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Graphite-alkali metal-heavy metal ternary compounds: Synthesis, structure, and superconductivity

Published online by Cambridge University Press:  31 January 2011

Philippe Lagrange
Philippe Lagrange
Affiliation:
Laboratoire de Chimie du Solids Minéral (U.A. C.N.R.S. 158), Université de Nancy I, B.P. 239, 54506-Vandoeuvre-lès-Nancy Cédex, France
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Abstract

The main results regarding the synthesis of the graphite intercalation compounds containing a metallic alloy (constituted by an alkali metal and a heavy metal: mercury, thallium, or bismuth) are reported. The synthesis conditions are described: reaction temperatures, compositions of the reactive alloys, and reaction mechanisms. The differences of behavior of the various alloys with respect to the graphite are explained. The structure of the ternary phases is described, and their superconducting properties are reported.

Type
Articles
Information
Journal of Materials Research , Volume 2 , Issue 6 , December 1987 , pp. 839 - 845
Copyright
Copyright © Materials Research Society 1987

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