Hostname: page-component-586b7cd67f-l7hp2 Total loading time: 0 Render date: 2024-11-22T19:59:22.656Z Has data issue: false hasContentIssue false
  • English
  • Français

Preparation of nonaggregated silver nanoparticles by the liquid phase plasma reduction method

Published online by Cambridge University Press:  03 April 2013

Heon Lee ,
Sung Hoon Park ,
Sang-Chul Jung ,
Je-Jung Yun ,
Sun-Jae Kim  and
Do-Heyoung Kim
Heon Lee
Affiliation:
Department of Environmental Engineering, Sunchon National University, Sunchon, Jeonnam 540-742, Republic of Korea
Sung Hoon Park
Affiliation:
Department of Environmental Engineering, Sunchon National University, Sunchon, Jeonnam 540-742, Republic of Korea
Sang-Chul Jung*
Affiliation:
Department of Environmental Engineering, Sunchon National University, Sunchon, Jeonnam 540-742, Republic of Korea
Je-Jung Yun
Affiliation:
Nano Bio Research Center, Jangseong, Jeonnam 515-893, Republic of Korea
Sun-Jae Kim
Affiliation:
Faculty of Nanotechnology and Advanced Materials Engineering, Sejong University, Seoul 143-747, Republic of Korea
Do-Heyoung Kim
Affiliation:
School of Applied Chemical Engineering and Research Institute for Catalysis, Chonnam National University, Gwangju 500-757, Republic of Korea
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

The liquid phase plasma reduction method has been applied to prepare silver nanoparticles from a solution of silver nitrate (AgNO3) using a bipolar pulsed electrical discharge system. The excited states of atomic silver, hydrogen and oxygen as well as the molecular bands of hydroxyl radicals were detected in the emission spectra. As the discharge duration increased up to 10 min, silver particle peaks produced by surface plasmon absorption were observed around 430 nm. Both the particle size and the particle numbers were observed to increase with the length of the plasma treatment time and with the initial AgNO3 concentration. Spherical nanoparticles of about 5–20 nm in size were obtained with the discharging time of 5 min, whereas aggregates of nanoparticles of about 10–50 nm in size were mainly produced with the discharging time of 20 min. The cationic surfactant of cetyltrimethylammonium bromide (CTAB) added with the CTAB/AgNO3 molar ratio of 30% was shown to inhibit nanoparticle aggregation.

Keywords

liquid-phase plasmananoparticlesilversurfactantoptical emission spectra
Type
Articles
Information
Journal of Materials Research , Volume 28 , Issue 8 , 28 April 2013 , pp. 1105 - 1110
Copyright
Copyright © Materials Research Society 2013

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Balan, L. and Burget, D.: Synthesis of metal/polymer nanocomposite by UV-radiation curing. Eur. Polym. J. 42, 3180 (2006).Google Scholar
Sosa, I.O., Nognez, C., and Barrera, R.G.: Optical properties of metal nanoparticles with arbitrary shapes. J. Phys. Chem. B. 107, 6269 (2003).CrossRefGoogle Scholar
Hayashi, T., Ohno, T., Yatsuya, S., and Uyeda, R.: Formation of ultrafine metal particles by gas-evaporation technique. J. Appl. Phys. 16, 705 (1976).Google Scholar
Barnickel, P. and Wokaun, A.: Synthesis of metal colloids in inverse microemulsions. Mol. Phys. 69, 1 (1990).Google Scholar
Sun, Y. and Xia, Y.: Gold and silver nanoparticles: A class of chromophores with colors tunable in the range from 400 to 750 nm. Analyst 128, 686 (2003).CrossRefGoogle Scholar
Barnickel, P. and Wokaun, A.: Silver coated latex spheres. Optical absorption spectra surface enhanced Raman scattering. Mol. Phys. 57, 1355 (1989).Google Scholar
Jiang, H.Q., Manolache, S., Wong, A.C.L., and Denes, F.S.: Plasma-enhanced deposition of silver nanoparticles onto polymer and metal surfaces for the generation of antimicrobial characteristics. J. Appl. Polym. Sci. 93, 1411 (2004).Google Scholar
Xu, J., Han, X., Lin, H., and Hu, Y.: Synthesis and optical properties of silver nanoparticles stabilized by gemini surfactant. Colloids Surf., A 273, 179 (2006).Google Scholar
Cai, W., Zhang, Y., Jia, J., and Zhang, L.: Semiconducting optical properties of silver/silica mesoporous composite. Appl. Phys. Lett. 73, 2709 (1998).Google Scholar
Pal, A.K., Hussain, S., and Roy, R.K.: Incorporation of silver nanoparticles in DLC matrix and surface plasmon resonance effect. Chem. Phys. 99, 375 (2006).Google Scholar
Mock, J.J., Barbic, M., and Smith, D.R.: Silver nanodisks: Synthesis, characterization, and self-assembly. J. Chem. Phys. 116, 6755 (2002).Google Scholar
Abid, J.P., Wark, A.W., Brevet, P.F., and Girault, H.: Preparation of silver nanoparticles in solution from a silver salt by laser irradiation. Chem. Commun. 7, 92 (1993).Google Scholar
Zou, K., Zhang, X.H., Duan, X.F., Meng, X.M., and Wu, S.K.: Seed-mediated synthesis of silver nanostructures and polymer/silver nanocables by UV irradiation. J. Cryst. Growth 273, 285 (2004).Google Scholar
Pal, A., Shah, S., and Devi, S.: Synthesis of Au, AgAu–Ag alloy nanoparticles in aqueous polymer solution. Colloids Surf., A 302, 51 (2007).Google Scholar
Xiong, Y., Siekkinen, A.R., Wang, J., Yin, Y., Kim, M.J., and Xia, Y.: Synthesis of silver nanoplates at high yields by slowing down the polyol reduction of silver nitrate with polyacrylamide. J. Mater. Chem. 17, 2600 (2007).Google Scholar
Oliveira, M.M., Ugarte, D., Zanchet, D., and Zarbin, A.: Influence of synthetic parameters on the size, structure and stability of dodecanethiol-stabilized silver nanoparticles. J. Colloid Interface Sci. 292, 429 (2005).Google Scholar
Zhang, W., Qiao, X., and Chen, J.: Synthesis of nanosilver colloidal particles in water/oil microemulsion. Colloids Surf., A 299, 22 (2007).Google Scholar
Lung, J.K., Huang, J.C., Tien, D.C., Liao, C.Y., Tseng, K.H., Tsung, T.T., Kao, W.S., Tsai, T.H., Jwo, C.S., Lin, H.M., and Stobinski, L.: Preparation of gold nanoparticles by arc discharge in water. J. Alloys Compd. 434, 655 (2007).Google Scholar
Saito, N., Hieda, J., and Takai, O.: Synthesis process of gold nanoparticles in solution plasma. Thin Solid Films 518, 912 (2009).CrossRefGoogle Scholar
Richmonds, C. and Sankaran, R.M.: Plasma-liquid electrochemistry: Rapid synthesis of colloidal metal nanoparticles by microplasma reduction of aqueous cations. Appl. Phys. Lett. 93, 131501 (2008).Google Scholar
Chung, Y. and Kang, W.: Preparation of ZnO nanoparticles by laser ablation of dispersed ZnO powder in solution. J. Korean Chem. Soc. 50, 440 (2006).Google Scholar
Potocký, Š., Saito, N., and Takai, O.: Needle electrode erosion in water plasma discharge. Thin Solid Films 518, 918 (2009).Google Scholar
Baroch, P., Anita, V., Saito, N., and Takai, O.: Bipolar pulsed electrical discharge for decomposition of organic compounds in water. J. Electrostatics 66, 294 (2008).Google Scholar