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Influence of Nanoparticle Surfaces on the Electrical Breakdown Strength of Nanoparticle-Filled Low-Density Polyethylene

Published online by Cambridge University Press:  03 March 2011

Dongling Ma ,
Richard W. Siegel ,
Jung-Il Hong ,
Linda S. Schadler ,
Eva Mårtensson  and
Carina Önneby
Dongling Ma
Affiliation:
Materials Science and Engineering Department and Rensselaer Nanotechnology Center, Rensselaer Polytechnic Institute, Troy, New York 12180
Richard W. Siegel
Affiliation:
Materials Science and Engineering Department and Rensselaer Nanotechnology Center, Rensselaer Polytechnic Institute, Troy, New York 12180
Jung-Il Hong
Affiliation:
Materials Science and Engineering Department and Rensselaer Nanotechnology Center, Rensselaer Polytechnic Institute, Troy, New York 12180
Linda S. Schadler
Affiliation:
Materials Science and Engineering Department and Rensselaer Nanotechnology Center, Rensselaer Polytechnic Institute, Troy, New York 12180
Eva Mårtensson
Affiliation:
ABB AB, Department H, Västerås, S-721 78, Sweden
Carina Önneby
Affiliation:
ABB AB, Department H, Västerås, S-721 78, Sweden
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Abstract

The electrical breakdown strength of TiO2 nanoparticle-filled low-density polyethylene (LDPE) nanocomposites was investigated. It was found that the surface water on the nanoparticles played a very important role in determining the breakdown strength. The breakdown strength at 63.2% cumulative failure probability (E0) for the composites filled with dried nanoscale TiO2 was similar to that of neat LDPE and 50% higher than that for the samples filled with as-received nanoscale TiO2. This increase was due to a better dispersion, a better interface, and a morphology change of the matrix. It was also found that surface modification of nanoscale TiO2 had a significant influence on the breakdown strength. N-(2-aminoethyl) 3-aminopropyl-trimethoxysilane (AEAPS)-coated TiO2-filled samples showed about 40% higher E0 than that of uncoated, as-received TiO2-filled samples. This was mainly due to enhanced electron scattering because of the presence of polar groups in AEAPS.

Keywords

Electrical propertiesDielectricNanoparticle
Type
Articles
Information
Journal of Materials Research , Volume 19 , Issue 3 , March 2004 , pp. 857 - 863
Copyright
Copyright © Materials Research Society 2004

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References

REFERENCES

1Tanaka, Y., Ohnuma, N., Katsunami, K. and Ohki, Y., IEEE Trans. Electr. Insul. 26, 258 (1991).CrossRefGoogle Scholar
2Hackam, R., IEEE Transactions on Dielectrics and Electrical Insulation 6, 557 (1999).CrossRefGoogle Scholar
3Ieda, M., IEEE Transactions on Dielectrics and Electrical Insulation 21, 793 (1986).CrossRefGoogle Scholar
4Ryfšavý, D. and TkadleČková, H., Polym. Degrad. Stabil. 37, 19 (1992).CrossRefGoogle Scholar
5Gächter, R. and Müller, H.: Plastics Additives Handbook (Hanser Publishers, Munich, 1990).Google Scholar
6Ashcraft, A.C., Eichhorn, R.M. and Shaw, R.G., in Conference Record of the 1976 IEEE International Symposium on Electrical Insulation (IEEE, Montreal, Canada, 1976), p.213.CrossRefGoogle Scholar
7Yamano, Y. and Endoh, H., IEEE Transactions on Dielectrics and Electrical Insulation 5, 270 (1998).CrossRefGoogle Scholar
8Sabuni, M.H. and Nelson, J.K., J. Mater. Sci. 14, 2791 (1979).CrossRefGoogle Scholar
9Ku, C.C. and Liepins, R.: Electrical Properties of Polymers: Chemical Principle (Hanser Publishers, Munich and New York, 1987).Google Scholar
10Khalil, M.S., IEEE Transactions on Dielectrics and Electrical Insulation 7, 261 (2000).CrossRefGoogle Scholar
11Chen, G. and Davies, A.E., IEEE Transactions on Dielectrics and Electrical Insulation 7, 401 (2000).CrossRefGoogle Scholar
12Fujita, S., Ruike, M. and Baba, M., in Conference on Electrical Insulation and Dielectric Phenomena (IEEE, San Francisco, 1996), p. 738.CrossRefGoogle Scholar
13Khalil, M.S., Henk, P.O. and Henriksen, M., in Conference Record of the 1990 IEEE International Symposium on Electrical Insulation (IEEE, Toronto, Canada, 1990), p.268.Google Scholar
14Electrical Properties of Polymers, edited by Seanor, D.A. (Academic Press, New York, 1982).Google Scholar
15Ueki, M.M. and Zanin, M., IEEE Transactions on Dielectrics and Electrical Insulation 6, 876 (1999).CrossRefGoogle Scholar
16Crist, B. and Mirabella, F.M., J. Polym. Sci. B, Polym. Phys. 37, 3131 (1999).3.0.CO;2-M>CrossRefGoogle Scholar
17Aggabwal, S.L. and Tilley, G.P., J. Polym. Sci. XVIII, 17 (1955).CrossRefGoogle Scholar
18Hosier, I.L., Vaughan, A.S. and Swingler, S.G., J. Mater. Sci. 32, 4523 (1997).CrossRefGoogle Scholar
19Ma, D., Rogers, D.F., Wu, N., Ash, B.J., Siegel, R.W., Apple, T., Benicewicz, B.C. and Schadler, L.S. (unpublished).Google Scholar
20Primet, M., Pichat, P. and Mathieu, M., J. Phys. Chem. 75, 1216 (1971).CrossRefGoogle Scholar
21Khalil, M.S., J. Polym. Mater. 41, 71 (1998).CrossRefGoogle Scholar
22Hosier, I.L., Vaughan, A.S. and Swingler, S.G., J. Polym. Sci. B, Polym. Phys. 38, 2309 (2000).3.0.CO;2-7>CrossRefGoogle Scholar
23Dissado, L.A., Doble, I., Wolfe, S.W., Norman, P.A., Davies, A.E., Chen, G., Zhong, Q., Wargotz, W.B. and Sanders, M.M., IEEE Transactions on Dielectrics and Electrical Insulation 4, 1 (1997).CrossRefGoogle Scholar