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Soft process for the intercalation of ammonium cations into vanadium oxide

Published online by Cambridge University Press:  31 January 2011

Michio Inagaki ,
Tomoyuki Nakamura  and
Akira Shimizu
Michio Inagaki
Affiliation:
Graduate School of Engineering, Hokkaido University, Kita-ku, Sapporo 060–8628, Japan
Tomoyuki Nakamura
Affiliation:
Graduate School of Engineering, Hokkaido University, Kita-ku, Sapporo 060–8628, Japan
Akira Shimizu
Affiliation:
Graduate School of Engineering, Hokkaido University, Kita-ku, Sapporo 060–8628, Japan
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Abstract

A soft process for the intercalation of different ammonium cations into vanadium pentoxide was developed. By refluxing an aqueous solution containing ammonium , tetramethylammonium (CH3)4N+, and tetraethylammonium (C2H5)4N+ with V2O5 powders, intercalation compounds containing corresponding ammonium cations were obtained. The compound with aniline C6H5NH2 was also synthesized by the same process. The compounds with (CH3)4N+, (C2H5)4N+, and also C6H5NH2 had diffraction patterns consisting of very sharp 00l lines. The spacing for sandwiching the intercalates (the identity period), (CH3)4N+, (C2H5)4N+, and C6H5NH2, was 1.29, 1.31, and 1.39 nm, respectively.

Type
Articles
Information
Journal of Materials Research , Volume 13 , Issue 4 , April 1998 , pp. 896 - 900
Copyright
Copyright © Materials Research Society 1998

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References

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