Hostname: page-component-586b7cd67f-vdxz6 Total loading time: 0 Render date: 2024-11-22T21:35:03.430Z Has data issue: false hasContentIssue false
  • English
  • Français

Infrared reflectance spectroscopy of electrochromic NiOxHy films made by reactive dc sputtering

Published online by Cambridge University Press:  31 January 2011

W. Estrada ,
A.M. Andersson ,
C.G. Granqvist ,
A. Gorenstein  and
F. Decker
W. Estrada
Affiliation:
Physics Department, Chalmers University of Technology and University of Gothenburg, S-412 96 Gothenburg, Sweden
A.M. Andersson
Affiliation:
Physics Department, Chalmers University of Technology and University of Gothenburg, S-412 96 Gothenburg, Sweden
C.G. Granqvist
Affiliation:
Physics Department, Chalmers University of Technology and University of Gothenburg, S-412 96 Gothenburg, Sweden
A. Gorenstein
Affiliation:
DFA/IFGW, UNICAMP, CP 6165 Campinas, SP, Brazil
F. Decker
Affiliation:
DFA/IFGW, UNICAMP, CP 6165 Campinas, SP, Brazil
Get access

Abstract

Films of NiOxHy were made by reactive dc magnetron sputtering of Ni followed by electrochemical treatment in KOH. Infrared reflectance spectroscopy with obliquely incident p-polarized light documented a unique topochemical reaction with the bleached state being β–Ni(OH)2 and the colored state being β–NiOOH. The same technique yielded clear, though not yet fully understood, data on the evolution of electrochromism during potentiodynamic cycling.

Type
Articles
Information
Journal of Materials Research , Volume 6 , Issue 8 , August 1991 , pp. 1715 - 1719
Copyright
Copyright © Materials Research Society 1991

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1.Large-area Chromogenics: Materials and Devices for Transmittance Control, edited by Lampert, C. M. and Granqvist, C. G. (SPIE Opt. Engr. Press, Bellingham, 1990).Google Scholar
2.Proc. Symp. Electrochromic Materials, edited by Carpenter, M. K. and Corrigan, D. A. (The Electrochem. Soc, Pennington, 1990), Proc. Vol. 90–2.Google Scholar
3.Lampert, C. M., Solar Energy Mater. 11, 1 (1984).Google Scholar
4.Faughnan, B. W. and Crandall, R. S., in Display Devices, edited by Pankove, J. I., Topics in Advanced Physics (Springer, Berlin, 1980), Vol. 40, p. 181.Google Scholar
5.Oi, T., Ann. Rev. Mater. Sci. 16, 185 (1986).CrossRefGoogle Scholar
6.Donnadieu, A., Mater. Sci. Engr. B 3, 185 (1989).CrossRefGoogle Scholar
7.Svensson, J. S. E. M. and Granqvist, C. G., Appl. Phys. Lett. 49, 1566 (1986).CrossRefGoogle Scholar
8.Svensson, J. S. E. M. and Granqvist, C. G., Appl. Opt. 26, 1554 (1987).CrossRefGoogle Scholar
9.Estrada, W., Andersson, A. M., and Granqvist, C. G., J. Appl. Phys. 64, 3678 (1988).CrossRefGoogle Scholar
10.Oliva, P., Leonardi, J., Laurent, J. F., Delmas, C., Braconnier, J. J., Figlarz, M., Fievet, F., and de Guibert, A., J. Power Sources 8, 229 (1982).CrossRefGoogle Scholar
11.McBreen, J., in Modern Aspects of Electrochemistry, edited by White, R. E., Bockris, J.O'M., and Conway, B. O. (Plenum, New York, 1990), No. 21, p. 29.Google Scholar
12.Bode, H., Dehmelt, K., and Witte, J., Electrochim. Acta 11, 1079 (1966).CrossRefGoogle Scholar
13.Kober, F. P., J. Electrochem. Soc. 112, 1064 (1965); 114, 215 (1967).CrossRefGoogle Scholar
14.McBreen, J., O'Grady, W. E., Pandya, K. I., Hoffman, R. W., and Sayers, D. E., Langmuir 3, 428 (1987).Google Scholar
15.Decker, F. and Gorenstein, A. (unpublished results).Google Scholar
16.Andersson, A. M., Estrada, W., Granqvist, C. G., Gorenstein, A., and Decker, F., Proc. Soc. Photo-Opt. Instrum. Engr. 1272, 96 (1990).Google Scholar
17.Eriksson, T. S. and Granqvist, C. G., J. Appl. Phys. 60,2081 (1986).CrossRefGoogle Scholar
18. Donnelly Corp., Holland, MI.Google Scholar
19.Estrada, W., Ph. D. Thesis, Facultad de Ciencias, Universidad Nacional de Ingenieria, Lima, Peru, 1990 (unpublished).Google Scholar
20.Scarminio, J., Sahu, S. N., and Decker, F., J. Phys. E 22, 755 (1989).Google Scholar
21.Estrada, W., Andersson, A. M., Deckerm, F., and Gorenstein, A., in Ref. 2, p. 54.Google Scholar
22.Mclntyre, J. D. E. and Aspnes, D. E., Surf. Sci. 24, 417 (1971).CrossRefGoogle Scholar
23.Beden, B. and Lamy, C., in Spectroelectrochemistry: Theory and Practice, edited by Gale, R. J. (Plenum, New York, 1988), p. 189.CrossRefGoogle Scholar
24.Hamberg, I. and Granqvist, C. G., J. Appl. Phys. 60, R123 (1986).Google Scholar
25.Figlarz, M. and Bihan, S. Le, Comptes Rendues Acad. Sci. Paris, Ser. C 272, 580 (1971).Google Scholar
26.Shamina, I. S., Malandin, O. G., Rakhovskaya, S. M., and Vereshchagina, L. A., Elektrokhim. 10, 1571 (1974) [Soviet Electrochem. 10, 1494 (1974)].Google Scholar
27.Houalla, M., Perrichon, V., and Turlier, P., Comptes Rendues Acad. Sci. Paris, Ser. C 284, 1 (1977).Google Scholar
28.Minkova, N., Krusteva, M., and Nikolov, G., J. Mol. Struct. 115, 23 (1984).CrossRefGoogle Scholar
29.Rakhovskaya, S. M., Egorova, S. A., Bolotina, N. É., and Tugushev, R. É, Kolloid. Zh. 47, 195 (1985) [Colloid J. USSR 47, 168 (1985)].Google Scholar
30.Beden, B. and Bewick, A., Electrochim. Acta 33, 1695 (1988).CrossRefGoogle Scholar
31.Lynam, N. R. and Habibi, H. R., Proc. Soc. Photo-Opt. Instrum. Engr. 1016, 63 (1988).Google Scholar
32.Baraldi, P. and Davolio, G., Mater. Chem. Phys. 21, 143 (1989).CrossRefGoogle Scholar
33.Nazri, G., Corrigan, D. A., and Maheswari, S.P., Langmuir 5, 17 (1989).CrossRefGoogle Scholar
34.Yu, P. C. and Lampert, C. M., Solar Energy Mater. 19, 1 (1989).CrossRefGoogle Scholar
35.Johnston, C. and Graves, P. R., Appl. Spectrosc. 44, 105 (1990).Google Scholar
36.Lucchesi, P. J and Glasson, W. A, J. Am. Chem. Soc. 78, 1347 (1956).CrossRefGoogle Scholar
37.Wagner, W., Rauch, F., Ottermann, C., and Bange, K., Nucl. Instrum. Methods B 50, 27 (1990); K. Bange, C. Ottermann, W. Wagner, and F. Rauch, Proc. Soc. Photo-Opt. Instrum. Engr. 1272, 122 (1990).CrossRefGoogle Scholar
38.Lampert, C. M. and Caron-Popowich, R. S., Proc. Soc. Photo-Opt. Instrum. Engr. 1149, 56 (1989).Google Scholar
39.Goff, A. Hugot-Le, Joiret, S., and Cordoba de Torresi, S., in Ref. 2, p. 70; S.Cordoba-Torresi, A. Hugot-Le Goff, and H.Takenouti, Proc. Soc. Photo-Opt. Instrum. Engr. 1272, 152 (1990).Google Scholar