Hostname: page-component-78c5997874-m6dg7 Total loading time: 0 Render date: 2024-11-20T05:40:43.719Z Has data issue: false hasContentIssue false
  • English
  • Français

Structural properties of unconventional lead cuprate glass

Published online by Cambridge University Press:  03 March 2011

S. Hazra  and
A. Ghosh
S. Hazra
Affiliation:
Solid State Physics Department. Indian Association for the Cultivation of Science. Calcutta 700 032, India
A. Ghosh
Affiliation:
Solid State Physics Department. Indian Association for the Cultivation of Science. Calcutta 700 032, India
Get access

Abstract

Glass formation and structural properties of the unconventional lead cuprate glasses of compositions (CuO)x (PbO)100−x (mol %), are reported for the first time. X-ray diffraction and electron microscopic studies show that the glass formation occurs for x = 15-50 mol%. The compositional dependence of the density, molar volume, and glass transition temperature suggests that all glass compositions in this domain have the same topology and network connectivity. The glass structure is built up of [PbO4] tetrahedral units. On heat treatment above glass transition temperatures, the glasses crystallize to CuO and PbO. Electron Spin Resonance (ESR) spectra of the glass compositions consist of broad resonance lines.

Type
Articles
Information
Journal of Materials Research , Volume 10 , Issue 9 , September 1995 , pp. 2374 - 2378
Copyright
Copyright © Materials Research Society 1995

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1Dimitriev, Y., Mihanilov, V., and Gattif, E., Phys. Chem. Glasses 34, 114 (1986).Google Scholar
2Mianxue, W. and Peinan, Z., J. Non-Cryst. Solids 84, 344 (1986).CrossRefGoogle Scholar
3Takahashi, Y. and Yamaguchi, K., J. Mater. Sci. 25, 3950 (1990).CrossRefGoogle Scholar
4Aegerter, M., Serra, E., Rodrignes, A., Kordas, G., and Moore, G., in Proceedings of Sol-Gel Optics, Julio, San Diego (SPIE, 1990).Google Scholar
5Dumbaugh, W.H., Phys. Chem. Glasses 19, 121 (1978).Google Scholar
6Dumbaugh, W.H., Phys. Chem. Glasses 27, 119 (1986).Google Scholar
7Fajans, K. and Kreidl, N.J., J. Am. Ceram. Soc. 31, 105 (1948).CrossRefGoogle Scholar
8Standworth, J.E., J. Soc. Glass Tech. 32, 154T (1948).Google Scholar
9Bray, P. J., in The Structure of Glass, Proc. 4th All-Union Conference of the Glassy State, Part II (Consultants Bureau, New York, 1966), p. 52.Google Scholar
10Rao, B.G. and Rao, K.J., Phys. Chem. Glasses 25, 11 (1984).Google Scholar
11Rao, K.J., Wong, J., and Rao, B.J., Phys. Chem. Glasses 25, 57 (1984).Google Scholar
12Morikawa, H., Jegoudey, J., Mazieres, C., and Revcolevschi, A., J. Non-Cryst. Solids 44, 107 (1981).CrossRefGoogle Scholar
13Chen, H.S. and Miller, C.E., Rev. Sci. Instrum. 41, 1237 (1970).CrossRefGoogle Scholar
14Drake, C.F., Stephan, J. A., and Yates, B., J. Non-Cryst. Solids 28, 61 (1978).CrossRefGoogle Scholar
15Hazra, S. and Ghosh, A., Phys. Rev. B. 51, 851 (1995).CrossRefGoogle Scholar
16Hazra, S. and Ghosh, A., J. Chem. Phys. (in press).Google Scholar