Hostname: page-component-745bb68f8f-g4j75 Total loading time: 0 Render date: 2025-01-11T00:24:49.707Z Has data issue: false hasContentIssue false
  • English
  • Français

Microstructural evolution of body-centered cubic structure related Ti–Zr–Ni phases in non-stoichiometric Zr-based Zr–Ti–Mn–V–Ni hydride electrode alloys

Published online by Cambridge University Press:  31 January 2011

Xueyan Song ,
Yun Chen ,
Cesar Sequeira ,
Yongquan Lei ,
Qidong Wang  and
Ze Zhang
Xueyan Song*
Affiliation:
Department of Materials Science and Engineering, Zhejiang University, People's Republic of China; Beijing Laboratory of Electron Microscopy, Chinese Academy of Sciences, Beijing, People's Republic of China, and Applied Superconductivity Center, University of Wisconsin-Madison, Madison, Wisconsin 53706
Yun Chen
Affiliation:
Department of Materials Science and Engineering, Zhejiang University, People's Republic of China, and Department of Chemical Engineering, Instituto Superior Tecnico, Lisbon, Portugal
Cesar Sequeira
Affiliation:
Department of Chemical Engineering, Instituto Superior Tecnico, Lisbon, Portugal
Yongquan Lei
Affiliation:
Department of Materials Science and Engineering, Zhejiang University, People's Republic of China
Qidong Wang
Affiliation:
Department of Materials Science and Engineering, Zhejiang University, People's Republic of China
Ze Zhang
Affiliation:
Beijing Laboratory of Electron Microscopy, Chinese Academy of Sciences, Beijing, People's Republic of China
*
a) Address all correspondence to this author. Applied Superconductivity Center, University of Wisconsin-Madison, 1500 Engineering Drive, 927 ERB, Madison, Wisconsin, 53706. e-mail: [email protected]
Get access

Abstract

Non-stoichiometric Zr-based alloys were prepared, and the corresponding electrochemical properties were characterized as hydride electrode alloys. The microstructure and chemical composition of non-stoichiometric Zr–Ti–Mn–V–Ni hydride electrode alloys were systematically investigated by x-ray Rietveld refinement, transmission electron microscopy (TEM), and energy dispersive spectroscopy under TEM observation. C14, C15 Laves phases and non-Laves phases were identified in Zr1−xTix(MnVNi)2.2 (x = 0, 0.2, 0.3, 0.4) alloys. Non-Laves phases in Zr1-xTix(MnVNi)2.2 (x = 0, 0.2, 0.3, 0.4) alloys are Ti–Zr–Ni phases related to the TiNi phase with pseudo-body-centered-cubic structure of the CsCl type. The evolution of crystallography and phase constitution for Ti–Zr–Ni non-Laves phases with different alloy composition was systematically studied. The influence of the Ti–Zr–Ni phases on the electrochemical properties of non-stoichiometric Zr1−xTix(MnVNi)2.2 alloys is briefly discussed.

Type
Articles
Information
Journal of Materials Research , Volume 18 , Issue 1 , January 2003 , pp. 37 - 44
Copyright
Copyright © Materials Research Society 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Willems, J.J.G., Philips J. Res. Suppl. 39, 10 (1984).Google Scholar
2.Coene, W., Notten, P.H.L., Hakkens, F., Einerhand, R.E.F., and Daams, J.L.C., Philos. Mag. A. 65, 1485 (1992).Google Scholar
3.Ovshinsky, S.R., Fetcenko, M.A., and Ross, J., Science 260, 9 (1993).CrossRefGoogle Scholar
4.Joubert, J.M., Latroche, M., Percheron-Guegan, A., Bovet, J., J. Alloys Comp. 240, 219 (1996).Google Scholar
5.Ciureanu, M., Ryan, D.H., and Strom-Olsen, J.O., J. Electrochem. Soc. 140, 579 (1993).CrossRefGoogle Scholar
6.Huot, J., Akiba, E., Ogura, T., and Ishido, Y., J. Alloys Compd. 218, 101 (1995).CrossRefGoogle Scholar
7.Hout, J., Akiba, E., and Ishido, Y., J. Alloys Compd. 231, 85 (1995).Google Scholar
8.Yang, H.W., Wang, Y.Y., and Wan, C.C., J. Electrochem. Soc. 143, 429 (1996).CrossRefGoogle Scholar
9.Yang, H.W., Lee, W.S., Wang, Y.Y., and Wan, C.C., J. Mater. Res. 10, 1680 (1995).Google Scholar
10.Wakao, S., Sawa, H., and Furukawa, J., J. Less-Common Met. 172–174, 1219 (1991).Google Scholar
11.Kim, D-M., Lee, S-M., Jung, J-H., Jang, K-J., and Lee, J-Y., J. Electrochem. Soc. 145, 93 (1998).Google Scholar
12.Song, X.Y., Zhang, X.B., Lei, Y.Q., Zhang, Z., and Wang, Q.D., Int. J. Hydrogen Energy 24, 455 (1999).CrossRefGoogle Scholar
13.Yoshida, M. and Akiba, E., J. Alloys Compd. 224, 121 (1995).Google Scholar
14.Song, X., Zhang, Z., Zhang, X., Lei, Y., and Wang, Q., J. Mater. Res. 14, 1279 (1999).CrossRefGoogle Scholar
15.Fruchart, D., Soubeyroux, J.L., Miraglia, S., and Obbade, S., Z. Phys. Chemie. 179, 225 (1994).Google Scholar
16.Han, X.D., Wang, R., Zhang, Z., and Yang, D.Z., Acta Mater. 46, 273 (1998).CrossRefGoogle Scholar
17.Gunier, A., X-ray Diffraction in Crystals, Imperfect Crystals and Amorphous Bodies (W.H. Freeman, San Francisco, CA, 1963).Google Scholar
18.Hwang, C.M., Meichle, M., Salamon, M.B., and Wayman, C.M., Philos. Mag. 47A, 9 (1983).Google Scholar
19.Salamon, M.B., Meichle, M.E., and Wayman, C.M., Phys. Rev. B. 31, 7306 (1985).CrossRefGoogle Scholar
20.Miyazaki, S. and Wayman, C.M., Acta Metall. 36, 181 (1988).CrossRefGoogle Scholar
21.Wu, S.K. and Wayman, C.M., Acta Metall. 37, 2805 (1989).CrossRefGoogle Scholar
22.Wakao, S., Sawa, H., Nakano, H., Chubachi, S., and Abe, M., J. Less-Common Met. 131, 311 (1987).Google Scholar
23.Justi, R.W., Energy Conver. 10, 183 (1970).Google Scholar
24.Guiahr, M., J. Power Sources. 4, 79 (1973).Google Scholar