Hostname: page-component-586b7cd67f-vdxz6 Total loading time: 0 Render date: 2024-11-23T02:43:14.048Z Has data issue: false hasContentIssue false
  • English
  • Français

A novel stable solid formed by C60 + oxygen at high P(O2)

Published online by Cambridge University Press:  03 March 2011

D.E. Morris ,
K.K. Singh  and
A.P.B. Sinha
D.E. Morris
Affiliation:
Morris Research Inc., 1918 University Avenue, Berkeley, California 94704
K.K. Singh
Affiliation:
Morris Research Inc., 1918 University Avenue, Berkeley, California 94704
A.P.B. Sinha
Affiliation:
Morris Research Inc., 1918 University Avenue, Berkeley, California 94704
Get access

Abstract

We report the formation of a novel solid form of carbon + oxygen. Exposure of C60 to high oxygen pressure [P(O2) ≍ 100 MPa] for several days at slightly above ambient temperature results in absorption of significant amounts of oxygen (up to ∼48% by weight after 3 days). X-ray diffraction measurements showed that the C60 pellets had become amorphous. Although part of the added weight is slowly lost in flowing oxygen at ambient pressure and temperature, most remains up to at least 100 °C. Heating in flowing He at 200 °C brought the weight back to near the original value. The reaction appears to be specific to C60 since the amorphous outgassed material had lost the capacity to absorb oxygen at high P(O2), and the oxygen absorption effect was absent in powdered graphite and in commercial amorphous carbon. The Raman spectrum differs from those of C60, soot, amorphous carbon, graphite, and diamond.

Type
Articles
Information
Journal of Materials Research , Volume 8 , Issue 9 , September 1993 , pp. 2273 - 2276
Copyright
Copyright © Materials Research Society 1993

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1Arbogast, J. W., Darmanyan, A. P., Foote, C. S., Rubin, Y., Diedrich, F. N., Alvarez, M. M., Anz, S. J., and Whetten, R. L., J. Phys. Chem. 95, 11 (1991).CrossRefGoogle Scholar
2Kroll, G. H., Benning, P. J., Chen, Y., Ohno, T. R., Weaver, J. H., Chibante, L. P. F., and Smalley, R.E., Chem. Phys. Lett. 181, 112 (1991).CrossRefGoogle Scholar
3Vijayakrishnan, V., Santra, A. K., Pradeep, T., Nagarajan, R., and Rao, C. N. R., J. Chem. Soc, Chem. Commun. 198 (1992).CrossRefGoogle Scholar
4Schirber, J. E., Assink, R. A., Loy, D., and Morosin, B., Bull. Am. Phys. Soc. 37, 400 (1992).Google Scholar
5Morris Research Inc., 1918 University Ave., Berkeley, CA 94704, Model HPS-5010.Google Scholar
6Although the evolved gas has not been analyzed, it is unlikely that the bound oxygen would be lost in the form of CO or CO2 at room temperature.Google Scholar
7Creegan, K. M., Robbins, J. L., Robbins, W. K., Millar, J. M., Sherwood, R. D., Tindall, P. J., Cox, D. M., Smith, A. B. III, McCauley, J. P. Jr., Jones, D. R., and Gallagher, R. T., J. Am. Chem. Soc. 114, 1103 (1992).CrossRefGoogle Scholar