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A silicon-29 NMR study of the structural intermediates in low pH sol-gel reactions

Published online by Cambridge University Press:  31 January 2011

L. W. Kelts  and
N. J. Armstrong
L. W. Kelts
Affiliation:
Corporate Research Laboratories, Eastman Kodak Company, Rochester, New York 14650
N. J. Armstrong
Affiliation:
Corporate Research Laboratories, Eastman Kodak Company, Rochester, New York 14650
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Abstract

Silicon-29 NMR is used to study the structural intermediates in tetramethyl and tetraethyl orthosilicate (TMOS and TEOS) low pH sol-gel reactions. Differences in the number of compact ring structures are related to differences in gel times. Reactions are followed at various silicon: water: acid molar ratios.

Type
Articles
Information
Journal of Materials Research , Volume 4 , Issue 2 , April 1989 , pp. 423 - 433
Copyright
Copyright © Materials Research Society 1989

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References

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