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A kaolinite-NMF-methanol intercalation compound as a versatile intermediate for further intercalation reaction of kaolinite

Published online by Cambridge University Press:  31 January 2011

Yoshihiko Komori ,
Yoshiyuki Sugahara  and
Kazuyuki Kuroda
Yoshihiko Komori
Affiliation:
Department of Applied Chemistry, School of Science and Engineering, Waseda University, Ohkubo-3, Shinjuku-ku, Tokyo 169, Japan
Yoshiyuki Sugahara
Affiliation:
Department of Applied Chemistry, School of Science and Engineering, Waseda University, Ohkubo-3, Shinjuku-ku, Tokyo 169, Japan
Kazuyuki Kuroda
Affiliation:
Department of Applied Chemistry, School of Science and Engineering, Waseda University, Ohkubo-3, Shinjuku-ku, Tokyo 169, Japan, and Kagami Memorial Laboratory for Materials Science and Technology, Waseda University, Nishiwaseda-2, Shinjuku-ku, Tokyo 169, Japan
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Abstract

A kaolinite-organic intercalation compound containing methanol was proved to be a versatile host for further displacement reaction with alkylamines. Kaolinite-organic intercalation compounds with polar molecules, such as N-methylformamide (NMF) and formamide, were used as the starting materials. After stirring the kaolinite-NMF intercalation compound with methanol, the basal spacing increased to 1.11 nm. The 13C MAS NMR result of the product indicated that methanol was intercalated into kaolinite by partial displacement with NMF. By use of the methanol-treated kaolinite intercalation compound as the intermediate, alkylamines were intercalated into the interlayer space of kaolinite by displacing with methanol.

Type
Articles
Information
Journal of Materials Research , Volume 13 , Issue 4 , April 1998 , pp. 930 - 934
Copyright
Copyright © Materials Research Society 1998

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