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Preliminary investigation on the catalytic mechanism of TiF3 additive in MgH2–TiF3 H-storage system

Published online by Cambridge University Press:  31 January 2011

Lai-Peng Ma ,
Ping Wang ,
Xiang-Dong Kang  and
Hui-Ming Cheng
Lai-Peng Ma
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, People’s Republic of China
Ping Wang*
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, People’s Republic of China
Xiang-Dong Kang
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, People’s Republic of China
Hui-Ming Cheng
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, People’s Republic of China
*
a) Address all correspondence to this author. e-mail: [email protected]
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Abstract

A combined structure/property investigation is performed to understand the catalytic effect of TiF3 additive on the absorption/desorption reactions of MgH2. It was found that both TiH2 and MgF2 phases identified by x-ray diffraction cannot explain the observed kinetic enhancement in the MgH2–TiF3 system, whether they are incorporated in a direct or an in situ manner. In combination with the comparative investigation on the catalytic activity of TiF3 and its analog TiCl3, as well as the samples milled under inert and reactive atmospheres, we propose that the catalytically active species is a multicomponent metastable phase composed of host Mg, transition metal Ti, and F anion, the catalytic activity of which is dependent on its interaction with the surrounding chemical environment.

Keywords

CatalyticEnergy-storageMg
Type
Articles
Information
Journal of Materials Research , Volume 22 , Issue 7 , July 2007 , pp. 1779 - 1786
Copyright
Copyright © Materials Research Society 2007

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