Hostname: page-component-78c5997874-v9fdk Total loading time: 0 Render date: 2024-11-20T04:30:57.812Z Has data issue: false hasContentIssue false
  • English
  • Français

Properties of ceramics in the system ZrB2–Ta5Si3

Published online by Cambridge University Press:  03 March 2011

I.G. Talmy ,
J.A. Zaykoski ,
M.M. Opeka  and
A.H. Smith
I.G. Talmy*
Affiliation:
Naval Surface Warfare Center Carderock Division (NSWCCD), West Bethesda, Maryland 20817-5700
J.A. Zaykoski
Affiliation:
Naval Surface Warfare Center Carderock Division (NSWCCD), West Bethesda, Maryland 20817-5700
M.M. Opeka
Affiliation:
Naval Surface Warfare Center Carderock Division (NSWCCD), West Bethesda, Maryland 20817-5700
A.H. Smith
Affiliation:
Naval Surface Warfare Center Carderock Division (NSWCCD), West Bethesda, Maryland 20817-5700
*
a) Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

Ceramics in the system ZrB2–Ta5Si3 were studied as candidates for the development of new ultra high-temperature ceramic materials. The ceramics were prepared by hot pressing at 1900–2200 °C in He. Mutual additions of ZrB2 and Ta5Si3 even in small amounts had significant densifying effects due to chemical interactions and solid solubility between the components, which have not been reported in the literature. Materials containing between 8 and 30 vol% Ta5Si3 exhibited less oxidation than pure ZrB2, which is the result of phase separation in surface borosilicate glass induced by Ta2O5. For higher concentrations, oxidation resistance substantially decreased with increasing Ta5Si3 content. The trend in the oxidation behavior of the materials showed significant dependence on the volume of oxidation products. Ceramics containing up to 10 mol% (30 vol%) Ta5Si3, which showed the highest oxidation resistance, also had the highest strength and hardness in the system, and are of interest for high-temperature structural applications in oxidizing environments.

Keywords

CeramicPhase equilibriaTa
Type
Articles
Information
Journal of Materials Research , Volume 21 , Issue 10 , October 2006 , pp. 2593 - 2599
Copyright
Copyright © Materials Research Society 2006

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Talmy, I., Zaykoski, J., Opeka, M., Dallek, S. Oxidation behavior of ZrB2 ceramics modified with SiC and group IV–VI transition metal diborides. Proceedings of the International Symposium on High Temperature Corrosion and Materials Chemistry III, Vol. 2001–12, edited by McNallan, M. and Opila, E. (The Electrochemical Society, Inc., Pennington, NJ, 2001) p. 144.Google Scholar
2.Pastor, H., Meyer, R.: An investigation of the effect of additions of metal silicides on titanium and zirconium borides from the point of view of their sintering behavior and their resistance to oxidation at high temperatures. Rev. Int. Htes Temp. Refract. 2, 41 (1974).Google Scholar
3.Shaffer, P. Oxidation-resistant ceramics and method of manufacturing same (U.S. Patent No. 3, 189, 477, 1965).Google Scholar
4.Parthe, E., Nowotny, H., Schmid, H.: Structure of silicides. Monatsh. Chem. 86, 385 (1955) in German.Google Scholar
5.Kudielka, H., Nowotny, H., Findeisen, G.: Study on the systems: V-B, Nb-B, V-B-Si and Ta-B-Si. Monatsh. Chem. 88, 1048 (1957) in German.CrossRefGoogle Scholar
6.Kieffer, R., Benesovsky, F.: Recent developments in the field of silicides and borides of the high-melting point transition metals. Powder Metall. 1/2, 145 (1958).Google Scholar
7.Mayer, I., Felner, I.: Nowotny phases of M5X3-type rare-earth silicides and Germanides with boron. J. Less-Common Met. 37, 171 (1974).CrossRefGoogle Scholar
8.Brukl, C.E. Ternary phase equilibrium in transition metal-boron-carbon-silicon systems. Part II. Ternary systems, AFML-TR-65-2, Part II, Vol. X (USAF, Dayton, OH, 1966).Google Scholar