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Properties of zirconia films dispersed with PbS nanoparticles

Published online by Cambridge University Press:  31 January 2011

Weimin Huang  and
Jianlin Shi
Weimin Huang
Affiliation:
State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Dingxi Road, Shanghai 200050, People's Republic of China
Jianlin Shi*
Affiliation:
State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Dingxi Road, Shanghai 200050, People's Republic of China
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

PbS/ZrO2 optical films were prepared by the dip-coating method from a mixed sol containing two precursors, Zr(OC3H7)4 and Pb(CH3COO)2. The phase structure and size of PbS nanoparticles were characterized by x-ray diffraction and transmission electron microscopy, respectively. Optical absorption and fluorescence spectra were taken on the PbS/ZrO2 films. Larger blue shifts of band edge and weak fluorescence emission of PbS were observed. The third-order nonlinear properties of PbS/ZrO2 films were studied. The calculated values of nonlinear refractive indexes n2 varied between 10−8 and 10−9 cm2/W.

Type
Articles
Information
Journal of Materials Research , Volume 15 , Issue 11 , November 2000 , pp. 2343 - 2346
Copyright
Copyright © Materials Research Society 2000

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References

REFERENCES

1.Stegeman, G.I., Burke, J.J., Seaton, C.T., in Integrated Optical Circuits and Components, edited by Hutchinson, L.D. (Marcel Dekker, New York, 1987), p. 47.Google Scholar
2.Reisfled, R., Structure and Bonding 85, (Springer, Heidelberg, Germany, 1996).Google Scholar
3.Beecroft, L.L. and Ober, C.K., Chem. Mater. 9, 1302 (1997).Google Scholar
4.Bass, M., Van Stryland, E.W., Williams, D.R., and Wolfe, W.L., Handbook of Optics, (McGraw-Hill, New York, 1995), pp. 36, 38.Google Scholar
5.Banyai, L., Hu, Y.Z., Lindberg, M., and Koch, S.W., Phys. Rev. B 38, 8142 (1988).CrossRefGoogle Scholar
6.Pellegri, N., Trbojevich, R., Desanctis, O., and Kadono, K., J. Sol-Gel Sci. Tech. 8, 1023 (1997).Google Scholar
7.Martucci, A., Guglielmi, M., and Urabe, K., J. Sol-Gel Sci. Technol. 11, 105 (1998).CrossRefGoogle Scholar
8.Guglielmi, M., Martucci, A., Menegazzo, E., Righini, G.C., Pelli, S., Fick, J., and Vitrant, G., J. Sol-Gel Sci. Technol. 8, 1017 (1997).Google Scholar
9.Wang, Y., Suna, A., Mahler, W., and Kasowski, R., J. Chem. Phys. 87, 7315 (1987).Google Scholar
10.Gao, M., Wang, Y., Yang, B., and Bian, F., J. Chem. Soc.—Chem. Commun. 2779 (1994).CrossRefGoogle Scholar
11.Mukherjee, M., Datta, A., and Chakravorty, D., Appl. Phys. Lett. 64, 1159 (1994).CrossRefGoogle Scholar
12.Guglielmi, M., Martucci, A., Fick, J., and Vitrant, G., J. Sol-Gel Sci. Technol. 11, 229 (1998).CrossRefGoogle Scholar
13.Atta, A.K., Biswas, P.K., and Ganguli, D., Mater. Lett. 15, 99 (1992).CrossRefGoogle Scholar
14.Cordoncillo, E., Carda, J.B., Tena, M.A., Monros, G., and Escribano, P., J. Sol-Gel Sci. Technol. 8, 1043 (1997).Google Scholar
15.Sorek, Y., Zevin, M., and Reisfeld, R., Chem. Mater. 9, 670 (1997).Google Scholar
16.Nogami, M., Nagasaka, K., and Suzuki, S., J. Non-Cryst. Solids 122, 101 (1990).Google Scholar
17.Minti, M., Eyal, M., Reisfeld, R., and Berkovic, G., Chem. Phys. Lett. 183, 277 (1991).CrossRefGoogle Scholar
18.Nozik, A.J., Williams, F., Nenadvic, M.T., Raih, T., and Mici, O.I., J. Phys. Chem. 89, 397 (1985);Google Scholar
Zhao, J., Zhang, J.S., Jing, C.M., Zhou, C.F., Gao, Y., Huang, S.H., Yu, J.Q., Zhou, B.S., Li, S.T., and Zhi, L.L., J. Luminescence (Chinese), 14(1), 1 (1993).Google Scholar
19.Huang, W. and Shi, J., Scripta Metall. Mater. (in press).Google Scholar
20.Sheik-Bahae, M., Hagan, D.J., Van Stryland, E.W., Opt. Lett. 14, 955 (1989).CrossRefGoogle Scholar
21.Toda, H., Verber, C.M., Opt. Lett. 17, 1379 (1992).Google Scholar