Hostname: page-component-586b7cd67f-t8hqh Total loading time: 0 Render date: 2024-11-23T03:38:56.210Z Has data issue: false hasContentIssue false
  • English
  • Français

Significant Increment of Photoluminescence Quantum Yield by Efficiently Prohibiting Fluorescence Quenching in Erbium(III) Organic Complexes

Published online by Cambridge University Press:  03 March 2011

Yigang Li ,
Hong Yang ,
Zian He ,
Liying Liu ,
Wencheng Wang ,
Fuyou Li  and
Lei Xu
Yigang Li
Affiliation:
The State Key Laboratory for Advanced Photonic Materials and Devices, Department of Optical Science and Engineering, Fudan University, Shanghai 200433, People’s Republic of China
Hong Yang
Affiliation:
The Institute for Advanced Materials, Fudan University, Shanghai 200433, People’s Republic of China
Zian He
Affiliation:
The State Key Laboratory for Advanced Photonic Materials and Devices, Department of Optical Science and Engineering, Fudan University, Shanghai 200433, People’s Republic of China
Liying Liu
Affiliation:
The State Key Laboratory for Advanced Photonic Materials and Devices, Department of Optical Science and Engineering, Fudan University, Shanghai 200433, People’s Republic of China
Wencheng Wang
Affiliation:
The State Key Laboratory for Advanced Photonic Materials and Devices, Department of Optical Science and Engineering, Fudan University, Shanghai 200433, People’s Republic of China
Fuyou Li
Affiliation:
The Institute for Advanced Materials, Fudan University, Shanghai 200433, People’s Republic of China
Lei Xu
Affiliation:
The State Key Laboratory for Advanced Photonic Materials and Devices, Department of Optical Science and Engineering, Fudan University, Shanghai 200433, People’s Republic of China
Get access

Abstract

A systematic investigation and comparison of the photoluminescence (PL) quantum yields of six erbium(III) organic complexes are reported. We demonstrated that the PL quantum yield could be significantly improved by getting rid of OH and CH groups in the complexes. Moreover, perfluooctanoic acid with neither OH nor CH groups was used as a ligand to form complex with Er3+. The quantum yield of the newly synthesized erbium(III) complex was found to be as high as 2%, 100 times higher than ever reported.

Keywords

LaserOptical propertiesPolymer
Type
Articles
Information
Journal of Materials Research , Volume 20 , Issue 11 , November 2005 , pp. 2940 - 2946
Copyright
Copyright © Materials Research Society 2005

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1Mears, R.J. and Baker, S.R.: Erbium fiber amplifiers and lasers. Opt. Quantum Electron. 24, 517 (1992).CrossRefGoogle Scholar
2Nikonorov, N.V. and Petrovskii, G.T.: Ion-exchanged glasses in integrated optics: The current state of research and prospects (a review). Glass Phys. Chem. 25, 16 (1999).Google Scholar
3Orignac, X., Barbier, D., Du, X.M., Almeida, R.M., McCarthy, O. and Yeatman, E.: Sol-gel silica/titania-on-silicon Er/Yb-doped waveguides for optical amplification at 1.5 μm. Opt. Mater. 12, 1 (1999).CrossRefGoogle Scholar
4Slooff, L.H., van Blaaderen, A., Polman, A., Hebbink, G.A., Klink, S.I., Van Veggel, F.C.J.M., Reinhoudt, D.N. and Hofstraat, J.W.: Rare-earth doped polymers for planar optical amplifiers. J. Appl. Phys. 91, 3955 (2002).CrossRefGoogle Scholar
5Kido, J. and Okamoto, Y.: Organo lanthanide metal complexes for electroluminescent materials. Chem. Rev. 102, 2357 (2002).CrossRefGoogle ScholarPubMed
6Tang, C.W. and VanSlyke, S.A.: Organic electroluminescent diodes. Appl. Phys. Lett. 51, 913 (1987).CrossRefGoogle Scholar
7Gillina, W.P. and Curry, R.J.: Erbium(III) tris(8-hydroxyquinoline) (ErQ): A potential material for silicon compatible 1.5 mm emitters. Appl. Phys. Lett. 74, 798 (1999).CrossRefGoogle Scholar
8Curry, R.J. and Gillina, W.P.: 1.54 mm electroluminescence from erbium(III) tris-(8-hydroxyquinoline) (ErQ)-based organic light-emitting diodes. Appl. Phys. Lett. 75, 1380 (1999).CrossRefGoogle Scholar
9Curry, R.J., Gillina, W.P., Knights, A.P. and Gwilliam, R.: Silicon-based organic light-emitting diode operating at a wavelength of 1.5 mm. Appl. Phys. Lett. 77, 2271 (2000).CrossRefGoogle Scholar
10Magennis, S.W., Ferguson, A.J., Bryden, T., Jones, T.S., Beeby, A. and Samuel, I.D.W.: Time-dependence of erbium(III) tris(8-hydroxyquinolate) near-infrared photoluminescence: Implications for organic light-emitting diode efficiency. Synth. Met. 138, 463 (2003).CrossRefGoogle Scholar
11Sun, R.G., Wang, Y.Z., Zheng, Q.B., Zhang, H.J. and Epstein, A.J.: 1.54 mm infrared photoluminescence and electroluminescence from an erbium organic compound. J. Appl. Phys. 87, 7589 (2000).CrossRefGoogle Scholar
12Zang, F.X., Hong, Z.R., Li, W.L., Li, M.T. and Sun, X.Y.: 1.4 mm band electroluminescence from organic light-emitting diodes based on thulium complexes. Appl. Phys. Lett. 84, 2679 (2004).CrossRefGoogle Scholar
13Koppe, M., Brabec, C.J., Sariciftci, N.S., Eichen, Y., Nakhmanovich, G., Ehrenfreund, E., Epstein, O. and Heiss, W.: Er3+-emission from organic complexes embedded in thin polymer films. Synth. Metals 121, 1511 (2001).CrossRefGoogle Scholar
14Yan, Y., Faber, A.J. and de Waal, H.: Luminescence quenching by OH groups in highly Er-doped phosphate glasses. J. Non-Cryst. Solids 181, 283 (1995).CrossRefGoogle Scholar
15Peters, P.M. and Houde-Walter, S.N.: New rare earth hosts: OH in laser glasses. SPIE Proceedings 3847, 168 (1999).CrossRefGoogle Scholar
16Li, Y.G., Liu, L.Y., He, Z.A., Tang, H.S., Xiao, S.M., Xu, L. and Wang, W.C.: Improvement of fluorescence lifetime from Er-doped sol-gel silica glass by dehydration in CCl4. J. Sol-Gel Sci. Technol. 30, 29 (2004).CrossRefGoogle Scholar
17Hebbink, G.A., Reinhoudt, D.N. and Van Veggel, F.C.J.M.: Increased luminescent lifetimes of Ln3+ complexes emitting in the near-infrared as a result of deuteration. Eur. J. Org. Chem., 4101 (2001).3.0.CO;2-9>CrossRefGoogle Scholar
18Hasegawa, Y., Ohkubo, T., Sogabe, K., Kawamura, Y., Wada, Y., Nakashima, N. and Yanagida, S.: Luminescence of novel neodymium sulfonylaminate complexes in organic media. Angew. Chem. Int. Ed. Engl. 39, 357 (2000).3.0.CO;2-M>CrossRefGoogle ScholarPubMed
19Klink, S.I., Hebbink, G.A., Grave, L., Van Veggel, F.C.J.M., Reinhoudt, D.N., Slooff, L.H., Polman, A. and Hofstraat, J.W.: Sensitized near-infrared luminescence from polydentate triphenylene-functionalized Nd3+, Yb3+, and Er3+ complexes. J. Appl. Phys. 86, 1181 (1999).CrossRefGoogle Scholar
20Hebbink, G.A., Klink, S.I., Alink, P.G.B.O. and van Veggel, F.C.J.M.: Visible and near-infrared light emitting calix[4]arene-based ternary lanthanide complexes. Inorg. Chim. Acta 317, 114 (2001).CrossRefGoogle Scholar
21Driesen, K., Van Deun, R., Gorller-Walrand, C. and Binnemans, K.: Near-infrared luminescence of lanthanide calcein and lanthanide dipicolinate complexes doped into a silica-PEG hybrid material. Chem. Mater. 16, 1531 (2004).CrossRefGoogle Scholar
22 Erbium-Doped Fiber Amplifiers, edited by Becker, P.C., Olsson, N.A., and Simpson, J.R. (Academic Press, 1999), p.112.Google Scholar
23http://www.chem.uni-potsdam.de/tools/.Google Scholar