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Reactions at the Interface Between Al2O3–SiO2 Ceramics with Additives of Alkaline-earth Oxides and Liquid Al–Si Alloy

Published online by Cambridge University Press:  31 January 2011

M. Oliveira ,
S. Agathopoulos  and
J. M. F. Ferreira
M. Oliveira
Affiliation:
Department of Ceramics and Glass Engineering, University of Aveiro, Portugal
S. Agathopoulos
Affiliation:
Department of Ceramics and Glass Engineering, University of Aveiro, Portugal
J. M. F. Ferreira
Affiliation:
Department of Ceramics and Glass Engineering, University of Aveiro, Portugal
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Abstract

The interfacial reactions between aluminosilicate ceramics doped with MgO, CaO, or BaO and Al–7 wt% Si alloy were investigated at 1023, 1173, and 1323 K under vacuum for 4 h. Alkaline-earth oxide additives defined phase formation and microstructure of the sintered ceramics and subsequently controlled the ceramic/metal interfacial reactions, which were always intensive. In general, reaction zones consisted of Al2O3, infiltrated with Al. In the case of CaO- and BaO-doped ceramics, precipitates formed into the metal phase and concentrated the reduced Ca and Ba, respectively. A reaction mechanism is proposed, which anticipates an active role of SiO2.

Type
Articles
Information
Journal of Materials Research , Volume 17 , Issue 3 , March 2002 , pp. 641 - 647
Copyright
Copyright © Materials Research Society 2002

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References

Wynn, A.M., Br. Ceram. Trans. J. 91, 153 (1992).Google Scholar
White, J., in The Relationship of Phase Diagrams to Constitution and Microstructure in Ceramic and Ceramic-Metal Systems Refactory Materials–A Series of Monographs: Phase Diagrams–Materials Science and Technology, Vol. 6–11, edited by Alper, Allen M. (Academic Press, Inc., London, 1971), p. 21.Google Scholar
Hall, T.H. and Wilson, G., in Non-Wetting Refractories for Aluminum Furnace Applications. Proc. Int. Symp. Adv. in Refractories for the Metallurgical Industries, Winnipeg, Canada, August 23–26 (Academic Press, Inc., London, 1987), p. 225.Google Scholar
Cruz, C.R.V., Refractários para Fundição (Comissão Cultural da Ordem dos Engenheiros, Lisboa, Portugal, 1984).Google Scholar
Furness, A.G., in The Importance of Refractory Materials in Aluminium Production, edited by Xiangchong, Zhong, Jiaquan, Lu, and Xingjian, YanProc. Int. Symp. Refractories, Hangzhou, China, November 15–18 (International Academic Publishers, A Pergamon Joint Venture/Beijing, People’s Republic of China, 1988), p. 539.Google Scholar
Weirauch, D.A. Jr. and Grady, G.E., Jr., Wetting and Corrosion in the Al–Mg–Si–O System, edited by Rigaud, M.A.J., Proc. Int. Symp. Adv. in Refractories for the Metallurgical Industries, Winnipeg, Canada, August 23–26 (Pergamon Press, Toronto, Ontario, Canada, 1987), p. 251.Google Scholar
Kraner, H.M., in The Use of Phase Diagrams in the Development and Use of Refractories, Refractory Materials -A series of Monographs, Vol. 6–11, edited by Alper, A.M. (Academic Press, London, United Kingdom, 1970), p. 67.Google Scholar
Lee, W.E. and Moore, R.E., J. Am. Ceram. Soc. 81, 1385 (1998).CrossRefGoogle Scholar
Saiz, E. and Tomsia, A.P., J. Am. Ceram. Soc. 81, 2381 (1998).CrossRefGoogle Scholar
Drouzy, M. and Richard, M., Fonderie 332, 121 (1974).Google Scholar
Afshar, S. and Allaire, C., JOM 4, 43 (2000).CrossRefGoogle Scholar
Sarpoolaky, H., Zhang, S., Argent, B.B., and Lee, W.E., J. Am. Ceram. Soc. 84, 426 (2001).CrossRefGoogle Scholar
Allaire, C. and Desclaux, P., J. Am. Ceram. Soc. 74, 2781 (1991).CrossRefGoogle Scholar
Allahevrdi, M., Afshar, S., and Allaire, C., JOM 50, 30 (1998).CrossRefGoogle Scholar
Liu, W. and Koester, U., J. Mater. Sci. Lett. 15, 2188 (1996).Google Scholar
Watari, T., Mori, K., Torikai, T., and Matsuda, O., J. Am. Ceram. Soc. 77, 2599 (1994).CrossRefGoogle Scholar
Eustathopoulos, N. and Drevet, B., J. Phys. III France 4, 1856 (1994).Google Scholar
Davies, L.J. and Mc, J.M.Collum, in Refractory Selection for Non-Ferrous Smelting Applications, edited by Rigaud, M.A.J., Proc. Intern. Symp. Advances in Refractories for the Metallurgical Industries, Winnipeg, Canada, August 23–26 (Pergamon Press, Toronto, Ontario, Canada, 1987), p. 195.Google Scholar
Davies, J.R., Aluminum and Aluminum Alloys (ASM Specialty Book, Materials Park, OH, 1996).Google Scholar
M.I. Pech-Canul, Katz, R.N., Makhlouf, M.M., and Pickard, S., J. Mater. Sci. 35, 2167 (2000).Google Scholar
Oliveira, M., Agathopoulos, S., and Ferreira, J.M.F., Acta Mater. (2002, in press).Google Scholar
Li, J-G., Ceram. Int. 20, 391 (1994).CrossRefGoogle Scholar
Sobczak, N., Asthana, R., Ksiazek, M., Radziwill, W., Mikulowski, B. and Surowiak, I., in The Influence of Wettability on the Interfacial Strength in the Al-Alumina System, edited by Rohatgi, P.K., Proc. Symp. ASM International, St. Louis, MO, (The Minerals, Metals and Materials Society, PA, 2000), p. 129.Google Scholar
Landry, K. and Eustathopoulos, N., Acta Mater. 44, 3923 (1996).CrossRefGoogle Scholar
Allaire, C. and Guermazi, M., Modern Casting 4, 45 (2000).Google Scholar
Galassi, C., Roncari, E., Basarello, C., and Lapasin, R., J. Am. Ceram. Soc. 82, 3453 (1999).CrossRefGoogle Scholar
Schmutzler, H.J. and Sandhage, K.H., Metall. Mater. Trans. B 26, 135 (1995).CrossRefGoogle Scholar
Quander, S.W., Bandyopadhyay, A., and Aswath, P.B., J. Mater. Sci. 32, 2021 (1997).CrossRefGoogle Scholar
Ali, M.M., Agarwal, S.K., and Handoo, S.K., Cement Concrete Res. 27, 979 (1997).CrossRefGoogle Scholar
Petzow, G. and G.Effenberg, Ternary Alloys: A Comprehensive Compendium of Evaluated Constitutional Data and Phase Diagrams (VCH, Weinheim, Germany, 1988), p. 310, 682.Google Scholar
Korgul, P., Wilson, D.R., and Lee, W.E., J. Eur. Ceram. Soc. 17, 77 (1997).CrossRefGoogle Scholar
JANAF Thermochemical Tables, J. Phys. Chem. Ref. Data 14, 156 (1985).Google Scholar
Xiao, P. and Derby, B., J. Am. Ceram. Soc. 77, 1761 (1994).CrossRefGoogle Scholar
H. Venugopalan. Tankala, K., and Debroy, T., Metall. Mater. Trans. B 27, 43 (1996).Google Scholar
Wu, S.Q. and Ca, G.H.O, J. Mat. Sci. Let. 19, 1449 (2000).CrossRefGoogle Scholar