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Superconducting fibers from organometallic precursors. Part II: Chemistry and low temperature processing1

Published online by Cambridge University Press:  31 January 2011

Richard M. Laine ,
Kay A. Youngdahl ,
Richard A. Kennish ,
Martin L. Hoppe ,
Zhi-Fan Zhang  and
Jean Ray
Richard M. Laine*
Affiliation:
Polymeric Materials Laboratory of the Washington Technology Center and the Department of Materials Science and Engineering, University of Washington, Seattle, Washington 98195
Kay A. Youngdahl
Affiliation:
Polymeric Materials Laboratory of the Washington Technology Center and the Department of Materials Science and Engineering, University of Washington, Seattle, Washington 98195
Richard A. Kennish
Affiliation:
Polymeric Materials Laboratory of the Washington Technology Center and the Department of Materials Science and Engineering, University of Washington, Seattle, Washington 98195
Martin L. Hoppe
Affiliation:
Polymeric Materials Laboratory of the Washington Technology Center and the Department of Materials Science and Engineering, University of Washington, Seattle, Washington 98195
Zhi-Fan Zhang
Affiliation:
Polymeric Materials Laboratory of the Washington Technology Center and the Department of Materials Science and Engineering, University of Washington, Seattle, Washington 98195
Jean Ray
Affiliation:
Polymeric Materials Laboratory of the Washington Technology Center and the Department of Materials Science and Engineering, University of Washington, Seattle, Washington 98195
*
a)Address correspondence to this author at the Department of Materials Science and Engineering, University of Michigan, Ann Arbor, Michigan 48109–2136.
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Abstract

Working principles are developed as guidelines for the selection and/or design of organometallic polymers for processing fiber precursors to metal oxide fibers. These principles form the basis for the selection of metal carboxylate preceramics as an optimal approach to processing yttrium barium cuprate (123) ceramic superconducting fibers. A variety of candidate yttrium, barium, calcium, strontium, bismuth, and copper metal carboxylates were synthesized. Solubility and empirical rheology tests were conducted to screen these compounds to choose spinnable precursor systems. Simple extrusion studies confirmed that THF solutions of mixtures of yttrium, barium, and copper isobutyrates with some quantity of barium 2-ethyl-hexanoates can be used to successfully form 60–70 μm diameter 123 precursor fibers.

Type
Articles
Information
Journal of Materials Research , Volume 6 , Issue 5 , May 1991 , pp. 895 - 907
Copyright
Copyright © Materials Research Society 1991

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