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Reactions and reversible hydrogenation of single-walled carbon nanotube anions

Published online by Cambridge University Press:  28 September 2012

Chaiwat Engtrakul ,
Calvin J. Curtis ,
Jamie E. Ellis ,
Lynn M. Gedvilas ,
Jeffrey L. Blackburn ,
Lin J. Simpson ,
Kim M. Jones ,
Philip A. Parilla ,
Anne C. Dillon  and
Michael J. Heben
...Show all authors
Chaiwat Engtrakul
Affiliation:
National Renewable Energy Laboratory, Golden, Colorado80401
Calvin J. Curtis
Affiliation:
National Renewable Energy Laboratory, Golden, Colorado80401
Jamie E. Ellis
Affiliation:
National Renewable Energy Laboratory, Golden, Colorado80401
Lynn M. Gedvilas
Affiliation:
National Renewable Energy Laboratory, Golden, Colorado80401
Jeffrey L. Blackburn
Affiliation:
National Renewable Energy Laboratory, Golden, Colorado80401
Lin J. Simpson
Affiliation:
National Renewable Energy Laboratory, Golden, Colorado80401
Kim M. Jones
Affiliation:
National Renewable Energy Laboratory, Golden, Colorado80401
Philip A. Parilla
Affiliation:
National Renewable Energy Laboratory, Golden, Colorado80401
Anne C. Dillon
Affiliation:
National Renewable Energy Laboratory, Golden, Colorado80401
Michael J. Heben
Affiliation:
National Renewable Energy Laboratory, Golden, Colorado80401
Thomas Gennett*
Affiliation:
National Renewable Energy Laboratory, Golden, Colorado80401
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

Single-walled carbon nanotube (SWNT) radical anions will react with tetrahydrofuran and generate ethylene, enolates, and a partially hydrogenated nanotube backbone. The experimental evidence suggests that there are sp3 C–H binding interactions. The total gravimetric content of hydrogen on a sample averages from 3.5% to 3.9% w/w, about four times the total amount observed for nanotubes hydrogenated via traditional Birch reduction reactions. Furthermore, the hydrogen desorbs at temperatures up to 400 °C less than those observed for the hydrogenated SWNTs formed after the Birch reduction. Finally, the first room temperature electron spin resonance spectrum of a nanotube radical ion is also reported.

Keywords

nanostructurehydrogenationenergy storage
Type
Articles
Information
Journal of Materials Research , Volume 27 , Issue 21 , 14 November 2012 , pp. 2806 - 2811
Copyright
Copyright © Materials Research Society 2012

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References

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