Hostname: page-component-586b7cd67f-t8hqh Total loading time: 0 Render date: 2024-11-22T20:46:10.220Z Has data issue: false hasContentIssue false

Microstructure and mechanical properties of dual two-phase Ni3Al–Ni3V intermetallic alloys charged with carbon

Published online by Cambridge University Press:  19 April 2016

Yuki Hamada
Affiliation:
Department of Materials Science, Osaka Prefecture University, Sakai, Osaka, 599-8531, Japan
Naotaka Kuroyanagi
Affiliation:
Department of Materials Science, Osaka Prefecture University, Sakai, Osaka, 599-8531, Japan
Yasuyuki Kaneno
Affiliation:
Department of Materials Science, Osaka Prefecture University, Sakai, Osaka, 599-8531, Japan
Takayuki Takasugi*
Affiliation:
Department of Materials Science, Osaka Prefecture University, Sakai, Osaka, 599-8531, Japan
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

The microstructures and mechanical properties of ternary (Ni75Al9V16) and multicomponent (Ni69Al9V9.5Nb3Ti1.5Co4Cr4) dual two-phase intermetallic alloys charged with C were investigated by scanning electron microscope, electron probe microscopic analyzer, x-ray diffraction, Vickers hardness, and tensile tests. Solid solubility limits of C in the dual two-phase microstructures were small, mostly less than 0.1 at.%. When C was charged exceeding the solid solubility limit, large-sized carbides were solidified with no structural coherency with the dual two-phase microstructure. Major transition metals constituting the carbides changed from Nb and Ti to V with increasing charged C content. This transition was correlated with the capability of the carbide formation. C dissolving in the dual two-phase microstructure enhanced hardness and flow strength through solid solution hardening without sacrificing tensile ductility. The formed carbides little contributed to strengthening, rather, contributed to softening through depleting constituent element V as well as alloying metals Nb, Ti, and Cr from the dual two-phase microstructures.

Type
Articles
Copyright
Copyright © Materials Research Society 2016 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Chan, R.W., West, D.R.F., Dunstan, D.J., McLean, M., Martin, J.W., and Morris, D.: Multiphase intermetallics. Philos. Trans. R. Soc., A 351, 497 (1995).Google Scholar
Yamaguchi, M. and Umakoshi, Y.: The deformation behaviour of intermetallic superlattice compounds. Prog. Mater. Sci. 34, 1 (1990).Google Scholar
Tomihisa, K., Kaneno, Y., and Takasugi, T.: Phase relation and microstructure in Ni3Al–Ni3Ti–Ni3Nb pseudo-ternary alloy system. Intermetallics 10, 247 (2002).CrossRefGoogle Scholar
Ohira, K., Kaneno, Y., and Takasugi, T.: Microstructures, mechanical property and chemical property in Ni3Al–Ni3Ti–Ni3Nb-based multi-intermetallic alloys. J. Mater. Sci. 39, 2295 (2004).CrossRefGoogle Scholar
Tomihisa, K., Kaneno, Y., and Takasugi, T.: Phase relation and microstructure in multi-phase intermetallic alloys based on Ni3Si–Ni3Ti–Ni3Nb pseudo-ternary alloy system. Intermetallics 12, 317 (2004).Google Scholar
Ohira, K., Kaneno, Y., and Takasugi, T.: Microstructure, mechanical property and oxidation property in Ni3Si–Ni3Ti–Ni3Nb multi-phase intermetallic alloys. Mater. Sci. Eng., A 399, 332 (2005).CrossRefGoogle Scholar
Fujita, M., Kaneno, Y., and Takasugi, T.: The effect of second-phase dispersions on mechanical property of Ni3Si based multi-phase intermetallic alloys. Mater. Sci. Eng., A 476, 112 (2008).Google Scholar
Nunomura, Y., Kaneno, Y., and Takasugi, T.: Phase relation and microstructure in multi-phase intermetallic alloys based on Ni3Al–Ni3Ti–Ni3V pseudo-ternary alloy system. Intermetallics 12, 389 (2004).Google Scholar
Nunomura, Y., Kaneno, Y., Tsuda, H., and Takasugi, T.: Dual multi-phase intermetallic alloys composed of geometrically close-packed Ni3X (X: Al, Ti and V) type structures—I. Microstructures and their stabilities. Acta Mater. 54, 851 (2006).CrossRefGoogle Scholar
Shibuya, S., Kaneno, Y., Yoshida, M., and Takasugi, T.: Dual multi-phase intermetallic alloys composed of geometrically close-packed Ni3X (X: Al, Ti and V) type structures—II. Mechanical properties. Acta Mater. 54, 861 (2006).Google Scholar
Shibuya, S., Kaneno, Y., Tsuda, H., and Takasugi, T.: Microstructural evolution of dual multi-phase intermetallic alloys composed of geometrically close packed Ni3X (X: Al and V) type structures. Intermetallics 15, 338 (2007).CrossRefGoogle Scholar
Shibuya, S., Kaneno, Y., Yoshida, M., Shishido, T., and Takasugi, T.: Mechanical properties of dual multi-phase single-crystal intermetallic alloy composed of geometrically close packed Ni3X (X: Al and V) type structures. Intermetallics 15, 119 (2007).Google Scholar
Soga, W., Kaneno, Y., and Takasugi, T.: Phase relation and microstructure in multi-phase intermetallic alloys based on Ni3Al–Ni3Nb–Ni3V pseudo-ternary alloy system. Intermetallics 14, 170 (2006).Google Scholar
Soga, W., Kaneno, Y., and Takasugi, T.: Microstructure and mechanical property in dual two-phase intermetallic alloys composed of geometrically close-packed Ni3X (X: Al and V) containing Nb. Mater. Sci. Eng., A 473, 180 (2008).Google Scholar
Kaneno, Y., Soga, W., Tsuda, H., and Takasugi, T.: Microstructural evolution and mechanical property in dual two-phase intermetallic alloys composed of geometrically close-packed Ni3X (X: Al and V) containing Nb. J. Mater. Sci. 43, 748 (2008).Google Scholar
Kawahara, K., Kaneno, Y., and Takasugi, T.: Microstructural factors affecting hardness property of dual two-phase intermetallic alloys based on Ni3Al–Ni3V pseudo-binary alloy system. Intermetallics 17, 938 (2009).CrossRefGoogle Scholar
Takasugi, T. and Kaneno, Y.: Properties and application for two-phase intermetallic alloys composed of geometrically close packed Ni3X (X: Al and V) structures. Mater. Res. Soc. Symp. Proc. 1128, 351 (2009).Google Scholar
Moronaga, T., Kaneno, Y., Ishii, S., and Takasugi, T.: Effect of the refractory element additions on microstructure and mechanical property of two-phase intermetallic alloys based on the Ni3Al–Ni3V pseudo-binary alloy system. Mater. Res. Soc. Symp. Proc. 1295, 231 (2011).Google Scholar
Kitaura, Y., Kaneno, Y., and Takasugi, T.: Effect of TiC addition on mechanical properties of dual two-phase Ni3Al–Ni3V intermetallic alloy. Intermetallics 18, 1623 (2010).CrossRefGoogle Scholar
Kitaura, Y., Kaneno, Y., and Takasugi, T.: Effect of NbC addition on mechanical properties of dual two-phase Ni3Al–Ni3V intermetallic alloy. Mater. Sci. Eng., A 527, 6012 (2010).Google Scholar
Osada, Y., Moronaga, T., Kaneno, Y., and Takasugi, T.: Effect of C addition on mechanical properties of dual two-phase Ni3Al–Ni3V intermetallic alloys. Mater. Sci. Eng., A 530, 481 (2011).CrossRefGoogle Scholar
Ochiai, S., Oya, Y., and Suzuki, T.: Alloying behaviour of Ni3Al, Ni3Ga, Ni3Si, and Ni3Ge. Acta Metall. 32, 289 (1984).CrossRefGoogle Scholar
Sugimura, H., Kaneno, Y., and Takasugi, T.: Alloying behavior of Ni3X-type GCP compounds. J. Alloys Compd. 496, 116 (2010).CrossRefGoogle Scholar
Hashimoto, T., Moronaga, T., Kaneno, Y., and Takasugi, T.: V content reduced dual two-phase Ni3Al–Ni3V intermetallic alloys. Mater. Sci. Eng., A 596, 207 (2014).Google Scholar
Kawahara, K., Moronaga, T., Kaneno, Y., Kakitsuji, A., and Takasugi, T.: Effect of Nb and Ti addition on microstructure and hardness of dual two-phase intermetallic alloys based on Ni3Al–Ni3V pseudo-binary alloy system. Mater. Trans. 51, 1395 (2010).CrossRefGoogle Scholar
Singleton, M. and Nash, P.: The C–Ni (carbon–nickel) system. J. Phase Equilib. 10, 121 (1989).Google Scholar
Huetter, L.J. and Stadelmaier, H.H.: Ternary carbides of transition metals with aluminum and magnesium. Acta Metall. 6, 367 (1958).CrossRefGoogle Scholar
Hong, T.M., Mishima, Y., and Suzuki, T.: Accurate determination of γ′ solvus in Ni–Al–X ternary systems. Mater. Res. Soc. Symp. Proc. 133, 429 (1988).Google Scholar
Gale, W.F. and Totemeier, T.C.: Smithells Metals Reference Book (Elsevier, Amsterdam, 2004); p. 822.Google Scholar
Masahashi, N., Takasugi, T., and Izumi, O.: Atomistic defect structures of Ni3Al containing C, B, and Be. Acta Metall., 36, 1815 (1988).CrossRefGoogle Scholar
Briant, C.L. and Huang, S.C.: Carbon segregation to grain boundaries in rapidly solidified Ni3Al. Metall. Trans. A 17, 2084 (1986).Google Scholar
Moronaga, T., Kaneno, Y., Semboshi, S., and Takasugi, T.: Microstructural stability and hardening behavior of Re-added dual two-phase Ni3Al and Ni3V intermetallic alloys. Philos. Mag. 95, 3859 (2015).Google Scholar
Edatsugi, D., Kaneno, Y., Semboshi, S., and Takasugi, T.: Fine precipitation in the channel region of dual two-phase Ni3Al and Ni3V intermetallic alloys added by Mo and W. Metall. Mater. Trans. A 47, 998 (2016).Google Scholar
Humphreys, F.J. and Hatherly, M.: Recrystallization and Related Annealing Phenomena (Pergamon, Oxford, 2004).Google Scholar
Fleck, N.A., Ashby, M.F., and Hutchinson, J.W.: The role of geometrically necessary dislocations in giving material strengthening. Scr. Mater. 48, 179 (2003).Google Scholar