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Mesoporous double-perovskite LaAMnNiO6 (A = La, Pr, Sm) photothermal synergistic degradation of gaseous toluene

Published online by Cambridge University Press:  16 September 2019

Yiran Tang ,
Yuwei Tao ,
Qing Wang ,
Zerui Zhu ,
Wanqi Zhang ,
Xiang Li ,
Aijuan Xie  and
Shiping Luo Open the ORCID record for Shiping Luo [Opens in a new window]
Yiran Tang
Affiliation:
School of Petrochemical Engineering, Changzhou University, Changzhou 213164, People’s Republic of China
Yuwei Tao
Affiliation:
Center of Information Development and Management, Changzhou University, Changzhou 213164, People’s Republic of China
Qing Wang
Affiliation:
School of Petrochemical Engineering, Changzhou University, Changzhou 213164, People’s Republic of China
Zerui Zhu
Affiliation:
School of Petrochemical Engineering, Changzhou University, Changzhou 213164, People’s Republic of China
Wanqi Zhang
Affiliation:
School of Petrochemical Engineering, Changzhou University, Changzhou 213164, People’s Republic of China
Xiang Li
Affiliation:
School of Petrochemical Engineering, Changzhou University, Changzhou 213164, People’s Republic of China
Aijuan Xie*
Affiliation:
School of Petrochemical Engineering, Changzhou University, Changzhou 213164, People’s Republic of China
Shiping Luo*
Affiliation:
School of Petrochemical Engineering, Changzhou University, Changzhou 213164, People’s Republic of China
*
a)Address all correspondence to these authors. e-mail: [email protected]
b)e-mail: [email protected]
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Abstract

A series of double-perovskite LaAMnNiO6 (A = La, Pr, Sm) catalysts with mesoporous morphology was prepared by a sol–gel method and further applied into photothermal synergistic degradation of gaseous toluene. Transmission electron microscopy and Brunauer–Emmett–Teller characterizations confirmed that double-perovskite LaAMnNiO6 (A = La, Pr, Sm) had obvious mesoporous structure, which can provide a larger specific surface area and further enhancing the reactivity of catalyst. UV-vis and X-ray photoelectron spectroscopy characterization illustrated that LaSmMnNiO6 possessed higher adsorption oxygen content and light absorption capacity, which contribute to the occurrence of catalytic oxidation in the Mars–van Krevelen redox cycle mechanism. A group of active tests showed that the double-perovskite LaSmMnNiO6 catalyst had a lower reaction initiation temperature (starting reaction at 75 °C) and a lower activity temperature of optimal reaction (more than 90% at 255 °C). Moreover, the research on reaction kinetics of the catalyst demonstrated that LaAMnNiO6 (A = La, Pr, Sm) had lower activation energy and thus exhibited better catalytic activity. The results of the study indicate that the double-perovskite LaAMnNiO6 (A = La, Pr, Sm) has broad application prospects in the field of volatile organic pollutant degradation.

Keywords

double perovskitecatalytic oxidationphotothermal synergygaseous toluenedegradation
Type
Article
Information
Journal of Materials Research , Volume 34 , Issue 20 , 28 October 2019 , pp. 3439 - 3449
Copyright
Copyright © Materials Research Society 2019 

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Footnotes

c)

These authors contributed equally to this work.

References

Chen, S., Li, W.B., Wang, J.X., and Gong, H.: Catalytic combustion of VOCs on non-noble metal catalysts. Catal. Today 148, 81 (2009).Google Scholar
Colman Lerner, J.E., Sanchez, E.Y., Sambeth, J.E., and Porta, A.A.: Characterization and health risk assessment of VOCs in occupational environments in Buenos Aires, Argentina. Atmos. Environ. 55, 440 (2012).CrossRefGoogle Scholar
Huang, G., Brook, R., Crippa, M., Janssens-Maenhout, G., Schieberle, C., Dore, C., Guizzardi, D., Muntean, M., Schaaf, E., and Friedrich, R.: Speciation of anthropogenic emissions of non-methane volatile organic compounds: A global gridded data set for 1970–2012. Atmos. Chem. Phys. 17, 7683 (2017).CrossRefGoogle Scholar
Yang, C., Miao, G., Pi, Y., Xia, Q., Wu, J., Li, Z., and Xiao, J.: Abatement of various types of VOCs by adsorption/catalytic oxidation: A review. Chem. Eng. J. 370, 128 (2019).CrossRefGoogle Scholar
Zhang, Z., Jiang, Z., and Shangguan, W.: Low-temperature catalysis for VOCs removal in technology and application: A state-of-the-art review. Catal. Today 264, 270 (2016).CrossRefGoogle Scholar
Dunn, R.F. and El-Halwagi, M.M.: Selection of optimal VOC-condensation systems. Waste Manage. 14, 103 (1994).CrossRefGoogle Scholar
Liu, Y., Feng, X., and Lawless, D.: Separation of gasoline vapor from nitrogen by hollow fiber composite membranes for VOC emission control. J. Membr. Sci. 271, 114 (2006).CrossRefGoogle Scholar
Wang, H., Wang, T., Han, L., Tang, M., Zhong, J., Huang, W., and Chen, R.: VOC adsorption and desorption behavior of hydrophobic, functionalized SBA-15. J. Mater. Res. 31, 516 (2016).CrossRefGoogle Scholar
Kamal, M.S., Razzak, S.A., and Hossain, M.M.: Catalytic oxidation of volatile organic compounds (VOCs)—A review. Atmos. Environ. 140, 117 (2016).CrossRefGoogle Scholar
Tomatis, M., Xu, H-H., He, J., and Zhang, X-D.: Recent development of catalysts for removal of volatile organic compounds in flue gas by combustion: A review. J. Chem. 2016, 1–15 (2016).CrossRefGoogle Scholar
Liu, H.H., Li, Y.Z., Yang, Y., Mao, M.Y., Zeng, M., Lan, L., Yun, L., and Zhao, X.J.: Highly efficient UV-vis-infrared catalytic purification of benzene on CeMnxOy/TiO2 nanocomposite, caused by its high thermocatalytic activity and strong absorption in the full solar spectrum region. J. Mater. Chem. A 4, 9890 (2016).CrossRefGoogle Scholar
Zeng, M., Li, Y., Mao, M., Bai, J., Ren, L., and Zhao, X.: Synergetic effect between photocatalysis on TiO2 and thermocatalysis on CeO2 for gas-phase oxidation of benzene on TiO2/CeO2 nanocomposites. ACS Catal. 5, 3278 (2015).CrossRefGoogle Scholar
Chen, J., He, Z., Li, G., An, T., Shi, H., and Li, Y.: Visible-light-enhanced photothermocatalytic activity of ABO3-type perovskites for the decontamination of gaseous styrene. Appl. Catal., B 209, 146 (2017).CrossRefGoogle Scholar
Li, J., Yu, E., Cai, S., Chen, X., Chen, J., Jia, H., and Xu, Y.: Noble metal free, CeO2/LaMnO3 hybrid achieving efficient photo-thermal catalytic decomposition of volatile organic compounds under IR light. Appl. Catal., B 240, 141 (2019).CrossRefGoogle Scholar
Li, J., Yang, R., Que, L., Wang, Y., Wang, F., Wu, J., and Li, S.: Optimization of anti-solvent engineering toward high performance perovskite solar cells. J. Mater. Res. 34, 2416 (2019).CrossRefGoogle Scholar
Chen, H. and Yang, S.: Stabilizing and scaling up carbon-based perovskite solar cells. J. Mater. Res. 32, 3011 (2017).CrossRefGoogle Scholar
Ahmed, S., Harris, J., Shaffer, J., Devgun, M., Chowdhury, S., Abdulllah, A., and Banerjee, S.: Simulation studies of Sn-based perovskites with Cu back-contact for non-toxic and non-corrosive devices. J. Mater. Res. 34, 2789 (2019).CrossRefGoogle Scholar
Pearson, A.J.: Structure formation and evolution in semiconductor films for perovskite and organic photovoltaics. J. Mater. Res. 32, 1798 (2018).CrossRefGoogle Scholar
Niu, S., Milam-Guerrero, J., Zhou, Y., Ye, K., Zhao, B., Melot, B.C., and Ravichandran, J.: Thermal stability study of transition metal perovskite sulfides. J. Mater. Res. 33, 4235 (2018).CrossRefGoogle Scholar
Maiti, T., Saxena, M., and Roy, P.: Double perovskite (Sr2B′B″O6) oxides for high-temperature thermoelectric power generation—A review. J. Mater. Res. 34, 107 (2019).CrossRefGoogle Scholar
Zhang, J., Tan, D., Meng, Q., Weng, X., and Wu, Z.: Structural modification of LaCoO3 perovskite for oxidation reactions: The synergistic effect of Ca2+ and Mg2+ co-substitution on phase formation and catalytic performance. Appl. Catal., B 172–173, 18 (2015).CrossRefGoogle Scholar
Steward, E.G. and Rooksby, H.P.: Pseudo-cubic alkaline-earth tungstates and molybdates of the R3MX6 type. Acta Crystallogr. 4, 503 (1951).CrossRefGoogle Scholar
Anderson, M.T., Greenwood, K.B., Taylor, G.A., and Poeppelmeier, K.R.: B-cation arrangements in double perovskites. Prog. Solid State Chem. 22, 197 (1993).CrossRefGoogle Scholar
Li, C., Wang, W., Xu, C., Liu, Y., He, B., and Chen, C.: Double perovskite oxides Sr2Mg1−xFexMoO6−δ for catalytic oxidation of methane. J. Nat. Gas Chem. 20, 345 (2011).CrossRefGoogle Scholar
Pan, K.L., Pan, G.T., Chong, S., and Chang, M.B.: Removal of VOCs from gas streams with double perovskite-type catalysts. J. Environ. Sci. 69, 205 (2018).CrossRefGoogle ScholarPubMed
Tasca, J.E., Lavat, A.E., and González, M.G.: Double perovskites La2MMnO6 as catalyst for propane combustion. J. Asian Ceram. Soc. 5, 235 (2017).CrossRefGoogle Scholar
Liu, Q., Wang, L.C., Chen, M., Cao, Y., He, H.Y., and Fan, K.N.: Dry citrate-precursor synthesized nanocrystalline cobalt oxide as highly active catalyst for total oxidation of propane. J. Catal. 263, 104 (2009).CrossRefGoogle Scholar
Hu, R., Li, C., Wang, X., Sun, Y., Jia, H., Su, H., and Zhang, Y.: Photocatalytic activities of LaFeO3 and La2FeTiO6 in p-chlorophenol degradation under visible light. Catal. Commun. 29, 35 (2012).CrossRefGoogle Scholar
Zhao, S., Shi, L., Zhou, S., Zhao, J., Yang, H., Guo, Y., Zhao, S., Shi, L., Zhou, S., Zhao, J., Yang, H., and Guo, Y.: Size-dependent magnetic properties and Raman spectra of La2NiMnO6 nanoparticles. J. Appl. Phys. 106, 123901 (2009).CrossRefGoogle Scholar
Gaikwad, V.M., Yadav, K.K., Lofland, S.E., Ramanujachary, K.V., Chakravertya, S., Ganguli, A.K., and Jha, M.: New low temperature process for stabilization of nanostructured La2NiMnO6 and their magnetic properties. J. Magn. Magn. Mater. 471, 8 (2019).CrossRefGoogle Scholar
Touahra, F., Rabahi, A., Chebout, R., Boudjemaa, A., Lerari, D., Sehailia, M., and Bachari, K.: Enhanced catalytic behaviour of surface dispersed nickel on LaCuO3 perovskite in the production of syngas: An expedient approach to carbon resistance during CO2 reforming of methane. Int. J. Hydrogen Energy 41, 2477 (2016).CrossRefGoogle Scholar
Liu, R., Jiang, Y., Gao, F., Du, W., and Lu, Q.: Biopolymer-assisted construction and gas-sensing study of uniform solid and hollow ZnSn(OH)6 spheres. Sens. Actuators, B 178, 119 (2013).CrossRefGoogle Scholar
Li, X., Yin, Y., Yao, C., Zuo, S., Lu, X., Luo, S., and Ni, C.: La1−xCexMnO3/attapulgite nanocomposites as catalysts for NO reduction with NH3 at low temperature. Particuology 26, 66 (2016).CrossRefGoogle Scholar
Mao, M., Li, Y., Hou, J., Zeng, M., and Zhao, X.: Extremely efficient full solar spectrum light driven thermocatalytic activity for the oxidation of VOCs on OMS-2 nanorod catalyst. Appl. Catal., B 174, 496 (2015).CrossRefGoogle Scholar
Han, J., Meeprasert, J., Maitarad, P., Nammuangruk, S., Shi, L.Y., and Zhang, D.S.: Investigation of the facet-dependent catalytic performance of Fe2O3/CeO2 for the selective catalytic reduction of NO with. J. Phys. Chem. C 120, 1523 (2016).CrossRefGoogle Scholar
Pan, Y., Shen, Y., Jin, Q., and Zhu, S.: Promotional effect of Ba additives on MnCeOx/TiO2 catalysts for NH3-SCR of NO at low temperature. J. Mater. Res. 33, 2414 (2018).CrossRefGoogle Scholar
Xie, A., Tang, Y., Huang, X., Jin, X., Gu, P., Luo, S., Yao, C., and Li, X.: Three-dimensional nanoflower MnCrOx/Sepiolite catalyst with increased SO2 resistance for NH3-SCR at low temperature. Chem. Eng. J. 370, 897 (2019).CrossRefGoogle Scholar
Tang, Y., Tao, Y., Wu, J., Xu, L., Huang, X., Zhou, X., Xie, A., Luo, S., Yao, C., and Li, X.: MnFeTiOx/attapulgite catalysts with excellent potassium resistance for SCR of NOx with NH3 at low temperatures. J. Mater. Res. 34, 1188 (2019).CrossRefGoogle Scholar
Zhang, C., Wang, C., Zhan, W., Guo, Y., Guo, Y., Lu, G., Baylet, A., and Giroir-Fendler, A.: Catalytic oxidation of vinyl chloride emission over LaMnO3 and LaB0.2Mn0.8O3 (B = Co, Ni, Fe) catalysts. Appl. Catal., B 129, 509 (2013).CrossRefGoogle Scholar
Álvarez-Galván, M.C., de la Peña O’Shea, V.A., Arzamend, G., Pawelec, B., Gandía, L.M., and Fierro, J.L.G.: Methyl ethyl ketone combustion over La-transition metal (Cr, Co, Ni, Mn) perovskites. Appl. Catal., B 92, 445 (2009).CrossRefGoogle Scholar
Zhao, X., Wang, Y., Wu, H., Fang, L., Liang, J., Fan, Q., and Li, P.: Insights into the effect of humic acid on Ni(II) sorption mechanism on illite: Batch, XPS and EXAFS investigations. J. Mol. Liq. 248, 1030 (2017).CrossRefGoogle Scholar
Li, X., Shi, H., Zhu, W., Zuo, S., Lu, X., Luo, S., Li, Z., Yao, C., and Chen, Y.: Nanocomposite LaFe1−xNixO3/palygorskite catalyst for photo-assisted reduction of NOx: Effect of Ni doping. Appl. Catal., B 231, 92 (2018).CrossRefGoogle Scholar
Guo, D., Yang, Q., Chen, P., Chu, Y., Zhang, Y., and Rao, P.: The influence of micronization on the properties of Pr–ZrSiO4 pigment. Dyes Pigm. 153, 74 (2018).CrossRefGoogle Scholar
Brunckova, H., Kanuchova, M., Kolev, H., Mudra, E., and Medvecky, L.: XPS characterization of SmNbO4 and SmTaO4 precursors prepared by sol–gel method. Appl. Surf. Sci. 473, 1 (2019).CrossRefGoogle Scholar
Wang, Z., Li, X., Qian, H., Zuo, S., Yan, X., Chen, Q., and Yao, C.: Upconversion Tm3+:CeO2/palygorskite as direct Z-scheme heterostructure for photocatalytic degradation of bisphenol A. J. Photochem. Photobiol., A 372, 42 (2019).CrossRefGoogle Scholar
Li, X., Yu, J., Jaroniec, M., and Chen, X.: Cocatalysts for selective photoreduction of CO2 into solar fuels. Chem. Rev. 119, 3962 (2019).CrossRefGoogle ScholarPubMed
Liu, Y.X., Dai, H.X., Du, Y.C., Deng, J.G., Zhang, L., Zhao, Z.X., and Au, C.T.: Controlled preparation and high catalytic performance of three-dimensionally ordered macroporous LaMnO3 with nanovoid skeletons for the combustion of toluene. J. Catal. 287, 149 (2012).CrossRefGoogle Scholar
Ziaei-Azad, H., Khodadadi, A., Esmaeilnejad-Ahranjani, P., and Mortazavi, Y.: Effects of Pd on enhancement of oxidation activity of LaBO3 (B = Mn, Fe, Co, and Ni) pervoskite catalysts for pollution abatement from natural gas fueled vehicles. Appl. Catal., B 102, 62 (2011).CrossRefGoogle Scholar
Li, X., Xie, J., Jiang, C., Yu, J., and Zhang, P.: Review on design and evaluation of environmental photocatalysts. Front. Environ. Sci. Eng. 12, 14 (2018).CrossRefGoogle Scholar
Lu, Y., Dai, Q., and Wang, X.: Catalytic combustion of chlorobenzene on modified LaMnO3 catalysts. Catal. Commun. 54, 114 (2014).CrossRefGoogle Scholar
Rivas, M.E., Hori, C.E., Fierro, J.L.G., Goldwasser, M.R., and Griboval-Constant, A.: H2 production from CH4 decomposition: Regeneration capability and performance of nickel and rhodium oxide catalysts. J. Power Sources 184, 265 (2008).CrossRefGoogle Scholar
Liu, Y.X., Dai, H.X., Deng, J.G., Du, Y.C., Li, X.W., Zhao, Z.X., Wang, Y., Gao, B., Yang, H., and Guo, G.: In situ poly(methyl methacrylate)-templating generation and excellent catalytic performance of MnOx/3DOM/LaMnO3 for the combustion of toluene and methanol. Appl. Catal. B Environ. 140–141, 493 (2013).CrossRefGoogle Scholar
Cai, S., Hu, H., Li, H., Shi, L., and Zhang, D.: Design of multi-shell Fe2O3@MnOx@CNTs for the selective catalytic reduction of NO with NH3: Improvement of catalytic activity and SO2 tolerance. Nanoscale 8, 3588 (2016).CrossRefGoogle ScholarPubMed
Boningari, T., Ettireddy, P.R., Somogyvari, A., and Liu, Y.: Influence of elevated surface texture hydrated titania on Ce-doped Mn/TiO2 catalysts for the low-temperature SCR of NOx under oxygen-rich conditions. J. Catal. 325, 145 (2015).CrossRefGoogle Scholar
Li, J., Hu, R., Zhang, J., Meng, W., Du, Y., Si, Y., and Zhang, Z.: Influence of preparation methods of La2CoMnO6/CeO2 on the methane catalytic combustion. Fuel 178, 148 (2016).CrossRefGoogle Scholar
Buciuman, F.C., Patcas, F., and Menezo, J.C.: Catalytic properties of La0.8A0.2MnO3 (A = Sr, Ba, K, Cs) and LaMn0.8B0.2O3 (B = Ni, Zn, Cu) perovskites: 1. Oxidation of hydrogen and propene. Appl. Catal. B Environ. 35, 175 (2002).CrossRefGoogle Scholar
Giroir-Fendler, A., Alves-Fortunato, M., Richard, M., Wnag, C., Díaz, J.A., Gil, S., Zhang, C., Can, F., Bion, N., and Guo, Y.: Synthesis of oxide supported LaMnO3 perovskites to enhance yields in toluene combustion. Appl. Catal. B Environ. 180, 29 (2016).CrossRefGoogle Scholar
Pang, H., Diao, Z., Wang, X., Ma, Y., Yu, S., Zhu, H., Chen, Z., Hu, B., Chen, J., and Wang, X.: Adsorptive and reductive removal of U(VI) by Dictyophora indusiate-derived biochar supported sulfide NZVI from wastewater. Chem. Eng. J. 366, 368 (2019).CrossRefGoogle Scholar
Wang, Y., Wang, Y., Yu, L., Wang, J., Du, B., and Zhang, X.: Enhanced catalytic activity of templated-double perovskite with 3D network structure for salicylic acid degradation under microwave irradiation: Insight into the catalytic mechanism. Chem. Eng. J. 368, 115 (2019).CrossRefGoogle Scholar
Xu, D., Lai, X., Guo, W., and Da, P.: Microwave-assisted catalytic degradation of methyl orange in aqueous solution by ferrihydrite/maghemite nanoparticles. J. Water Process Eng. 16, 270 (2017).CrossRefGoogle Scholar
Li, X., Yu, J., Low, J., Fang, Y., Xiao, J., and Chen, X.: Engineering heterogeneous semiconductors for solar water splitting. J. Mater. Chem. A 3, 2485 (2015).CrossRefGoogle Scholar
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