Hostname: page-component-586b7cd67f-2plfb Total loading time: 0 Render date: 2024-11-23T18:30:38.086Z Has data issue: false hasContentIssue false
  • English
  • Français

High energy density lithium-ion batteries with carbon nanotube anodes

Published online by Cambridge University Press:  31 January 2011

Brian J. Landi ,
Cory D. Cress  and
Ryne P. Raffaelle
Brian J. Landi*
Affiliation:
Chemical and Biomedical Engineering, and NanoPower Research Labs, Rochester Institute of Technology, Rochester, New York 14623
Cory D. Cress*
Affiliation:
United States Naval Research Laboratory, Washington, District of Columbia
Ryne P. Raffaelle
Affiliation:
NanoPower Research Labs, Rochester Institute of Technology, Rochester, New York 14623
*
a)Address all correspondence to this author. e-mail: [email protected]
b)Both authors contributed equally to this publication.
Get access

Abstract

Recent advancements using carbon nanotube electrodes show the ability for multifunctionality as a lithium-ion storage material and as an electrically conductive support for other high capacity materials like silicon or germanium. Experimental data show that replacement of conventional anode designs, which use graphite composites coated on copper foil, with a freestanding silicon-single-walled carbon nanotube (SWCNT) anode, can increase the usable anode capacity by up to 20 times. In this work, a series of calculations were performed to elucidate the relative improvement in battery energy density for such anodes paired with conventional LiCoO2, LiFePO4, and LiNiCoAlO2 cathodes. Results for theoretical flat plate prismatic batteries comprising freestanding silicon-SWCNT anodes with conventional cathodes show energy densities of 275 Wh/kg and 600 Wh/L to be theoretically achievable; this is a 50% improvement over today's commercial cells.

Keywords

NanostructureEnergy storageLi
Type
Articles
Information
Journal of Materials Research , Volume 25 , Issue 8: Materials for Electrical Energy Storage , August 2010 , pp. 1636 - 1644
Copyright
Copyright © Materials Research Society 2010

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Endo, M., Kim, C., Nishimura, K., Fujino, T., Miyashita, K.Recent development of carbon materials for Li ion batteries. Carbon 38, 183 (2000)CrossRefGoogle Scholar
2.Ehrlich, G.M.Lithium-ion batteriesHandbook of Batteries 3rd edited by D. Linden and T.B. Reddy (McGraw-Hill, New York 2002)35.135.94Google Scholar
3.Howard, W.F., Spotnitz, R.M.Theoretical evaluation of high-energy lithium metal phosphate cathode materials in Li-ion batteries. J. Power Sources 165, 887 (2007)CrossRefGoogle Scholar
4.Whittingham, M.S.Lithium batteries and cathode materials. Chem. Rev. 104, 4271 (2004)CrossRefGoogle ScholarPubMed
5.Landi, B.J., Ganter, M.J., Cress, C.D., DiLeo, R.A., Raffaelle, R.P.Carbon nanotubes for lithium ion batteries. Energy Environ. Sci. 2, 638 (2009)CrossRefGoogle Scholar
6.Hossain, S., Saleh, Y., Loutfy, R.Carbon-carbon composite as anodes for lithium-ion battery systems. J. Power Sources 96, 5 (2001)CrossRefGoogle Scholar
7.Chan, C.K., Zhang, X.F., Cui, Y.High capacity Li ion battery anodes using Ge nanowires. Nano Lett. 8, 307 (2008)CrossRefGoogle ScholarPubMed
8.Meduri, P., Pendyala, C., Kumar, V., Sumanasekera, G.U., Sunkara, M.K.Hybrid tin oxide nanowires as stable and high capacity anodes for Li-ion batteries. Nano Lett. 9, 612 (2009)CrossRefGoogle ScholarPubMed
9.Lagarias, J.C., Reeds, J.A., Wright, M.H., Wright, P.E.Convergence properties of the Nelder–Mead simplex method in low dimensions. SIAM J. Optim. 9, (1)112 (1998)CrossRefGoogle Scholar
10.Lee, S.I., Kim, Y.S., Chun, H.S.Modeling on lithium insertion of porous carbon electrodes. Electrochim. Acta 47, 1055 (2002)CrossRefGoogle Scholar
11.Landi, B.J., Ganter, M.J., Schauerman, C.M., Cress, C.D., Raffaelle, R.P.Lithium ion capacity of single wall carbon nanotube paper electrodes. J. Phys. Chem. C 112, 7509 (2008)CrossRefGoogle Scholar
12.Nechev, K.3rd Annual International Conference Lithium Mobile Power, San Diego, CA, 2007 (The Knowledge Foundation Press, San Diego, CA 2007)Google Scholar
13.Landi, B.J., DiLeo, R.A., Schauerman, C.M., Cress, C.D., Ganter, M.J., Raffaelle, R.P.Multi-walled carbon nanotube paper anodes for lithium ion batteries. J. Nanosci. Nanotechnol. 9, 3406 (2009)CrossRefGoogle ScholarPubMed