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Microwave-assisted hydrothermal synthesis and electrochemical characterization of niobium pentoxide/carbon nanotubes composites

Published online by Cambridge University Press:  30 January 2019

Ricardo M. Silva ,
Bruno S. Noremberg ,
Natália H. Marins ,
Jordan Milne ,
Igor Zhitomirsky  and
Neftalí L.V. Carreño Open the ORCID record for Neftalí L.V. Carreño [Opens in a new window]
Ricardo M. Silva
Affiliation:
Materials Science and Engineering, Federal University of Pelotas, RS 96010-610, Brazil; and Materials Science and Engineering, McMaster University, Hamilton, ON L8S 4L8, Canada
Bruno S. Noremberg
Affiliation:
Materials Science and Engineering, Federal University of Pelotas, Pelotas - RS 96010-610, Brazil
Natália H. Marins
Affiliation:
Materials Science and Engineering, Federal University of Pelotas, RS 96010-610, Brazil; and Materials Science and Engineering, McMaster University, Hamilton, ON L8S 4L8, Canada
Jordan Milne
Affiliation:
Materials Science and Engineering, McMaster University, Hamilton, ON L8S 4L8, Canada
Igor Zhitomirsky
Affiliation:
Materials Science and Engineering, McMaster University, Hamilton, ON L8S 4L8, Canada
Neftalí L.V. Carreño*
Affiliation:
Materials Science and Engineering, Federal University of Pelotas, Pelotas - RS 96010-610, Brazil
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

This study reports the fabrication of high mass loading (32 mg/cm2) electrodes of niobium pentoxide (Nb2O5) nanoparticles and carbon nanotubes (CNTs) using a facile procedure. The as-obtained Nb2O5 nanoparticles by microwave-assisted hydrothermal synthesis presented pseudohexagonal (TT) phase, and when exposed to the thermal treatment, the Nb2O5 nanoparticles changed to orthorhombic (T) phase. Distinct morphologies were obtained, which exhibited a specific surface area of 216 m2/g and 47 m2/g to pseudohexagonal and orthorhombic phases, respectively. Cyclic voltammetry and electrochemical impedance spectroscopy techniques were performed in a three-electrode system using 1 M Li2SO4 as electrolyte with a potential window of 0–0.9 V (versus standard calomel electrode). Both materials showed capacitive behavior with a specific capacitance of 0.11 F/cm2 and 0.09 F/cm2 to nanocomposites CNT + TT-Nb2O5 and CNT + T-Nb2O5 at 2 mV/s, respectively. Thus, an efficient, simple, and promising process to produce electrodes for supercapacitors was demonstrated.

Keywords

Nbnanostructuremicrowave heating
Type
Article
Information
Journal of Materials Research , Volume 34 , Issue 4 , 28 February 2019 , pp. 592 - 599
Copyright
Copyright © Materials Research Society 2019 

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References

Lim, E., Kim, H., Jo, C., Chun, J., Ku, K., Kim, S., Lee, H.I., Nam, I.S., Yoon, S., Kang, K., and Lee, J.: Advanced hybrid supercapacitor based on a mesoporous niobium pentoxide/carbon as high-performance anode. ACS Nano 8, 8968 (2014).CrossRefGoogle ScholarPubMed
Augustyn, V., Simon, P., and Dunn, B.: Pseudocapacitive oxide materials for high-rate electrochemical energy storage. Energy Environ. Sci. 7, 1597 (2014).CrossRefGoogle Scholar
Kong, L., Zhang, C., Zhang, S., Wang, J., Cai, R., Lv, C., Qiao, W., Ling, L., and Long, D.: High-power and high-energy asymmetric supercapacitors based on Li+-intercalation into a T-Nb2O5/graphene pseudocapacitive electrode. J. Mater. Chem. A 2, 17962 (2012).Google Scholar
Cui, H., Zhu, G., Liu, X., Liu, F., Xie, Y., and Yang, C.: Niobium nitride Nb4N5 as a new high-performance electrode material for supercapacitors. Adv. Sci. 2, 1500126 (2015).CrossRefGoogle ScholarPubMed
Falk, G., Borlaf, M., López-Muñoz, M.J., Fariñas, J.C., Rodrigues Neto, J.B., and Moreno, R.: Microwave-assisted synthesis of Nb2O5 for photocatalytic application of nanopowders and thin films. J. Mater. Res. 32, 3271 (2017).Google Scholar
Lopes, O.F., Paris, E.C., and Ribeiro, C.: Synthesis of Nb2O5 nanoparticles through the oxidant peroxide method applied to organic pollutant photodegradation: A mechanistic study. Appl. Catal., B 144, 800 (2014).CrossRefGoogle Scholar
Rani, R.A., Zoolfakar, A.S., O’Mullane, A.P., Austin, M.W., and Kalantar-Zadeh, K.: Thin films and nanostructures of niobium pentoxide: Fundamental properties, synthesis methods and applications. J. Mater. Chem. A 2, 15683 (2014).CrossRefGoogle Scholar
Liu, M., Yan, C., and Zhang, Y.: Fabrication of Nb2O5 nanosheets for high-rate lithium ion storage applications. Sci. Rep. 5, 8326 (2015).CrossRefGoogle ScholarPubMed
Kocjan, A., Logar, M., and Shen, Z.: The agglomeration, coalescence and sliding of nanoparticles, leading to the rapid sintering of zirconia nanoceramics. Sci. Rep. 7, 1 (2017).CrossRefGoogle ScholarPubMed
Taberna, P.L., Simon, P., and Fauvarque, J.F.: Electrochemical characteristics and impedance spectroscopy studies of carbon–carbon supercapacitors. J. Electrochem. Soc. 150, A292 (2003).CrossRefGoogle Scholar
Luo, G., Li, H., Zhang, D., Gao, L., and Lin, T.: A template-free synthesis via alkaline route for Nb2O5/carbon nanotubes composite as pseudo-capacitor material with high-rate performance. Electrochim. Acta 235, 175 (2017).CrossRefGoogle Scholar
Wang, X., Li, G., Chen, Z., Augustyn, V., Ma, X., Wang, G., Dunn, B., and Lu, Y.: High-performance supercapacitors based on nanocomposites of Nb2O5 nanocrystals and carbon nanotubes. Adv. Energy Mater. 1, 1089 (2011).CrossRefGoogle Scholar
Li, S., Xu, Q., Uchaker, E., Cao, X., and Cao, G.: Comparison of amorphous, pseudohexagonal and orthorhombic Nb2O5 for high-rate lithium ion insertion. CrystEngComm 18, 2532 (2016).CrossRefGoogle Scholar
Wang, X., Li, G., Tjandra, R., Fan, X., Xiao, X., and Yu, A.: Fast lithium-ion storage of Nb2O5 nanocrystals in situ grown on carbon nanotubes for high-performance asymmetric supercapacitors. RSC Adv. 5, 41179 (2015).CrossRefGoogle Scholar
Kong, L., Zhang, C., Wang, J., Qiao, W., Ling, L., and Long, D.: Nanoarchitectured Nb2O5 hollow, Nb2O5@carbon and NbO2@carbon core–shell microspheres for ultrahigh-rate intercalation pseudocapacitors. Sci. Rep. 6, 1 (2016).Google ScholarPubMed
Come, J., Augustyn, V., Kim, J.W., Rozier, P., Taberna, P-L., Gogotsi, P., Long, J.W., Dunn, B., and Simon, P.: Electrochemical kinetics of nanostructured Nb2O5 electrodes. J. Electrochem. Soc. 161, A718 (2014).CrossRefGoogle Scholar
Wang, X., Yan, C., Yan, J., Sumboja, A., and Lee, P.S.: Orthorhombic niobium oxide nanowires for next generation hybrid supercapacitor device. Nano Energy 11, 765 (2015).CrossRefGoogle Scholar
Yang, H., Xu, H., Wang, L., Zhang, L., Huang, Y., and Hu, X.: Microwave-assisted rapid synthesis of self-assembled T-Nb2O5 nanowires for high-energy hybrid supercapacitors. Chem. – Eur. J. 23, 4203 (2017).CrossRefGoogle Scholar
Leite, E.R., Vila, C., Bettini, J., and Longo, E.: Synthesis of niobia nanocrystals with controlled morphology. J. Phys. Chem. B 110, 18088 (2006).CrossRefGoogle ScholarPubMed
Menéndez, J.A., Arenillas, A., Fidalgo, B., Fernández, Y., Zubizarreta, L., Calvo, E.G., and Bermúdez, J.M.: Microwave heating processes involving carbon materials. Fuel Process. Technol. 91, 1 (2010).CrossRefGoogle Scholar
Wang, Q., Zheng, H., Long, Y., Zhang, L., Gao, M., and Bai, W.: Microwave-hydrothermal synthesis of fluorescent carbon dots from graphite oxide. Carbon 49, 3134 (2011).CrossRefGoogle Scholar
Yan, L., Rui, X., Chen, G., Xu, W., Zou, G., and Luo, H.: Recent advances in nanostructured Nb-based oxides for electrochemical energy storage. Nanoscale 8, 8443 (2016).CrossRefGoogle ScholarPubMed
Kim, J.W., Augustyn, V., and Dunn, B.: The effect of crystallinity on the rapid pseudocapacitive response of Nb2O5. Adv. Energy Mater. 2, 141 (2012).CrossRefGoogle Scholar
Goyanes, S., Rubiolo, G.R., Salazar, A., Jimeno, A., Corcuera, M.A., and Mondragon, I.: Carboxylation treatment of multiwalled carbon nanotubes monitored by infrared and ultraviolet spectroscopies and scanning probe microscopy. Diamond Relat. Mater. 16, 412 (2007).CrossRefGoogle Scholar
Marins, N.H., Meereis, C.T.W., Silva, R.M., Ruas, C.P., Takimi, A.S., Carreño, N.L.V., and Ogliari, F.A.: Radiopaque dental adhesive with addition of niobium pentoxide nanoparticles. Polym. Bull. 75, 2301 (2018).CrossRefGoogle Scholar
Ata, M.S., Milne, J., and Zhitomirsky, I.: Fabrication of Mn3O4–carbon nanotube composites with high areal capacitance using cationic and anionic dispersants. J. Colloid Interface Sci. 512, 758 (2018).CrossRefGoogle ScholarPubMed
Ventura, W.M., Batalha, D.C., Fajardo, H.V., Taylor, J.G., Marins, N.H., Noremberg, B.S., Tański, T., and Carreño, N.L.V.: Low temperature liquid phase catalytic oxidation of aniline promoted by niobium pentoxide micro and nanoparticles. Catal. Commun. 99, 135 (2017).CrossRefGoogle Scholar
Chan, X., Pu, T., Chen, X., James, A., Lee, J., Parise, J.B., Kim, D.H., and Kim, T.: Effect of niobium oxide phase on the furfuryl alcohol dehydration. Catal. Commun. 97, 65 (2017).CrossRefGoogle Scholar
Paraguassú Cecchi, C., Cesarín-Sobrinho, D., Buarque Ferreira, A., and Netto-Ferreira, J.: New insights on the oxidation of unsaturated fatty acid methyl esters catalyzed by niobium(V) oxide. A study of the catalyst surface reactivity. Catalysts 8, 6 (2018).CrossRefGoogle Scholar
Raba, A.M., Ruíz, J.B., and Joya, M.R.: Synthesis and structural properties of niobium pentoxide powders: A comparative study of the growth process. Mater. Res. 19, 1381 (2016).CrossRefGoogle Scholar
Zhao, W., Zhao, W., Zhu, G., Lin, T., Xu, F., and Huang, F.: Black Nb2O5 nanorods with improved solar absorption and enhanced photocatalytic activity. Dalton Trans. 45, 3888 (2016).CrossRefGoogle ScholarPubMed
Roh, J.: Structural study of the activated carbon fiber using laser Raman spectroscopy. Carbon Lett. 9, 127 (2008).CrossRefGoogle Scholar
Augustyn, V., Come, J., Lowe, M.A., Kim, J.W., Taberna, P.L., Tolbert, S.H., Abruña, H.D., Simon, P., and Dunn, B.: High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance. Nat. Mater. 12, 518 (2013).CrossRefGoogle ScholarPubMed