Hostname: page-component-cd9895bd7-7cvxr Total loading time: 0 Render date: 2024-12-24T02:03:51.672Z Has data issue: false hasContentIssue false
  • English
  • Français

Modification of sensitivity of BaSnO3 sensor due to parameters of synthesis and formation of the device

Published online by Cambridge University Press:  02 November 2015

Yasser H. Ochoa Open the ORCID record for Yasser H. Ochoa [Opens in a new window] ,
Federico Schipani ,
Celso M. Aldao ,
Jorge E. Rodríguez-Páez  and
Miguel A. Ponce
Yasser H. Ochoa*
Affiliation:
Department of Physics, CYTEMAC Group, University of Cauca, Popayán 90002, Colombia
Federico Schipani
Affiliation:
Catalysts and Surfaces Division, INTEMA, National University of Mar del Plata, Mar del Plata 7600, Argentina
Celso M. Aldao
Affiliation:
Catalysts and Surfaces Division, INTEMA, National University of Mar del Plata, Mar del Plata 7600, Argentina
Jorge E. Rodríguez-Páez
Affiliation:
Department of Physics, CYTEMAC Group, University of Cauca, Popayán 90002, Colombia
Miguel A. Ponce
Affiliation:
Catalysts and Surfaces Division, INTEMA, National University of Mar del Plata, Mar del Plata 7600, Argentina
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

Powders of BaSnO3 were synthesized to obtain gas sensor thick films (using the screen printing technique) for the detection of O2 and CO. Impedance spectroscopy was used at different atmospheres and temperatures. In the presence of O2, the films showed a maximum value of sensitivity at 300 °C, with the powders formed by Pechini presenting greater reproducibility and sensitivity (with an order of magnitude greater than that for the powders formed by precipitation). Results showed that the films formed with powders obtained using the Pechini method presented a better response to CO, with a maximum sensitivity at 450 °C. In addition, in the presence of CO and for T > 250 °C, these films showed an anomalous behavior regarding their sensitivity as a function of time when platinum electrodes were used: a great increase in the electrical resistance value for exposure times greater than 10 min.

Keywords

BaSnO3controlled precipitation methodPechini methodthick filmsCO detectionsensitivity
Type
Articles
Information
Journal of Materials Research , Volume 30 , Issue 22 , 27 November 2015 , pp. 3423 - 3430
Copyright
Copyright © Materials Research Society 2015 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Megaw, H.D.: Crystal structure of double oxides of the perovskite type. Proc. Phys. Soc. 58(2), 133–152 (1946).Google Scholar
Cerda, J., Arbiol, J., Dezanneau, G., Díaz, R., and Morante, J.R.. Perovskite-type BaSnO3 powders for high temperature gas sensor applications. Sens. Actuators, B 84, 21–25 (2002).Google Scholar
Yuan, Y., Lv, J., and Jiang, X.: Large impact of strontium substitution on photocatalytic water splitting activity of BaSnO3. Appl. Phys. Lett. 91, 094107 (2007).Google Scholar
Zhigang, Z. and Gang, Z.: BTS: A new ferroelectric for multifunctional sensors. Ferroelectrics 101, 43–54 (1990).Google Scholar
Huang, T., Nakamura, T., Itoh, M., Inaguma, Y., and Ishiyama, O.: Electrical properties of BaSnO3 in substitution of antimony for tin and lanthanum for barium. J. Mater. Sci. 30, 1556–1560 (1995).CrossRefGoogle Scholar
Upadhyay, S., Parkash, O., and Kumar, D.: Solubility of lanthanum, nickel and chromium in barium stannate. Mater. Lett. 49, 251–255 (2001).Google Scholar
Lu, W. and Schmidt, H.: Hydrothermal synthesis of nanocrystalline BaSnO3 using a SnO2·xH2O sol. J. Eur. Ceram. Soc. 25, 919–925 (2005).Google Scholar
Lu, W. and Schmidt, H.: Synthesis of tin oxide hydrate (SnO2·xH2O) gel and its effects on the hydrothermal preparation of BaSnO3 powders. Adv. Powder Technol. 19, 1–12 (2008).Google Scholar
Lu, W. and Schmidt, H.: Lyothermal synthesis of nanocrystalline BaSnO3 powders. Ceram. Int. 34, 645–649 (2008).Google Scholar
Lu, W. and Schmidt, H.: Synthesis of nanosized BaSnO3 powders from metal isopropoxides. J. Sol-Gel Sci. Technol. 42, 55–64 (2007).CrossRefGoogle Scholar
Azad, A.M., Shyan, L.W., Pang, T.Y., and Nee, C.H.: Microstructural evolution in MSnO3 ceramics derived via self-heat-sustained (SHS) reaction technique. Ceram. Int. 26, 685–692 (2000).Google Scholar
Deep, A.S., Vidya, S., Manu, P.C., Solomon, S., John, A., and Thomas, J.K.: Structural and optical characterization of BaSnO3 nanopowder synthesized through novel combustion technique. J. Alloys Compd. 509, 1830–1835 (2011).Google Scholar
Ahmed, J., Blakely, C.K., Bruno, S.R., and Poltavets, V.V.: Synthesis of MSnO3 (M = Ba, Sr) nanoparticles by reverse micelle method and particle size distribution analysis by whole powder pattern modeling. Mater. Res. Bull. 47, 2282–2287 (2012).CrossRefGoogle Scholar
Larramona, G., Gutierrez, C., Pereira, I., Nunes, M.R., and Da Costa, F.M.A.: Characterization of the mixed perovskite BaSn1−xSbxO3 by electrolyte electroreflectance, diffuse reflectance, and x-ray photoelectron spectroscopy. J. Chem. Soc., Faraday Trans. 85, 907 (1989).CrossRefGoogle Scholar
Madou, M.J. and Morrison, S.R.: Chapter 3. In Chemical Sensing with Solid State Devices, Academic Press: New York, 1989.Google Scholar
Shimizu, Y., Fukuyama, Y., Narikiyo, T.N., Arari, H., and Seiyama, T.: Perovskite-type oxides having semiconductivity as oxygen sensors. Chem. Lett. 14, 377–380 (1985).Google Scholar
Ostrick, B., Fleischer, M., and Meixner, H.: High-temperature Hall measurements on BaSnO3 ceramics. J. Am. Ceram. Soc. 80(8), 2153–2156 (1997).Google Scholar
Yamazoe, N., Fuchigami, J., Kishikawa, M., and Seiyama, T.: Interactions of tin oxide with O2, H2O and H2. Surf. Sci. 86, 335 (1979).CrossRefGoogle Scholar
Chang, S.C.: Oxygen chemisorption on tin oxide: Correlation between electrical conductivity and EPR measurements. J. Vac. Sci. Technol. 17, 366 (1980).CrossRefGoogle Scholar
Lampe, U., Gerblinger, J., and Meixner, H.: Carbon-monoxide sensors based on thin films of BaSnO3. Sens. Actuators, B 25, 657–660 (1995).Google Scholar
Ochoa-Muñoz, Y.H., Ponce, M.A., and Rodríguez-Páez, J.E.: Comparative study of two wet chemical methods of BaSnO3 synthesis: Mechanism of formation of mixed oxide. Powder Technol. 279, 86–95 (2015).CrossRefGoogle Scholar
Aldao, C.M., Schipani, F., Ponce, M.A., and Joanni, E., Williams, F.J.: Conductivity in SnO2 polycrystalline thick film gas sensors: Tunneling electron transport and oxygen diffusion. Sens. Actuators, B 193, 428–433 (2014).Google Scholar
Socrates, G.: Infrared and Raman Characteristic Group Frequencies: Tables and Charts, 3rd ed. (John Wiley & Sons Ltd., West Sussex, 2001).Google Scholar
Amalric-Popescu, D. and Bozon-Verduraz, F.: Infrared studies on SnO2 and Pd/SnO2. Catal. Today 70, 139–154 (2001).Google Scholar
Nakamato, K.: Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part A, B, 5th ed. (John Wiley & Sons Inc., New York, 1997).Google Scholar
Batzill, M. and Diebold, U.: The surface and materials science of tin oxide. Prog. Surf. Sci. 79, 47–154 (2005).Google Scholar
Ponce, M., Aldao, C.M., and Castro, M.S.: Influence of particle size on the conductance of SnO2 thick films. J. Eur. Ceram. Soc. 23, 2105–2111 (2003).Google Scholar
Aldao, C.M., Mirabella, D.A., Ponce, M.A., Giberti, A., and Malagù, C.: Role of intragrain oxygen diffusion in polycrystalline tin oxide conductivity. J. Appl. Phys. 109, 063723 (2011).CrossRefGoogle Scholar
Malagu, C., Carotta, M.C., Giberti, A., Guidi, V., Martinelli, G., Ponce, M.A., Castro, M.S., and Aldao, C.M.: Two mechanisms of conduction in polycrystalline SnO2. Sens. Actuators, B 136, 230–234 (2009).Google Scholar
Schipani, F., Aldao, C.M., and Ponce, M.A.: Schottky barriers measurements through Arrhenius plots in gas sensors based on semiconductor films. AIP Adv. 2, 2158–3226 (2012).Google Scholar
Ponce, M.A., Castro, M.S., and Aldao, C.M.: Influence of oxygen adsorption and diffusion on the overlapping of intergranular potential barriers in SnO2 thick films. Mater. Sci. Eng., B 111, 14–19 (2004).Google Scholar
Sze, S.M.: Physics of Semiconductor Devices, 3rd ed. (John Wiley & Sons, New Jersey, 1981).Google Scholar
Kao, K.C.: Dielectric Phenomena in Solids, 1st ed. (Elsevier Academics Press, New York, 2004).Google Scholar
Ponce, M.A., Malagu, C., Carotta, M.C., Martinelli, G., and Aldao, C.M.: Gas in-diffusion contribution to impedance in tin oxide thick films. J. Appl. Phys. 104, 054907 (2008).Google Scholar