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Initial plasticity onset in Zr- and Hf-rich bulk metallic glasses during instrumented indentation

Published online by Cambridge University Press:  03 March 2011

Tyler D. Krus
Affiliation:
U.S. Army Research Laboratory, Weapons and Materials Research Directorate, Aberdeen Proving Ground, Maryland 21005
Thomas F. Juliano
Affiliation:
U.S. Army Research Laboratory, Weapons and Materials Research Directorate, Aberdeen Proving Ground, Maryland 21005
Laszlo J. Kecskes
Affiliation:
U.S. Army Research Laboratory, Weapons and Materials Research Directorate, Aberdeen Proving Ground, Maryland 21005
Mark R. VanLandingham*
Affiliation:
U.S. Army Research Laboratory, Weapons and Materials Research Directorate, Aberdeen Proving Ground, Maryland 21005
*
a) Address all correspondence to this author. e-mail: [email protected]
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Abstract

Sudden jumps in nanoindentation load-displacement curves of bulk metallic glasses (BMGs) signify the onset of plastic deformation. These events are investigated on varying compositions of Zr- and Hf-rich BMGs. Load-versus-displacement graphs for spherical indentations are analyzed to determine displacement, load, intensity of deformation, energy per volume, energy loss, and pressure corresponding to these key locations. Attention is focused on pressure, energy loss, and energy per volume at initial plasticity in response to varying strain rates, indenter tip radii, preload, and material composition. Energy loss was found to correlate with preload. The Zr-rich metallic glass was found to plastically deform in response to smaller loads than Hf-rich specimens.

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Copyright
Copyright © Materials Research Society 2007

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References

REFERENCES

1Klement, W., Willens, R.H., and Duwez, P.: Non-crystalline structure in solidified gold-silicon alloys. Nature 187, 869 (1960).CrossRefGoogle Scholar
2Johnson, W.L.: Bulk amorphous metal: An emerging engineering material. J. Min. Met. Mater. Soc. 54, 40 (2002).CrossRefGoogle Scholar
3Inoue, A.: Stabilization of metallic supercooled liquid and bulk amorphous alloys. Acta Mater. 48, 279 (2000).CrossRefGoogle Scholar
4Gu, X., Jiao, T., Kecskes, L.J., Woodman, R.H., Fan, C., Ramesh, K.T., and Hufnagel, T.C.: Crystallization and mechanical behavior of (Hf, Zr)-Ti-Cu-Ni-Al metallic glasses. J. Non-Cryst. Solids 317, 112 (2003).CrossRefGoogle Scholar
5Nagendra, N., Ramamurty, U., Goh, T.T., and Li, Y.: Effect of crystallinity on the impact toughness of a La-based bulk metallic glass. Acta Mater. 48, 2603 (2000).CrossRefGoogle Scholar
6Gilbert, C.J., Schroeder, V., and Ritchie, R.O.: Mechanisms for fracture and fatigue-crack propagation in a bulk metallic glass. Metall. Mater. Trans. A 30, 1739 (1999).CrossRefGoogle Scholar
7Vaillant, M.L., Keryvin, V., Rouxel, T., and Kawamura, Y.: Changes in the mechanical properties of a Zr55Cu30Al10Ni5 bulk metallic glass due to heat treatments below 540 °C. Scripta Mater. 47, 19 (2002).CrossRefGoogle Scholar
8Bakke, E., Busch, R., and Johnson, W.L.: The viscosity of the Zr46.75Ti8.25Cu7.5Ni10Be27.5 bulk metallic glass forming alloy in the supercooled liquid. Appl. Phys. Lett. 67, 3260 (1995).CrossRefGoogle Scholar
9Schuh, C.A. and Nieh, T.G.: A nanoindentation study of serrated flow in bulk metallic glasses. Acta Mater. 51, 87 (2003).CrossRefGoogle Scholar
10Jiang, W.H. and Atzmon, M.: Rate dependence of serrated flow in a metallic glass. J. Mater. Res. 18, 755 (2003).CrossRefGoogle Scholar
11Schuh, C.A., Nieh, T.G., and Kawamura, Y.: Rate dependence of serrated flow during nanoindentation of a bulk metallic glass. J. Mater. Res. 17, 1651 (2002).CrossRefGoogle Scholar
12Nieh, T.G., Schuh, C., Wadsworth, J., and Li, Y.: Strain rate-dependent deformation in bulk metallic glasses. Intermetallics 10, 1177 (2002).CrossRefGoogle Scholar
13Schuh, C.A. and Neih, T.G.: A survey of instrumented indentation studies on metallic glasses. J. Mater. Res. 19, 11 (2004).CrossRefGoogle Scholar
14Vaidyanathan, R., Dao, M., Ravichandran, G., and Suresh, S.: Study of mechanical deformation in bulk metallic glass through instrumented indentation. Acta Mater. 49, 3781 (2001).CrossRefGoogle Scholar
15Patnaik, M.N.M., Narasimhan, R., and Ramamurty, U.: Spherical indentation response of metallic glasses. Acta Mater. 52, 3335 (2004).CrossRefGoogle Scholar
16Kim, J-J., Choi, Y., Suresh, S., and Argon, A.S.: Nanocrystallization during nanoindentation of a bulk amorphous metal alloy at room temperature. Science 295, 654 (2002).CrossRefGoogle ScholarPubMed
17Zhang, H., Jing, X., Subhash, G., Kecskes, L.J., and Dowding, R.J.: Investigation of shear band evolution in amorphous alloys beneath a Vickers indentation. Acta Mater. 53, 3849 (2005).CrossRefGoogle Scholar
18Juliano, T., Domnich, V., Buchheit, T., and Gogotsi, Y.: Numerical derivative analysis of load-displacement curves in depth sensing indentation, in Mechanical Properties of Nanostructured Materials and Nanocomposites edited by Ovid’ko, I., Pande, C.S., Krishnamoorti, R., Lavernia, E. and Skandan, G. (Mater. Res. Soc. Symp. Proc. 791, Warrendale, PA, 2004), pp. Q7.5.1Q7.5.11.Google Scholar
19Concustell, A., Sort, J., Greer, A.L., and Baro, M.D.: Anelastic deformation of Pd40Cu30Ni10P20 bulk metallic glass during nanoindentation. Appl. Phys. Lett. 88, 171911 (2006).CrossRefGoogle Scholar
20VanLandingham, M., Juliano, T., and Hagon, M.: Measuring tip shape for instrumented indentation using atomic force microscopy. Meas. Sci. Technol. 16, 2173 (2005).CrossRefGoogle Scholar