Hostname: page-component-cd9895bd7-jn8rn Total loading time: 0 Render date: 2024-12-29T05:22:38.572Z Has data issue: false hasContentIssue false
  • English
  • Français

Preparation and characterization of Ag/AgO nanoshells on carboxylated polystyrene latex particles

Published online by Cambridge University Press:  01 February 2006

Rongwei Zhang ,
Dan Zhang ,
Hui Mao ,
Wenlong Song ,
Ge Gao  and
Fengqi Liu
Rongwei Zhang
Affiliation:
College of Chemistry, Jilin University, Changchun 130023, People’s Republic of China
Dan Zhang
Affiliation:
College of Chemistry, Jilin University, Changchun 130023, People’s Republic of China
Hui Mao
Affiliation:
College of Chemistry, Jilin University, Changchun 130023, People’s Republic of China
Wenlong Song
Affiliation:
College of Chemistry, Jilin University, Changchun 130023, People’s Republic of China
Ge Gao
Affiliation:
College of Chemistry, Jilin University, Changchun 130023, People’s Republic of China
Fengqi Liu*
Affiliation:
College of Chemistry, Jilin University, Changchun 130023, People’s Republic of China
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

Smooth and uniform Ag/AgO nanoshells (about 3–4 nm) on carboxylated polystyrene latex particles were prepared by electrostatic attraction between negatively charged –COO− on the surface of carboxylated polystyrene latex particles and positively charged Ag(NH3)2+ in the solution, and subsequent decomposition of the silver complex. The resultant nanoparticles were characterized with Fourier transform infrared, transmission electron microscopy, scanning electron microscopy, and x-ray diffraction. The effects of reducing agents, the amount of NaOH and temperature on the morphology of hybrid latex particles were discussed.

Keywords

CompositeDepositionNanoparticle
Type
Articles
Information
Journal of Materials Research , Volume 21 , Issue 2 , February 2006 , pp. 349 - 354
Copyright
Copyright © Materials Research Society 2006

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Dong, A.G., Wang, Y.J., Tang, Y., Ren, N., Yang, W.L. and Gao, Z.: Fabrication of compact silver nanoshells on polystyrene spheres through electrostatic attraction. Chem. Commun. 350 (2002).CrossRefGoogle ScholarPubMed
2.Mayer, A.B.R., Grebner, W. and Wannemacher, R.: Preparation of silver–latex composites. J. Phys. Chem. B 104, 7278 (2000).CrossRefGoogle Scholar
3.Burke, N.A.D., Stöver, H.D.H. and Dawson, F.P.: Magnetic nanocomposites: Preparation and characterization of polymer-coated iron nanoparticles. Chem. Mater. 14, 4752 (2002).CrossRefGoogle Scholar
4.Ji, T.H., Lirtsman, V.G., Avny, Y. and Davidov, D.: Preparation, characterization and application of Au-shell/polystyrene beads and Au-shell/magnetic beads. Adv. Mater. 13, 1253 (2001).3.0.CO;2-T>CrossRefGoogle Scholar
5.Quaroni, L. and Chumanov, G.: Preparation of polymer-coated functionalized silver nanoparticles. J. Am. Chem. Soc. 121, 10642 (1999).CrossRefGoogle Scholar
6.Dokoutchaev, A., James, J.T., Koene, S.C., Pathak, S., Prakash, G.K.S. and Thompson, M.E.: Colloidal metal deposition onto functionalized polystyrene microspheres. Chem. Mater. 13, 2389 (1999).CrossRefGoogle Scholar
7.Zhao, M.Q. and Crooks, R.M.: Dendrimer-encapsulated Pt nanoparticles: Synthesis, characterization, and application to catalysis. Adv. Mater. 11, 217 (1999).Google Scholar
8.Rong, M.Z., Zhang, M.Q., Liu, H. and Zeng, H.M.: Synthesis of silver nanoparticles and their self-organization behavior in epoxy rezin. Polymer 40, 6169 (1999).CrossRefGoogle Scholar
9.Son, W.K., Youk, J.H., Lee, T.S. and Park, W.H.: Preparation of antimicrobial ultrafine cellulose acetate fibers with silver nanoparticles. Macromol. Rapid Commun. 25, 1632 (2004).CrossRefGoogle Scholar
10.Zhang, J.H., Wang, S.Z., Liu, J.B., Wang, Z.L. and Ming, N.B.: Preparation and absorption of polystyrene/Ag/TiO2 multiple coated colloids. J. Mater. Res. 20, 965 (2005).CrossRefGoogle Scholar
11.Shiraishi, Y. and Toshima, N.: Colloidal silver catalysts for oxidation of ethylene. J. Mol. Catal. A: Chem. 141, 187 (1999).CrossRefGoogle Scholar
12.Warshamsky, A. and Upson, D.A.: Zerovalent metal polymer composites. I. Metallized beads. J. Polym. Sci., Part A: Polym. Chem. 27, 2963 (1989).CrossRefGoogle Scholar
13.Tamai, H., Sakurai, H., Hirota, Y., Nishiyama, F. and Yasuda, H.: Preparation and characteristics of ultrafine metal particles immobilized on fine polymer particles. J. Appl. Polym. Sci. 56, 441 (1995).CrossRefGoogle Scholar
14.Moody, R.L., Vo-Dihn, T. and Fletcher, W.H.: Formation of silver nanoshells on latex spheres. Appl. Spectrosc. 41, 966 (1987).CrossRefGoogle Scholar
15.Jackson, J.B. and Halas, N.J.: Silver nanoshells: Variation in morphoragies and optical properties. J. Phys. Chem. B 105, 2743 (2001).CrossRefGoogle Scholar
16.Kocareva, T., Grozdanov, I. and Pejova, B.: Ag and AgO thin film formation in Ag+-triethanolamine solutions. Mater. Lett. 47, 319 (2001).CrossRefGoogle Scholar
17.Wang, P.H. and Pan, C.Y.: Ultrafine palladium particles immobilized on polymer microspheres. Colloid Polym. Sci. 279, 171 (2001).CrossRefGoogle Scholar
18.Sadtler, B. and Wei, A.: Spherical ensembles of gold nanoparticles on silica: Electrostatic and size effects. Chem. Commun. 1604 (2002).CrossRefGoogle ScholarPubMed
19.Jing, L.Q., Sun, X.J., Xin, B.F., Wang, B.Q., Cai, W.M. and Fu, H.G.: The preparation and characterization of La doped TiO2 nanoparticles and their photocatalytic activity. J. Solid State Chem. 17, 3375 (2004).Google Scholar
20.Zhang, Z.P., Zhang, L.D., Wang, S.X., Chen, W. and Li, Y.: A convenient route to polyacrylonitrile/silver nanoparticle composite by simultaneous polymerization-reduction approach. Polymer 42, 8315 (2001).CrossRefGoogle Scholar
21.Waterhouse, G.I.N., Bowmaker, G.A. and Metson, J.B.: The thermal decomposition of silver (I, III) oxide: A combined XRD, FTIR, and Raman spectroscopic. Phys. Chem. Chem. Phys. 3, 3838 (2001).CrossRefGoogle Scholar
22.Fergus, J.W., Mallipedi, C.V.S. and Edwards, D.L.: Silver/silver-oxide composite coating for intrinsically adaptive thermal regulation. Composites Part B 29B, 51 (1998).CrossRefGoogle Scholar