Hostname: page-component-cd9895bd7-7cvxr Total loading time: 0 Render date: 2024-12-23T12:25:27.145Z Has data issue: false hasContentIssue false
  • English
  • Français

Novel approach for the synthesis of Mg(OH)2 nanosheets and lamellar MgO nanostructures and their ultra-high adsorption capacity for Congo red

Published online by Cambridge University Press:  11 May 2015

Xueming Liu ,
Chunge Niu ,
Xinping Zhen ,
Jide Wang  and
Xintai Su
Xueming Liu
Affiliation:
Ministry Key Laboratory of Oil and Gas Fine Chemicals, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China
Chunge Niu
Affiliation:
Petrochemical Research Institute, Karamay Petrochemical Company, Karamay, Xinjiang 83400, China
Xinping Zhen
Affiliation:
Petrochemical Research Institute, Karamay Petrochemical Company, Karamay, Xinjiang 83400, China
Jide Wang
Affiliation:
Ministry Key Laboratory of Oil and Gas Fine Chemicals, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China
Xintai Su*
Affiliation:
Ministry Key Laboratory of Oil and Gas Fine Chemicals, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

A phase transfer method was developed to prepare Mg(OH)2 nanosheets and a subsequent adsorption–calcination process was followed to obtain lamellar MgO nanostructures. The as-prepared MgO nanosheets also showed a superior adsorption property of Congo red. Transmission electron microscopy and x-ray diffractometer results indicated that the as-obtained Mg(OH)2 was plate-shaped with a hexagonal crystal structure where MgO possessed a lamellar structure with a cubic phase. The maximum adsorption capacities of Mg(OH)2 and MgO were reached up to 1820 and 2650 mg g−1, respectively. The high adsorption capacity might be related to the particle geometry and large surface area (87.97 m2 g−1 for Mg(OH)2 and 132.31 m2 g−1 for MgO). The adsorbents can be easily regenerated for five times without any significant loss in their adsorption property. The adsorption behaviors of the Mg(OH)2 and MgO adsorbents showed that the adsorption kinetics and isotherms were in good agreement with pseudo-second-order rate equation and Freundlich adsorption model.

Keywords

phase transformationnanostructureadsorption
Type
Articles
Information
Journal of Materials Research , Volume 30 , Issue 10 , 28 May 2015 , pp. 1639 - 1647
Copyright
Copyright © Materials Research Society 2015 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Shter, G.E., Behar‐Levy, H., Gelman, V., Grader, G.S., and Avnir, D.: Organically doped metals—A new approach to metal catalysis: Enhanced Ag‐catalyzed oxidation of methanol. Adv. Funct. Mater. 17(6), 913 (2007).Google Scholar
Ahmad, R. and Kumar, R.: Adsorptive removal of Congo red dye from aqueous solution using bael shell carbon. Appl. Surf. Sci. 257(5), 1628 (2010).Google Scholar
Zou, G., Chen, W., Liu, R., and Xu, Z.: Morphology-tunable synthesis and characterizations of Mg(OH)2 films via a cathodic electrochemical process. Mater. Chem. Phys. 107(1), 85 (2008).Google Scholar
Liakos, T.I. and Lazaridis, N.K.: Melanoidins removal from simulated and real wastewaters by coagulation and electro-flotation. Chem. Eng. J. 242, 269 (2014).Google Scholar
Turhan, K., Durukan, I., Ozturkcan, S.A., and Turgut, Z.: Decolorization of textile basic dye in aqueous solution by ozone. Dyes Pigm. 92(3), 897 (2012).Google Scholar
Yu, S., Liu, M., Ma, M., Qi, M., Lü, Z., and Gao, C.: Impacts of membrane properties on reactive dye removal from dye/salt mixtures by asymmetric cellulose acetate and composite polyamide nanofiltration membranes. J. Membr. Sci. 350(1–2), 83 (2010).Google Scholar
Gao, X., Xiao, F., Yang, C., Wang, J., and Su, X.: Hydrothermal fabrication of W18O49 nanowire networks with superior performance for water treatment. J. Mater. Chem. A 1, 5831 (2013).CrossRefGoogle Scholar
Hao, T., Yang, C., Rao, X., Wang, J., Niu, C., and Su, X.: Facile additive-free synthesis of iron oxide nanoparticles for efficient adsorptive removal of Congo red and Cr (VI). Appl. Surf. Sci. 292, 174 (2013).Google Scholar
Wang, B., Wu, H., Yu, L., Xu, R., and Lim, T.T.: Template-free formation of uniform urchin-like a-FeOOH hollow spheres with superior capability for water treatment. Adv. Mater. 24(8), 1111 (2012).Google Scholar
Cheng, B., Le, Y., Cai, W., and Yu, J.: Synthesis of hierarchical Ni(OH)2 and NiO nanosheets and their adsorption kinetics and isotherms to Congo red in water. J. Hazard. Mater. 185(2–3), 889 (2011).Google Scholar
Kumari, L., Li, W.Z., Vannoy, C.H., Leblanc, R.M., and Wang, D.Z.: Synthesis, characterization and optical properties of Mg(OH)2 micro-/nanostructure and its conversion to MgO. Ceram. Int. 35(8), 3355 (2009).Google Scholar
Hu, J., Song, Z., Chen, L., Yang, H., Li, J., and Richards, R.: Adsorption properties of MgO (111) nanoplates for the dye pollutants from wastewater. J. Chem. Eng. Data 55(9), 3742 (2010).Google Scholar
Todan, L., Dascalescu, T., Preda, S., Andronescu, C., Munteanu, C., Culita, D.C., Rusu, A., State, R., and Zaharescu, M.: Porous nanosized oxide powders in the MgO-TiO2 binary system obtained by sol–gel method. Ceram. Int. 40(10), 15693 (2014).Google Scholar
Bouberka, Z., Bentaleb, K., Benabbou, K.A., and Maschke, U.: Adsorption of two dyes by Mg(OH)2: Procion blue HB and Remazol brilliant blue R. Springer Proc. Phys. 155, 463 (2014).Google Scholar
Nga, N.K., Hong, P.T., Lam, T.D., and Huy, T.Q.: A facile synthesis of nanostructured magnesium oxide particles for enhanced adsorption performance in reactive blue 19 removal. J. Colloid Interface Sci. 398, 210 (2013).Google Scholar
Cao, C.Y., Qu, J., Wei, F., Liu, H., and Song, W.G.: Superb adsorption capacity and mechanism of flowerlike magnesium oxide nanostructures for lead and cadmium ions. ACS Appl. Mater. Interfaces 4(8), 4283 (2012).Google Scholar
Li, Y., Yang, C., Ge, J., Sun, C., Wang, J., and Su, X.: A general microwave-assisted two-phase strategy for nanocrystals synthesis. J. Colloid Interface Sci. 407, 296 (2013).CrossRefGoogle ScholarPubMed
Giauque, W.F. and Archibald, R.C.: The entropy of water from the third law of thermodynamics. The dissociation pressure and calorimetric heat of the reaction Mg(OH)2 = MgO + H2O. the heat capacities of Mg(OH)2 and MgO from 20 to 300°K. J. Am. Chem. Soc. 59(3), 561 (1937).Google Scholar
Zhang, S., Deng, C., Liu, F.L., Wu, Q., Zhang, M., Meng, F.L., and Gao, H.: Impacts of in situ carbon coating on the structural, morphological and electrochemical characteristics of Li2MnSiO4 prepared by a citric acid assisted sol–gel method. J. Electroanal. Chem. 689, 88 (2013).Google Scholar
Selvam, N.C.S., Kumar, R.T., Kennedy, L.J., and Vijaya, J.J.: Comparative study of microwave and conventional methods for the preparation and optical properties of novel MgO-micro and nano-structures. J. Alloys Compd. 509(41), 9809 (2011).Google Scholar
Alavi, M.A. and Morsali, A.: Syntheses and characterization of Mg(OH)2 and MgO nanostructures by ultrasonic method. Ultrason. Sonochem. 17(2), 441 (2010).Google Scholar
Yu, X-Y., Luo, T., Jia, Y., Zhang, Y-X., Liu, J-H., and Huang, X-J.: Porous hierarchically micro-/nanostructured MgO: Morphology control and their excellent performance in As (III) and As (V) removal. J. Phys. Chem. C 115(45), 22242 (2011).Google Scholar
Rezaei, M., Khajenoori, M., and Nematollahi, B.: Synthesis of high surface area nanocrystalline MgO by pluronic P123 triblock copolymer surfactant. Powder Technol. 205(1–3), 112 (2011).Google Scholar
Ai, L., Yue, H., and Jiang, J.: Sacrificial template-directed synthesis of mesoporous manganese oxide architectures with superior performance for organic dye adsorption. Nanoscale 4(17), 5401 (2012).CrossRefGoogle Scholar
Dong, H., Du, Z., Zhao, Y., and Zhou, D.: Preparation of surface modified nano-Mg(OH)2 via precipitation method. Powder Technol. 198(3), 325 (2010).Google Scholar
Ruminski, A.M., Jeon, K-J., and Urban, J.J.: Size-dependent CO2 capture in chemically synthesized magnesium oxide nanocrystals. J. Mater. Chem. 21(31), 11486 (2011).Google Scholar
Li, X., Xiao, W., He, G., Zheng, W., Yu, N., and Tan, M.: Pore size and surface area control of MgO nanostructures using a surfactant-templated hydrothermal process: High adsorption capability to azo dyes. Colloids Surf., A 408, 79 (2012).CrossRefGoogle Scholar
Tian, P., Han, X.Y., Ning, G.L., Fang, H.X., Ye, J.W., Gong, W.T., and Lin, Y.: Synthesis of porous hierarchical MgO and its superb adsorption properties. ACS Appl. Mater. Interfaces 5(23), 12411 (2013).CrossRefGoogle ScholarPubMed
Huang, J., Chen, W., Zhao, W., Li, Y., Li, X., and Chen, C.: One-dimensional chainlike arrays of Fe3O4 hollow nanospheres synthesized by aging iron nanoparticles in aqueous solution. J. Phys. Chem. C 113(28), 12067 (2009).Google Scholar
Wang, L., Li, J., Wang, Z., Zhao, L., and Jiang, Q.: Low-temperature hydrothermal synthesis of α-Fe/Fe3O4 nanocomposite for fast Congo red removal. Dalton Trans. 42(7), 2572 (2013).CrossRefGoogle ScholarPubMed
Zhu, T., Chen, J.S., and Lou, X.W.: Highly efficient removal of organic dyes from waste water using hierarchical NiO spheres with high surface area. J. Phys. Chem. C 116(12), 6873 (2012).Google Scholar
Zhang, Z., Shan, Y., Wang, J., Ling, H., Zang, S., Gao, W., Zhao, Z., and Zhang, H.: Investigation on the rapid degradation of Congo red catalyzed by activated carbon powder under microwave irradiation. J. Hazard. Mater. 147(1), 325 (2007).Google Scholar
Cai, W., Yu, J., and Jaroniec, M.: Template-free synthesis of hierarchical spindle-like γ-Al2O3 materials and their adsorption affinity towards organic and inorganic pollutants in water. J. Mater. Chem. 20(22), 4587 (2010).Google Scholar
Chong, K.Y., Chia, C.H., Zakaria, S., and Sajab, M.S.: Vaterite calcium carbonate for the adsorption of Congo red from aqueous solutions. J. Environ. Chem. Eng. 2(4), 2156 (2014).Google Scholar