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Origin of cristobalite formation during sintering of a binary mixture of borosilicate glass and high silica glass

Published online by Cambridge University Press:  03 March 2011

Tapan K. Gupta
Affiliation:
Alcoa Technical Center, Alcoa Center, Pennsylvania 15069–0001
Jau-Ho Jean
Affiliation:
Alcoa Electronic Packaging, Inc., San Diego, California 92127
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Abstract

It was shown previously1 that cristobalite precipitates out of a mixture of borosilicate glass (BSG) and high silica glass (HSG) when sintered at temperatures ranging from 800 to 1200 °C. In this paper, both direct and indirect evidences are presented to conclude that the formation of cristobalite originates in HSG. It is proposed that the cristobalite is formed as a result of dissolution of HSG in BSG and precipitation at heterogeneously nucleated sites. The process of dissolution and precipitation continues until the whole HSG particle is consumed.

Type
Articles
Copyright
Copyright © Materials Research Society 1994

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References

REFERENCES

1Jean, J-H. and Gupta, T. K., J. Mater. Res. 7, 3103 (1992).CrossRefGoogle Scholar
2Kingery, W. D., Bowen, H. K., and Uhlmann, D. R., Introduction to Ceramics, 2nd ed. (John Wiley and Sons, New York, 1976), Chaps. 9 and 12.Google Scholar
3Ainslie, N. G., Morelock, C. R., and Turnbull, G., in Symposium on Nucleation and Crystallization in Glasses and Melts (The American Ceramics Society, Westerville, OH, 1962), p. 97.Google Scholar
4Turner, J., J. Res. Natl. Bur. Stand. 37, 239 (1956).CrossRefGoogle Scholar
5Doerner, P., Gauckler, L. J., Krieg, H., Lukas, H. L., Petzow, G., and Weiss, J., CALPHAD: Comput. Coupling Phase Diagrams Thermochem. 3, 241 (1979).CrossRefGoogle Scholar
6Sosman, R. B., Phases of Sio2 (Rutgers University Press, New Brunswick, NJ, 1965), pp. 121147.Google Scholar
7Grimshaw, R. W. and Roberts, A. L., Trans. Br. Ceramic Society 52, 5067 (1953).Google Scholar
8Grimshaw, R. W., Hargreaves, J., and Roberts, A. L., Trans. Br. Ceramic Society 55, 3656 (1956).Google Scholar
9Roberts, A. L., in Kinetics of High Temperature Processes, edited by Kingery, W. D. (MIT, Cambridge, MA, 1959), pp. 222227.Google Scholar
10Hill, V. G. and Roy, R., Trans. Br. Ceramic Society 57, 496510 (1958).Google Scholar