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Preparation of a sulfonated activated carbon fiber catalyst with γ-irradiation-induced grafting method

Published online by Cambridge University Press:  19 November 2012

Qihan Li ,
Shuixia Chen ,
Linzhou Zhuang ,
Xiuzhu Xu  and
Haichao Li
Qihan Li
Affiliation:
PCFM Lab, School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, People’s Republic of China
Shuixia Chen*
Affiliation:
PCFM Lab, School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, People’s Republic of China; and DSAPM Lab, Materials Science Institute, Sun Yat-sen University, Guangzhou 510275, People’s Republic of China
Linzhou Zhuang
Affiliation:
PCFM Lab, School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, People’s Republic of China
Xiuzhu Xu
Affiliation:
PCFM Lab, School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, People’s Republic of China
Haichao Li
Affiliation:
PCFM Lab, School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, People’s Republic of China
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

A sulfonated activated carbon fiber catalyst (SACF) was prepared through γ-irradiation-induced grafting of styrene onto the surface of activated carbon fiber (ACF) with an irradiation dose of 0.837 kGy/h for 48 h that was then sulfonated with chlorosulfonic acid under mild reaction conditions. Scanning electron microscopy observation showed that the ACF was wrapped by a thin layer of copolymer, and Fourier transfer infrared spectroscopy analysis indicated that sulfonic acid groups were successfully introduced onto the ACF. Pore structure analysis based on nitrogen adsorption isotherms at 77 K demonstrated that pore parameters of ACF were well maintained after the process of grafting and sulfonation modification. Proper conditions for the SACF preparation were sulfonated at 80 °C for 1.5 h in the 20% mass percentage of chlorosulfonic acid solution using ACF precursor, whose acid density could reach 1.47 mmol/g. The sulfonated ACF was used as catalyst for the esterification of acetic acid and ethanol. Evaluation of the catalytic activity of SACF showed evident advantages over other typical catalyst, with a turnover frequency value of 0.780 min−1, about five times higher than Nafion.

Type
Articles
Information
Journal of Materials Research , Volume 27 , Issue 24 , 28 December 2012 , pp. 3083 - 3089
Copyright
Copyright © Materials Research Society 2012

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References

REFERENCES

Wu, Y., Fu, Z., Yin, D., Xu, Q., Liu, F., Lu, C., and Mao, L.: Microwave-assisted hydrolysis of crystalline cellulose catalyzed by biomass char sulfonic acids. Green Chem. 12, 696 (2010).CrossRefGoogle Scholar
Jiang, Y., Li, X., Cao, Q., and Mu, X.: Acid functionalized, highly dispersed carbonaceous spheres: An effective solid acid for hydrolysis of polysaccharides. J. Nanopart. Res. 13, 463 (2011).CrossRefGoogle Scholar
Wilson, K. and Lee, A.F.: Rational design of heterogeneous catalysts for biodiesel synthesis. Catal. Sci. Technol. 2, 844 (2012).CrossRefGoogle Scholar
Wang, X. and Liang, X.: Highly efficient procedure for biodiesel synthesis using novel resorcinol–furaldehyde based acid catalyst. Fuel 97, 891 (2012).CrossRefGoogle Scholar
Fang, L., Zhang, K., Li, X., Wu, H., and Wu, P.: Preparation of a carbon-silica mesoporous composite functionalized with sulfonic acid groups and its application to the production of biodiesel. Chin. J. Catal. 33, 114 (2012).CrossRefGoogle Scholar
Liu, K., Li, C., Zhang, X., Hua, W., Yang, D., Hu, J., Yue, Y., and Gao, Z.: Poly(styrene sulfonic acid)–grafted carbon nanotube as a stable protonic acid catalyst. Catal. Commun. 12, 217 (2010).CrossRefGoogle Scholar
Zhao, Y., Wang, H., Zhao, Y., and Shen, J.: Preparation of a novel sulfonated carbon catalyst for the etherification of isopentene with methanol to produce tert-amyl methyl ether. Catal. Commun. 11, 824 (2010).CrossRefGoogle Scholar
Du, Y., Li, C., Sun, X., Liang, X., and Qi, C.: Synthesis of a novel polythiourethane-based acid and its catalytic activity. Asia-Pac. J. Chem. Eng. 6, 933 (2011).CrossRefGoogle Scholar
Hara, M.: Biomass conversion by a solid acid catalyst. Energy Environ. Sci. 3, 601 (2010).CrossRefGoogle Scholar
Hou, K., Zhang, A., Gu, L., Liu, M., and Guo, X.: Efficient synthesis and sulfonation of ordered mesoporous carbon materials. J. Colloid Interface Sci. 377, 18 (2012).CrossRefGoogle ScholarPubMed
Peng, L., Philippaerts, A., Ke, X., Van Noyen, J., De Clippel, F., Van Tendeloo, G., Jacobs, P.A., and Sels, B.F.: Preparation of sulfonated ordered mesoporous carbon and its use for the esterification of fatty acids. Catal. Today 150, 140 (2010).CrossRefGoogle Scholar
Sharifi, M., Wark, M., Freude, D., and Haase, J.: Highly proton conducting sulfonic acid functionalized mesoporous materials studied by impedance spectroscopy, MAS NMR spectroscopy and MAS PFG NMR diffusometry. Microporous Mesoporous Mater. 156, 80 (2012).CrossRefGoogle Scholar
Fraile, J.M., Garcia-Bordeje, E., and Roldan, L.: Deactivation of sulfonated hydrothermal carbons in the presence of alcohols: Evidences for sulfonic esters formation. J. Catal. 289, 73 (2012).CrossRefGoogle Scholar
Liu, F., Sun, J., Zhu, L., Meng, X., Qi, C. and Xiao, F.: Sulfated graphene as an efficient solid catalyst for acid-catalyzed liquid reactions. J. Mater. Chem. 22, 5495 (2012).CrossRefGoogle Scholar
Nakajima, K., Tomita, I., Hara, M., Hayashi, S., Domen, K., and Kondo, J.N.: A stable and highly active hybrid mesoporous solid acid catalyst. Adv. Mater. 17, 1839 (2005).CrossRefGoogle Scholar
Kiss, A.A., Dimian, A.C., and Rothenberg, G.: Solid acid catalysts for biodiesel production–towards sustainable energy. Adv. Synth. Catal. 348, 75 (2006).CrossRefGoogle Scholar
Okuhara, T.: Design and preparation of organic−inorganic hybrid catalysts. Chem. Rev. 102, 3641 (2002).CrossRefGoogle Scholar
Harmer, M.A., Farneth, W.E., and Sun, Q.: Towards the sulfuric acid of solids. Adv. Mater. 10, 1255 (1998).3.0.CO;2-T>CrossRefGoogle Scholar
Kitano, M., Arai, K., Kodama, A., Kousaka, T., Nakajima, K., Hayashi, S., and Hara, M.: Preparation of a sulfonated porous carbon catalyst with high specific surface area. Catal. Lett. 131, 242 (2009).CrossRefGoogle Scholar
Yu, H., Jin, Y., Li, Z., Peng, F., and Wang, H.: Synthesis and characterization of sulfonated single-walled carbon nanotubes and their performance as solid acid catalyst. J. Solid State Chem. 181, 432 (2008).CrossRefGoogle Scholar
Wang, X., Liu, R., Waje, M.M., Chen, Z., Yan, Y., Bozhilov, K.N., and Feng, P.: Sulfonated ordered mesoporous carbon as a stable and highly active protonic acid catalyst. Chem. Mater. 19, 2395 (2007).CrossRefGoogle Scholar
Ma, N., Yang, Y., Chen, S., and Zhang, Q.: Preparation of amine group-containing chelating fiber for thorough removal of mercury ions. J. Hazard. Mater. 171, 288 (2009).CrossRefGoogle ScholarPubMed
Zhang, C., Zhu, F., Wang, Z., Meng, L., and Liu, Y.: Amino functionalization of multiwalled carbon nanotubes by gamma ray irradiation and its epoxy composites. Polym. Compos. 33, 267 (2012).CrossRefGoogle Scholar
Zhao, F. and Huang, Y.. Uniform modification of carbon fibers in high density fabric by γ-ray irradiation grafting. Mater. Lett. 65, 3351 (2011).CrossRefGoogle Scholar
Roldán, L., Santos, I., Armenise, S., Fraile, J.M., and García-Bordeje, E.: The formation of a hydrothermal carbon coating on graphite microfiber felts for using as structured acid catalyst. Carbon 50, 1363 (2012).CrossRefGoogle Scholar
Tian, X., Zhang, L., Bai, P., and Zhao, X.S.: Sulfonic-acid-functionalized porous benzene phenol polymer and carbon for catalytic esterification of methanol with acetic acid. Catal. Today 166, 53 (2011).CrossRefGoogle Scholar
Zhang, S., Zhang, Q., Chen, S., Yuan, Q., and Li, P.: Irradiation-induced grafting of acrylonitrile onto activated carbon fiber. Polym. Adv. Technol. 20, 1 (2009).CrossRefGoogle Scholar
Liu, P.: Facile graft polystyrene onto multi-walled carbon nanotubes via in situ thermo-induced radical polymerization. J. Nanopart. Res. 11, 1011 (2009).CrossRefGoogle Scholar
Jung, C., Kim, D., and Choi, J.: Surface modification of multi-walled carbon nanotubes by radiation-induced graft polymerization. Curr. Appl. Phys. 11, s85 (2009).CrossRefGoogle Scholar