Hostname: page-component-586b7cd67f-t7czq Total loading time: 0 Render date: 2024-11-23T01:08:37.377Z Has data issue: false hasContentIssue false
  • English
  • Français

Nitrogen-doped ordered mesoporous carbon using task-specific ionic liquid as a dopant for high-performance supercapacitors

Published online by Cambridge University Press:  05 January 2017

Jie Zhou ,
Li Bao ,
Shengji Wu ,
Wei Yang  and
Hui Wang
Jie Zhou*
Affiliation:
College of Materials and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, China
Li Bao
Affiliation:
College of Materials and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, China
Shengji Wu
Affiliation:
College of Materials and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, China
Wei Yang
Affiliation:
College of Materials and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, China
Hui Wang
Affiliation:
College of Materials and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, China
*
a) Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

Ordered mesoporous carbons (OMCs) are appealing alternatives to conventional porous activated carbon applied to electronic energy storage and conversion devices. Nitrogen-doped OMC (NOMC) was prepared with a soft-template strategy directly using task-specific ionic liquid with dicyanamide anion as the nitrogen dopant, and utilized as supercapacitors for the first time. Compared with pristine OMC, NOMC showed excellent electrochemical capacitive behavior in 6 M KOH electrolyte. NOMC possessed a high specific capacitance of 427 F/g at a current density of 1 A/g and exhibited a stable cycle life (almost 98% retained at a current density of 5 A/g after 2000 cycles). The outstanding capacitive performance of NOMC was ascribed to the synergetic effects of its bimodal mesoporous structure, large specific surface area (1919 m2/g), and nitrogen doping (3.52 wt%), which help to accelerate the ion diffusion, increase the surface charge storage, and intensify pseudo-capacitive reactions.

Keywords

nitrogen-doped ordered mesoporous carbontask-specific ionic liquidsoft-template methodsupercapacitor
Type
Articles
Information
Journal of Materials Research , Volume 32 , Issue 2 , 27 January 2017 , pp. 404 - 413
Check for updates
Copyright
Copyright © Materials Research Society 2017 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Simon, P. and Gogotsi, Y.: Materials for electrochemical capacitors. Nat. Mater. 7(11), 845 (2008).Google Scholar
Zhang, L.L. and Zhao, X.S.: Carbon-based materials as supercapacitor electrodes. Chem. Soc. Rev. 38(9), 2520 (2009).Google Scholar
Elmouwahidi, A., Zapata-Benabithe, Z., Carrasco-Marin, F., and Moreno-Castilla, C.: Activated carbons from KOH-activation of argan (Argania spinosa) seed shells as supercapacitor electrodes. Bioresour. Technol. 111, 185 (2012).Google Scholar
Zhang, D., Hao, Y., Zheng, L., Ma, Y., Feng, H., and Luo, H.: Nitrogen and sulfur co-doped ordered mesoporous carbon with enhanced electrochemical capacitance performance. J. Mater. Chem. A 1(26), 7584 (2013).Google Scholar
Ryoo, R., Joo, S.H., Kruk, M., and Jaroniec, M.: Ordered mesoporous carbons. Adv. Mater. 13(9), 677 (2001).Google Scholar
Zhai, Y., Dou, Y., Zhao, D., Fulvio, P.F., Mayes, R.T., and Dai, S.: Carbon materials for chemical capacitive energy storage. Adv. Mater. 23(42), 4828 (2011).Google Scholar
Gnanakan, S.R.P., Karthikeyan, K., Amaresh, S., Cho, S.J., Park, G.J., and Lee, Y.S.: New application and electrochemical characterization of a nickel-doped mesoporous carbon for supercapacitors. J. Alloys Compd. 509(41), 9858 (2011).CrossRefGoogle Scholar
Xiong, W., Liu, M., Gan, L., Lv, Y., Li, Y., Yang, L., Xu, Z., Hao, Z., Liu, H., and Chen, L.: A novel synthesis of mesoporous carbon microspheres for supercapacitor electrodes. J. Power Sources 196(23), 10461 (2011).CrossRefGoogle Scholar
Xu, J.X., Zhao, Y., Shen, C., and Guan, L.H.: Sulfur- and nitrogen-doped, ferrocene-derived mesoporous carbons with efficient electrochemical reduction of oxygen. ACS Appl. Mater. Interfaces 5(23), 12594 (2013).Google Scholar
Guo, H. and Gao, Q.: Boron and nitrogen co-doped porous carbon and its enhanced properties as supercapacitor. J. Power Sources 186(2), 551 (2009).Google Scholar
Zhou, T., Wang, H., Key, J., Ji, S., Linkov, V., and Wang, R.: Highly dispersed ultrafine Pt nanoparticles on hydrophilic N-doped carbon tubes for improved methanol oxidation. RSC Adv. 3(38), 16949 (2013).Google Scholar
Goscianska, J., Olejnik, A., and Pietrzak, R.: Adsorption of L-phenylalanine on ordered mesoporous carbons prepared by hard template method. J. Taiwan Inst. Chem. Eng. 45(2), 347 (2014).Google Scholar
Xia, Y.D. and Mokaya, R.: Synthesis of ordered mesoporous carbon and nitrogen-doped carbon materials with graphitic pore walls via a simple chemical vapor deposition method. Adv. Mater. 16(17), 1553 (2004).Google Scholar
Liu, J., Yang, T.Y., Wang, D.W., Lu, G.Q.M., Zhao, D.Y., and Qiao, S.Z.: A facile soft-template synthesis of mesoporous polymeric and carbonaceous nanospheres. Nat. Commun. 4(1), 94 (2013).Google Scholar
Zhai, Y.P., Dou, Y.Q., Liu, X.X., Park, S.S., Ha, C.S., and Zhao, D.Y.: Soft-template synthesis of ordered mesoporous carbon/nanoparticle nickel composites with a high surface area. Carbon 49(2), 545 (2011).Google Scholar
Vinu, A.: Two-dimensional hexagonally-ordered mesoporous carbon nitrides with tunable pore diameter, surface area and nitrogen content. Adv. Funct. Mater. 18(5), 816 (2008).Google Scholar
Chen, H., Zhou, M., Wang, Z., Zhao, S.Y., and Guan, S.Y.: Rich nitrogen-doped ordered mesoporous phenolic resin-based carbon for supercapacitors. Electrochim. Acta 148, 187 (2014).Google Scholar
Yu, J., Guo, M., Muhammad, F., Wang, A., Zhang, F., Li, Q., and Zhu, G.: One-pot synthesis of highly ordered nitrogen-containing mesoporous carbon with resorcinol-urea-formaldehyde resin for CO2 capture. Carbon 69, 502 (2014).Google Scholar
Lu, A., Kiefer, A., Schmidt, W., and Schüth, F.: Synthesis of polyacrylonitrile-based ordered mesoporous carbon with tunable pore structures. Chem. Mater. 16(1), 100 (2004).Google Scholar
Wei, J., Zhou, D., Sun, Z., Deng, Y., Xia, Y., and Zhao, D.: A controllable synthesis of rich nitrogen doped ordered mesoporous carbon for CO2 capture and supercapacitors. Adv. Funct. Mater. 23(18), 2322 (2013).Google Scholar
Sánchez-Sánchez, Á., Suárez-García, F., Martínez-Alonso, A., and Tascón, J.: Synthesis, characterization and dye removal capacities of N-doped mesoporous carbons. J. Colloid Interface Sci. 450, 91 (2015).Google Scholar
Lin, T.Q., Chen, I.W., Liu, F.X., Yang, C.Y., Bi, H., Xu, F.F., and Huang, F.Q.: Nitrogen-doped mesoporous carbon of extraordinary capacitance for electrochemical energy storage. Science. 350(6267), 1508 (2015).Google Scholar
Welton, T.: Room-temperature ionic liquids. Solvents for synthesis and catalysis. Chem. Rev. 99(8), 2071 (1999).Google Scholar
Ma, Z., Yu, J., and Dai, S.: Preparation of inorganic materials using ionic liquids. Adv. Mater. 22(2), 261 (2010).Google Scholar
Liao, C., Liu, R., Hou, X.S., Sun, X.G., and Dai, S.: Easy synthesis of poly(ionic liquid) for use as a porous carbon precursor. Carbon 29(1), 78 (2014).Google Scholar
Wang, X. and Dai, S.: Ionic liquids as versatile precursors for functionalized porous carbon and carbon–oxide composite materials by confined carbonization. Angew. Chem., Int. Ed. 49(37), 6664 (2010).Google Scholar
Lee, J.S., Wang, X., Luo, H., Baker, G.A., and Dai, S.: Facile ionothermal synthesis of microporous and mesoporous carbons from task specific ionic liquids. J. Am. Chem. Soc. 131(13), 4596 (2009).Google Scholar
Paraknowitsch, J.P., Zhang, J., Su, D.S., Thomas, A., and Antonietti, M.: Ionic liquids as precursors for nitrogen-doped graphitic carbon. Adv. Mater. 22(1), 87 (2010).Google Scholar
Zhou, J., Yang, B., Li, Z.J., Lei, L.C., and Zhang, X.W.: Selective adsorption of naphthalene in aqueous solution on mesoporous carbon functionalized by task-specific ionic liquid. Ind. Eng. Chem. Res. 54(8), 2329 (2015).Google Scholar
Scovazzo, P., Havard, D., Mcshea, M., Mixon, S., and Morgan, D.: Long-term, continuous mixed-gas dry fed CO2/CH4 and CO2/N2 separation performance and selectivities for room temperature ionic liquid membranes. J. Membr. Sci. 327(s 1–2), 41 (2009).Google Scholar
Meng, Y., Gu, D., Zhang, F.Q., Shi, Y.F., Yang, H.F., Li, Z., Yu, C.Z., Tu, B., and Zhao, D.Y.: Ordered mesoporous polymers and homologous carbon frameworks: Amphiphilic surfactant templating and direct transformation. Angew. Chem., Int. Ed. 44(43), 7053 (2005).Google Scholar
Xie, M., Dong, H., Zhang, D., Guo, X., and Ding, W.: Simple synthesis of highly ordered mesoporous carbon by self-assembly of phenol–formaldehyde and block copolymers under designed aqueous basic/acidic conditions. Carbon 49(7), 2459 (2011).CrossRefGoogle Scholar
Chen, H., Zhou, M., Wang, Z., Zhao, S., and Guan, S.: Rich nitrogen-doped ordered mesoporous phenolic resin-based carbon for supercapacitors. Electrochim. Acta 148, 187 (2014).Google Scholar
Soin, N., Roy, S.S., Sharma, S., Thundat, T., and Mclaughlin, J.A.: Electrochemical and oxygen reduction properties of pristine and nitrogen-doped few layered graphene nanoflakes (FLGs). J. Solid State Electrochem. 257(3), 300 (2014).Google Scholar
Panja, T., Bhattacharjya, D., and Yu, J.S.: Nitrogen and phosphorus co-doped cubic ordered mesoporous carbon as a supercapacitor electrode material with extraordinary cyclic stability. Proc. SPIE 3570(35), 176 (2015).Google Scholar
Shi, Q., Zhang, R., Lv, Y., Deng, Y., Elzatahrya, A.A., Zhao, D., Shi, Q., Zhang, R., Lv, Y., and Elzatahrya, A.A.: Nitrogen-doped ordered mesoporous carbons based on cyanamide as the dopant for supercapacitor. Carbon 84(1), 335 (2015).Google Scholar
Xu, B., Hou, S., Cao, G., Wu, F., and Yang, Y.: Sustainable nitrogen-doped porous carbon with high surface areas prepared from gelatin for supercapacitors. J. Mater. Chem. 22(36), 19088 (2012).Google Scholar
Yang, S., Wu, X., Chen, C., Dong, H., Hu, W., and Wang, X.: Spherical α-Ni(OH)2 nanoarchitecture grown on graphene as advanced electrochemical pseudocapacitor materials. Chem. Commun. 48(22), 2773 (2012).Google Scholar
Meher, S.K. and Rao, G.R.: Enhanced activity of microwave synthesized hierarchical MnO2 for high performance supercapacitor applications. J. Power Sources 215, 317 (2012).Google Scholar
Kim, C. and Yang, K.S.: Electrochemical properties of carbon nanofiber web as an electrode for supercapacitor prepared by electrospinning. Appl. Phys. Lett. 83(6), 1216 (2003).Google Scholar
Supplementary material: File

Zhou supplementary material S1

Zhou supplementary material

Download Zhou supplementary material S1(File)
File 40.5 KB
Supplementary material: Image

Zhou supplementary material S2

Supplementary Figure

Download Zhou supplementary material S2(Image)
Image 164.8 KB