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In situ chemical synthesis of SnO2/reduced graphene oxide nanocomposites as anode materials for lithium-ion batteries

Published online by Cambridge University Press:  11 March 2014

Haijiao Zhang ,
Panpan Xu ,
Yang Ni ,
Hongya Geng ,
Guanghong Zheng ,
Bin Dong  and
Zheng Jiao
Haijiao Zhang
Affiliation:
Institute of Nanochemistry and Nanobiology, School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, People's Republic of China; and State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai 200433, People's Republic of China
Panpan Xu
Affiliation:
Institute of Nanochemistry and Nanobiology, School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, People's Republic of China
Yang Ni
Affiliation:
Institute of Nanochemistry and Nanobiology, School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, People's Republic of China
Hongya Geng
Affiliation:
Institute of Nanochemistry and Nanobiology, School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, People's Republic of China
Guanghong Zheng
Affiliation:
College of Environmental Science and Engineering, Tongji University, Shanghai 200092, People's Republic of China
Bin Dong*
Affiliation:
College of Environmental Science and Engineering, Tongji University, Shanghai 200092, People's Republic of China
Zheng Jiao*
Affiliation:
Institute of Nanochemistry and Nanobiology, School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, People's Republic of China
*
b)e-mail: [email protected]
a)Address all correspondence to these authors. e-mail: [email protected]
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Abstract

In the work, an in situ chemical synthesis approach has been developed to fabricate SnO2/reduced graphene oxide nanocomposites in ethanol solution. X-ray diffraction, x-ray photoelectron, Fourier transform infrared and Raman spectrum revealed the formation of SnO2/reduced graphene oxide nanocomposites. Scanning electron microscopy and transmission electron microscopy showed that SnO2 nanoparticles had a crystal size of about 3–4 nm and homogeneously distributed on reduced graphene oxide matrix. The electrochemical performances of the SnO2/reduced graphene oxide nanocomposites as anode materials were measured by the galvanostatic charge/discharge cycling. The results indicated that as-synthesized SnO2/reduced graphene oxide nanocomposites had a reversible lithium storage capacity of 1051 mAh/g and an enhanced cyclability, which can be attributed to increased electrode conductivity and buffer effect to volume change in the presence of a percolated reduced graphene oxide network embedded into the metal oxide electrodes.

Keywords

SnO2/reduced graphene oxidecompositeschemical synthesisanodelithium-ion batteries
Type
Articles
Information
Journal of Materials Research , Volume 29 , Issue 5 , 14 March 2014 , pp. 617 - 624
Copyright
Copyright © Materials Research Society 2014 

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References

REFERENCES

Paek, S.M., Yoo, E.J., and Honma, I.: Enhanced cyclic performance and lithium storage capacity of SnO2/graphene nanoporous electrodes with three-dimensionally delaminated flexible structure. Nano Lett. 9, 72 (2008).Google Scholar
Buqa, H., Goers, D., Holzapfel, M., Spah, M.E., and Novák, P.: High rate capability of graphite negative electrodes for lithium-ion batteries. J. Electrochem. Soc. 152, 474 (2005).CrossRefGoogle Scholar
Akl, N.N., Trofymluk, O., Qi, X., Kim, J.Y., Osterloh, F.E., and Navrotsky, A.: A nanowire-nanoparticle cross-linking approach to highly porous electrically conducting solids. Angew. Chem. Int. Ed. 118, 3735 (2006).CrossRefGoogle Scholar
Lou, X.W., Wang, Y., Yuan, C., Lee, J.Y., and Archer, L.A.: Template-free synthesis of SnO2 hollow nanostructures with high lithium storage capacity. Adv. Mater. 18, 2325 (2006).CrossRefGoogle Scholar
Chan, C.K., Zhang, X.F., and Cui, Y.: High capacity Li ion battery anodes using Ge nanowires. Nano Lett. 8, 307 (2008).CrossRefGoogle ScholarPubMed
Kim, D.W., Hwang, I.S., Kwon, S.J., Kang, H.Y., Park, K.S., Choi, Y.J., Choi, K.J., and Park, J.G.: Highly conductive coaxial SnO2-In2O3 heterostructured nanowires for Li ion battery electrodes. Nano Lett. 7, 3041 (2007).Google Scholar
Wang, Y., Lee, J.Y., and Zeng, H.C.: Polycrystalline SnO2 nanotubes prepared via infiltration casting of nanocrystallites and their electrochemical application. Chem. Mater. 17, 3899 (2005).Google Scholar
Liu, Y.L., Yang, H.F., Yang, Y., Liu, Z.M., Shen, G.L., and Yu, R.Q.: Gas sensing properties of tin dioxide coated onto multi-walled carbon nanotubes. Thin Solid Films 497, 355 (2006).Google Scholar
Han, W.Q. and Zettl, A.: Coating single-walled carbon nanotubes with tin oxide. Nano Lett. 3, 681 (2003).CrossRefGoogle Scholar
Fan, J., Wang, T., Yu, C., Tu, B., Jiang, Z., and Zhao, D.: Ordered, nanostructured tin-based oxides/carbon composite as the negative-electrode material for lithium-ion batteries. Adv. Mater. 16, 1432 (2004).Google Scholar
Wen, Z., Wang, Q., Zhang, Q., and Li, J.: In situ growth of mesoporous SnO2 on multiwalled carbon nanotubes: A novel composite with porous-tube structure as anode for lithium batteries. Adv. Funct. Mater. 17, 2772 (2007).Google Scholar
Fu, Y.B., Ma, R.B., Shu, Y., Cao, Z., and Ma, X.H.: Preparation and characterization of SnO2/carbon nanotube composite for lithium ion battery applications. Mater. Lett. 63, 1946 (2009).CrossRefGoogle Scholar
Wang, D., Choi, D., Li, J., Yang, Z., Nie, Z., Kou, R., Hu, D., Wang, C., Saraf, L.V., and Zhang, J.: Self-assembled TiO2-graphene hybrid nanostructures for enhanced Li-ion insertion. ACS Nano 3, 907 (2009).Google Scholar
Li, Y., Tang, L., and Li, J.: Preparation and electrochemical performance for methanol oxidation of Pt/graphene nanocomposites. Electrochem. Commun. 11, 846 (2009).Google Scholar
Wang, D.H., Kou, R., Choi, D.W., Yang, Z.G., Nie, Z.M., Li, J., Saraf, L.V., Hu, D.H., Zhang, J.G., Graff, G.L., Liu, J., Pope, M.A., and Aksay, I.A.: Ternary self-assembly of ordered metal oxide-graphene nanocomposites for electrochemical energy storage. ACS Nano 4, 1587 (2010).Google Scholar
Yao, J., Shen, X., Wang, B., Liu, H., and Wang, G.: In situ chemical synthesis of SnO2-graphene nanocomposite as anode materials for lithium-ion batteries. Electrochem. Commun. 11, 1849 (2009).Google Scholar
Wang, Y., Zeng, H.C., and Lee, J.Y.: Highly reversible lithium storage in porous SnO2 nanotubes with coaxially grown carbon nanotube overlayers. Adv. Mater. 18, 645 (2006).Google Scholar
Li, X., Wang, X., Zhang, L., Lee, S., and Dai, H.: Chemically derived, ultrasmooth graphene nanoribbon semiconductors. Science 319, 1229 (2008).CrossRefGoogle ScholarPubMed
Meyer, J.C., Geim, A., Katsnelson, M., Novoselov, K., Booth, T., and Roth, S.: The structure of suspended graphene sheets. Nature 446, 60 (2007).Google Scholar
Watcharotone, S., Dikin, D.A., Stankovich, S., Piner, R., Jung, I., Dommett, G.H.B., Evmenenko, G., Wu, S.E., Chen, S.F., Liu, C.P., Nguyen, S.T., and Ruoff, R.S.: Graphene-silica composite thin films as transparent conductors. Nano Lett. 7, 1888 (2007).Google Scholar
Wang, X., Zhi, L., and Müllen, K.: Transparent, conductive graphene electrodes for dye-sensitized solar cells. Nano Lett. 8, 323 (2008).Google Scholar
Gilje, S., Han, S., Wang, M., Wang, K.L., and Kaner, R.B.: A chemical route to graphene for device applications. Nano Lett. 7, 3394 (2007).Google Scholar
Sun, Y., Li, C., Xu, Y., Bai, H., Yao, Z., and Shi, G.: Chemically converted graphene as substrate for immobilizing and enhancing the activity of a polymeric catalyst. Chem. Commun. 46, 4740 (2010).CrossRefGoogle ScholarPubMed
Yang, H., Hu, Y., Tang, A., Jin, S., and Qiu, G.: Synthesis of tin oxide nanoparticles by mechanochemical reaction. J. Alloys Compd. 363, 276 (2004).Google Scholar
An, G., Na, N., Zhang, X., Miao, Z., Miao, S., Ding, K., and Liu, Z.: SnO2/carbon nanotube nanocomposites synthesized in supercritical fluids: Highly efficient materials for use as a chemical sensor and as the anode of a lithium-ion battery. Nanotechnology 18, 435707 (2007).Google Scholar
Stankovich, S., Piner, R.D., Nguyen, S.T., and Ruoff, R.S.: Synthesis and exfoliation of isocyanate-treated graphene oxide nanoplatelets. Carbon 44, 3342 (2006).Google Scholar
Akhavan, O.: The effect of heat treatment on formation of graphene thin films from graphene oxide nanosheets. Carbon 48, 509 (2010).Google Scholar
Yang, D., Velamakanni, A., Bozoklu, G., Park, S., Stoller, M., Piner, R.D., Stankovich, S., Jung, I., Field, D.A., and Ventrice, C.A. Jr.: Chemical analysis of graphene oxide films after heat and chemical treatments by X-ray photoelectron and micro-Raman spectroscopy. Carbon 47, 145 (2009).Google Scholar
Akhavan, O.: Graphene nanomesh by ZnO nanorod photocatalysts. ACS nano 4, 4174 (2010).Google Scholar
Tuinstra, F. and Koenig, J.L.: Raman spectrum of graphite. J. Chem. Phys. 53, 1126 (1970).CrossRefGoogle Scholar
Stankovich, S., Dikin, D.A., Piner, R.D., Kohlhaas, K.A., Kleinhammes, A., Jia, Y., Wu, Y., Nguyen, S.T., and Ruoff, R.S.: Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon 45, 1558 (2007).Google Scholar
Lee, K.T., Lytle, J.C., Ergang, N.S., Oh, S.M., and Stein, A.: Synthesis and rate performance of monolithic macroporous carbon electrodes for lithium-ion secondary batteries. Adv. Funct. Mater. 15, 547 (2005).Google Scholar
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