivity of 0.005 S cm−1 and the anodic and cathodic peaks were observed at 0.47 and 0.37 V. Galvanostatical charge/discharge tests give good cycling behavior of maintaining a stable capacitance value of 66.7 F g−1 over 1000 cycles at a current load of 1 mA cm−2 without distinct drop.

Type
Articles
Information
Journal of Materials Research , Volume 29 , Issue 22 , 28 November 2014 , pp. 2634 - 2643
Copyright
Copyright © Materials Research Society 2014 

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