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Oxidation kinetics of Pb–Sn alloys

Published online by Cambridge University Press:  31 January 2011

R. A. Konetzki ,
Y. A. Chang  and
V. C. Marcotte
R. A. Konetzki
Affiliation:
Department of Materials Science and Engineering, University of Wisconsin–Madison, Madison, Wisconsin 53706
Y. A. Chang
Affiliation:
Department of Materials Science and Engineering, University of Wisconsin–Madison, Madison, Wisconsin 53706
V. C. Marcotte
Affiliation:
IBM General Technology Division, East Fishkill Facility, Hopewell Junction. New York 12533
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Abstract

The solid state oxidation kinetics of Pb–Sn single-phase (2.5 at. % Sn) and eutectic alloys were studied with Auger Electron Spectroscopy combined with sputter depth profiling. The single-phase samples were oxidized in air in the temperature range 22 °C to 250 °C, while the eutectic samples were oxidized from 22 °C to 175 °C. Both alloys oxidize logarithmically between 22 °C and 90 °C and parabolically at temperatures greater than 120 °C. The activation energies for the parabolic oxidation of the single-phase and eutectic alloys are 69.5 and 67.1 ± 8 kJ/mole, respectively.

Type
Articles
Information
Journal of Materials Research , Volume 4 , Issue 6 , December 1989 , pp. 1421 - 1426
Copyright
Copyright © Materials Research Society 1989

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