Hostname: page-component-78c5997874-xbtfd Total loading time: 0 Render date: 2024-11-06T02:12:27.719Z Has data issue: false hasContentIssue false
  • English
  • Français

Graphite-alkali metal-heavy metal ternary compounds: Synthesis, structure, and superconductivity

Published online by Cambridge University Press:  31 January 2011

Philippe Lagrange
Philippe Lagrange
Affiliation:
Laboratoire de Chimie du Solids Minéral (U.A. C.N.R.S. 158), Université de Nancy I, B.P. 239, 54506-Vandoeuvre-lès-Nancy Cédex, France
Get access

Abstract

The main results regarding the synthesis of the graphite intercalation compounds containing a metallic alloy (constituted by an alkali metal and a heavy metal: mercury, thallium, or bismuth) are reported. The synthesis conditions are described: reaction temperatures, compositions of the reactive alloys, and reaction mechanisms. The differences of behavior of the various alloys with respect to the graphite are explained. The structure of the ternary phases is described, and their superconducting properties are reported.

Type
Articles
Information
Journal of Materials Research , Volume 2 , Issue 6 , December 1987 , pp. 839 - 845
Copyright
Copyright © Materials Research Society 1987

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1Fredenhagen, K. and Cadenbach, G., Z. Anorg. Allg. Chem. 158, 249 (1926).CrossRefGoogle Scholar
2Rüdorff, W. and Schulze, E., Z. Anorg. Allg. Chem. 277, 156 (1954).CrossRefGoogle Scholar
3Hérold, A., Bull. Soc. Chim. Fr. Bull. Soc. Chim. Fr. 1955, 999.Google Scholar
4Métrot, A. and Herold, A., J. Chim. Phys. 1969, 71.CrossRefGoogle Scholar
5Guérard, D. and Herold, A., C. R. Acad. Sci. Paris C275, 571 (1972).Google Scholar
6Guérard, D. and Herold, A., C. R. Acad. Sci. Paris, C 279, 455 (1974); C 280, 729 (1975).Google Scholar
7Guérard, D. and Herold, A., C. R. Acad. Sci. Paris, C 281, 929 (1975).Google Scholar
8Billaud, D. and Herold, A., Bull. Soc. Chim. Fr. 103 (1972); 1974, 2407.Google Scholar
9Billaud, D. and Herold, A., Bull. Soc. Chim. Fr. 1974, 2715.Google Scholar
10York, B. R., Hark, S. K., and Solin, S., Synth. Met. 7, 25 (1983).CrossRefGoogle Scholar
11Billaud, D. and Herold, A., Bull. Soc. Chim. Fr. 1978, 131.Google Scholar
12Makrini, M. El, Lagrange, P., Guerard, D., and Herold, A., Carbon 18, 211 (1980).CrossRefGoogle Scholar
13Makrini, M. El, Lagrange, P., and Herold, A., Carbon 18, 374 (1980).CrossRefGoogle Scholar
14Lagrange, P., Makrini, M. El, and Herold, A., C. R. Acad. Sci. Paris C 290, 283 (1980).Google Scholar
15Lagrange, P., Bendriss-Rerhrhaye, A., Mareche, J. F., and McRae, E., Synth. Met. 12, 201 (1985).CrossRefGoogle Scholar
16Lagrange, P., Makrini, M. El, and Herold, A., Rev. Chim. Miner. 20, 229 (1983).Google Scholar
17Lagrange, P., Carbon 22, 315 (1984).CrossRefGoogle Scholar
18Bendriss-Rerhrhaye, A., Rousseaux, F., and Lagrange, P., Synth. Met. (to be published).Google Scholar
19Hansen, M., Constitution of Binary Alloys, Materials Science and Engineering Series (Elsevier, New York, 1958).Google Scholar
20Timp, G., Elman, B. S., Al-Jishi, R., and Dresselhaus, G., Solid State Commun. 44, 987 (1982).CrossRefGoogle Scholar
21Bendriss-Rerhrhaye, A., Thesis, Universite de Nancy, 1986.Google Scholar
22Lagrange, P., Mater. Res. Soc. Symp. Proc. EA-8, 155 (1986).Google Scholar
23Lagrange, P., Makrini, M. El, Guerard, D., and Herold, A., Synth. Met. 2, 191 (1980).CrossRefGoogle Scholar
24Makrini, M. El, Thesis, Universite de Nancy, 1980.Google Scholar
25Yang, M. H., Eklund, P. C., and Kamitakahara, W. A., Mater. Res. Soc. Symp. Proc. EA-2, 125 (1984).Google Scholar
26Roth, G., Yeh, N. C., Chaiken, A., Dresselhaus, G., and Tedrow, P. M., Mat. Res. Soc. Symp. Proc. EA-2, 149 (1984).Google Scholar
27Yang, M. H. and Eklund, P. C., Mater. Res. Soc. Symp. Proc. EA-8, 161 (1986).Google Scholar
28lye, Y. and Tanuma, S., Phys. Rev. B 25, 4583 (1982).Google Scholar
29Wachnik, R. A., Pendrys, L. A., Vogel, F. L., and Lagrange, P., Solid State Commun. 43, 5 (1982).CrossRefGoogle Scholar
30Roth, G., Chaiken, A., Enoki, T., Yeh, N. C., Dresselhaus, G., and Tedrow, P. M., Phys. Rev. B. 32, 533 (1985).CrossRefGoogle Scholar
31McRae, E., Mareche, J. F., Bendriss-Rerhrhaye, A., Lagrange, P., and Lelaurain, M., Ann. Phys. 11, 13 (1985).Google Scholar
32.Yang, H., Eklund, P. C., and Delong, L. E. (to be published).Google Scholar
33Chaiken, A., Yeh, N. C., Dresselhaus, G., and Tedrow, P. M., Mater. Res. Soc. Symp. Proc. EA-8, 158 (1986).Google Scholar
34Stang, I., Luders, K., Geiser, V., and Guntherodt, H. J., Synth. Met. (to be published).Google Scholar
35Marèché, J. F., McRae, E., Bendriss-Rerhrhaye, A., and Lagrange, P., J. Phys. Chem. Solids 47, 477 (1986).CrossRefGoogle Scholar