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Microwave assisted synthesis of technologically important transition metal silicides

Published online by Cambridge University Press:  31 January 2011

B. Vaidhyanathan
Affiliation:
Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore–560 012, India
K. J. Rao*
Affiliation:
Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore–560 012, India
*
a)Author to whom correspondence should be addressed.
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Abstract

A novel, simple, clean, and fast microwave assisted method of preparing important transition metal silicides (MoSi2, WSi2, CoSi2, and TiSi2) has been described. Amorphous carbon is used both as a microwave susceptor and as a preventer of oxidation.

Type
Articles
Copyright
Copyright © Materials Research Society 1997

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References

REFERENCES

1.Petrovic, J. J., Mater. Sci. Eng. A192/193, 31 (1995).Google Scholar
2.Petrovic, J. J. and Vasudévan, A. K., in High-Temperature Silicides and Refractory Alloys, edited by Briant, C. L., Petrovic, J. J., Bewlay, B. P., Vasudévan, A. K., and Lipsitt, H. A. (Mater. Res. Soc. Symp. Proc. 322, Pittsburgh, PA, 1994), p. 3.Google Scholar
3.Vasudévan, A. K. and Petrovic, J. J., Mater. Sci. Eng. A155, 1 (1992).CrossRefGoogle Scholar
4.Petrovic, J. J., MRS Bull. XVIII, 35 (1993).CrossRefGoogle Scholar
5.Colgan, E. G., Cabral, C., Jr., and Kotecki, D. E., J. Appl. Phys. 77 (2), 614 (1995).CrossRefGoogle Scholar
6.Kanno, Eiichi, Kokai, Japan, Japanese Patent 75 57,100 (1975).Google Scholar
7. Fujitsu Ltd., Kokai, Japan, Japanese Patent JP 58 61,666 (1981).Google Scholar
8.Schwartz, R. B., Srinivasan, S. R., Petrovic, J. J., and Maggiore, C. J., Mater. Sci. Eng. A155, 75 (1992).CrossRefGoogle Scholar
9.Jeitschko, W., Acta Crystallogr. B33, 2347 (1977).CrossRefGoogle Scholar
10.Whittaker, A. G. and Mingos, D. M. P., J. Chem. Soc. Dalton Trans., 2073 (1995).CrossRefGoogle Scholar
11.Gasgnier, M., Petit, A., Jullien, H., and Loupy, A., Mater. Res. Bull. 31 (9), 1101 (1996).CrossRefGoogle Scholar
12.Landry, C. C. and Barron, A. R., Science 260, 1653 (1993).CrossRefGoogle Scholar
13.Clark, D. E., Ahmad, I., and Dalton, R. C., Mater. Sci. Eng. A144, 91 (1991).CrossRefGoogle Scholar
14.Vaidhyanathan, B., Ganguli, M., and Rao, K. J., Mater. Res. Bull. 30 (9), 1173 (1995).CrossRefGoogle Scholar
15.Ramesh, P. D., Vaidhyanathan, B., Ganguli, M., and Rao, K. J., J. Mater. Res. 9, 3057 (1994).Google Scholar
16.Komarneni, S., Pidugu, R., Li, Q. H., and Roy, R., J. Mater. Res. 10, 1687 (1995).Google Scholar
17.Vaidhyanathan, B., Ganguli, M., and Rao, K. J., J. Solid State Chem. 113, 448 (1994).CrossRefGoogle Scholar
18.Baghurst, D. R. and Mingos, D. M. P., J. Chem. Soc. Chem. Commun., 829 (1988).CrossRefGoogle Scholar
19.Xu, Y. and Xiao, X., J. Mater. Res. 10, 334 (1995).CrossRefGoogle Scholar
20.Ramesh, P. D. and Rao, K. J., Adv. Mater. 7 (2), 177 (1995).CrossRefGoogle Scholar
21.Monsef-Mirzai, P., Ravindran, M., McWhinnie, W. R., and Burchill, P., Fuel 74 (1), 20 (1995).CrossRefGoogle Scholar
22.Vaidhyanathan, B., Ganguli, M., and Rao, K. J., J. Mater. Chem. 6 (3), 391 (1996).CrossRefGoogle Scholar
23.Wells, A. F., Structural Inorganic Chemistry (Clarendon Press, Oxford, 1975).Google Scholar
24.Kieffer, R., Z. Metallk. 43, 284 (1952).Google Scholar
25.Bertaut, F. and Blum, P., Z. Metallk. 231, 626 (1950).Google Scholar
26. Natl. Bur. Stand. (U.S.) Monogr. 25 21, 126 (1984).Google Scholar
27.Meek, T. T., Holcombe, C. E., and Dykes, N., J. Mater. Sci. Lett. 6, 1060 (1987).CrossRefGoogle Scholar
28.Rao, K. J. and Vaidhyanathan, B., Indian Patent No. 788/MAS/95 (1995).Google Scholar
29.Cotton, J. D., Kim, Y. S., and Kaufman, M. J., Mater. Sci. Eng. A144, 287 (1991).CrossRefGoogle Scholar
30.Walkiewicz, J. W., Kazonich, G., and McGill, S. L., Miner. Metall. Process. 39 (1988).Google Scholar