Hostname: page-component-cd9895bd7-q99xh Total loading time: 0 Render date: 2024-12-24T13:48:43.723Z Has data issue: false hasContentIssue false
  • English
  • Français

Enhanced supercapacitor performance based on 3D porous graphene with MoO2 nanoparticles

Published online by Cambridge University Press:  28 November 2016

Lina Zhang ,
Hongtao Lin ,
Liming Zhai ,
Mengfan Nie ,
Jin Zhou  and
Shuping Zhuo
Lina Zhang
Affiliation:
School of Chemical Engineering, Shandong University of Technology, Zibo 255049, People’s Republic of China
Hongtao Lin*
Affiliation:
School of Chemical Engineering, Shandong University of Technology, Zibo 255049, People’s Republic of China
Liming Zhai
Affiliation:
School of Chemical Engineering, Shandong University of Technology, Zibo 255049, People’s Republic of China
Mengfan Nie
Affiliation:
School of Chemical Engineering, Shandong University of Technology, Zibo 255049, People’s Republic of China
Jin Zhou
Affiliation:
School of Chemical Engineering, Shandong University of Technology, Zibo 255049, People’s Republic of China
Shuping Zhuo*
Affiliation:
School of Chemical Engineering, Shandong University of Technology, Zibo 255049, People’s Republic of China
*
a) Address all correspondence to these authors. e-mail: [email protected]
b) e-mail: [email protected]
Get access

Abstract

Three dimensional (3D) porous graphene decorated with MoO2 nanoparticles were successfully synthesized by hydrothermal method and characterized by SEM and TEM, x-ray diffraction, Raman spectra, x-ray photoelectron spectroscopy, nitrogen adsorption–desorption analysis and electrochemical experiments. The results revealed that the in situ formed monoclinic MoO2 nanoparticles were randomly decorated on the surface of graphene sheets and the obtained graphene–MoO2 nanohybrids were 3D porous structures. The mass ratio of molybdenum precursor with GO has effects on the specific surface area and the electrochemical properties of the nanocomposite. The M30G1 (the mass ratio of molybdenum precursor with GO was 30:1) composite electrode exhibited a higher specific capacitance and better cycling stability. The specific capacitances were 356 F/g at the current density of 0.1 A/g in KOH electrolyte, which predicted their potential application in energy storage. The electrochemical performance of M30G1 composite was also investigated in Na2SO4 electrolyte, which was poorer than that in KOH electrolyte. Therefore, the chosen of electrolyte is important to materials performance.

Keywords

MoO2graphenecompositesupercapacitorshydrothermal
Type
Articles
Information
Journal of Materials Research , Volume 32 , Issue 2 , 27 January 2017 , pp. 292 - 300
Check for updates
Copyright
Copyright © Materials Research Society 2016 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Wang, G., Zhang, L., and Zhang, J.: A review of electrode materials for electrochemical supercapacitors. Chem. Soc. Rev. 41, 797 (2012).Google Scholar
Huang, Y., Liang, J., and Chen, Y.: An overview of the applications of graphene-based materials in supercapacitors. Small 8, 1805 (2012).CrossRefGoogle ScholarPubMed
Shao, Y., El-Kady, M.F., Wang, L.J., Zhang, Q., Li, Y., Wang, H., Mousavi, M.F., and Kaner, R.B.: Graphene-based materials for flexible supercapacitors. Chem. Soc. Rev. 44, 3639–3665 (2015).Google Scholar
Patil, S., Harle, A., Sathaye, S., and Patil, K.: Development of a novel method to grow mono-/few-layered MoS2 films and MoS2–graphene hybrid films for supercapacitor applications. CrystEngComm 16, 10845 (2014).Google Scholar
Gao, N. and Fang, X.: Synthesis and development of graphene–inorganic semiconductor nanocomposites. Chem. Rev. 115, 8294 (2015).Google Scholar
Prakash, A. and Bahadur, D.: The role of ionic electrolytes on capacitive performanceof ZnO–reduced graphene oxide nanohybrids with thermally tunable morphologies. ACS Appl. Mater. Interfaces 6, 1394 (2014).Google Scholar
Wang, Y., He, P., Lei, W., Dong, F., and Zhang, T.: Novel FeMoO4/graphene composites based electrode materials for supercapacitors. Compos. Sci. Technol. 103, 16 (2014).Google Scholar
Li, Y., Zhao, N., Shi, C., Liu, E., and He, C.: Improve the supercapacity performanceof MnO2-decorated graphene by controlling the oxidization extent of graphene. J. Phys. Chem. C 116, 25226 (2012).Google Scholar
Marlinda, A.R., Huang, N.M., Muhamad, M.R., An’amt, M.N., Chang, B.Y.S., Yusoff, N., Harrison, I., Lim, H.N., Chia, C.H., and Kumar, S.V.: Highly efficient preparation of ZnO nanorods decorated reduced graphene oxide nanocomposites. Mater. Lett. 80, 9 (2012).Google Scholar
Liu, Y., Jiao, Y., Zhang, Z., Qu, F., Umar, A., and Wu, X.: Hierarchical SnO2 nanostructures made of intermingled ultrathin nanosheets for environmental remediation, smart gas sensor, and supercapacitor applications. ACS Appl. Mater. Interfaces 6, 2174 (2014).CrossRefGoogle ScholarPubMed
Huguenin, F. and Torresi, R.M.: Investigation of the electrical and electrochemical properties of nanocomposites from V2O5, polypyrrole, and polyaniline. J. Phys. Chem. C 112, 2202 (2008).Google Scholar
Yu, W.J., Hou, P.X., Zhang, L.L., Li, F., Liu, C., and Cheng, H.M.: Preparation and electrochemical property of Fe2O3 nanoparticles-filled carbon nanotubes. Chem. Commun. 46, 8576 (2010).Google Scholar
Li, G.R., Wang, Z.L., Zheng, F.L., Ou, Y.N., and Tong, Y.X.: ZnO@MoO3 core/shell nanocables: facile electrochemical synthesis and enhanced supercapacitor performances. J. Mater. Chem. 21, 4217 (2011).CrossRefGoogle Scholar
Zhou, J., Song, J., Li, H., Feng, X., Huang, Z., Chen, S., Ma, Y., Wang, L., and Yan, X.: The synthesis of shape-controlled α-MoO3/graphene nanocomposites for high performance supercapacitors. New J. Chem. 39, 8780 (2015).Google Scholar
Wu, X., Zeng, Y., Gao, H., Su, J., Liu, J., and Zhu, Z.: Template synthesis of hollow fusiform RuO2·xH2O nanostructure and its supercapacitor performance. J. Mater. Chem. A 1, 469 (2013).Google Scholar
Giardi, R., Porro, S., Topuria, T., Thompson, L., Pirri, C.F., and Kim, H.C.: One-pot synthesis of graphene–molybdenum oxide hybrids and their application to supercapacitor electrodes. Appl. Mater. Today 1, 27 (2015).CrossRefGoogle Scholar
Hu, S., Yin, F., Uchaker, E., Chen, W., Zhang, M., Zhou, J., Qi, Y., Cao, G., Qi, Y., Cao, G.: Facile, and Green Preparation for the formation of MoO2–GO composites as anode material for lithium-ion batteries. J. Phys. Chem. C 118, 24890 (2014).Google Scholar
Zhang, X., Zeng, X., Yang, M., and Qi, Y.: Investigation of a branchlike MoO3/polypyrrole hybrid with enhanced electrochemical performance used as an electrode in supercapacitors. ACS Appl. Mater. Inter. 6, 1125 (2013).Google Scholar
Feng, C., Gao, H., Zhang, C., Guo, Z., and Liu, H.: Synthesis and electrochemical properties of MoO3/C nanocomposite. Electrochim. Acta 93, 101 (2013).Google Scholar
Palanisamy, K., Kim, Y., Kim, H., Kim, J.M., and Yoon, W.S.: Self-assembled porous MoO2/graphene microspheres towards high performance anodes for lithium ion batteries. J. Power Sources, 275, 351 (2015).Google Scholar
Yang, L.C., Sun, W., Zhong, Z.W., Liu, J.W., Gao, Q.S., Hu, R.Z., and Zhu, M.: Hierarchical MoO2/N-doped carbon heteronanowires with high rate and improved long-term performance for lithium-ion batteries. J. Power Sources 306, 78 (2016).Google Scholar
Zhou, Y., Liu, Q., Liu, D., Xie, H., Wu, G., Huang, W., Tian, Y., He, Q., Khalil, A., Haleem, Y.A., Xiang, T., Chu, W., Zou, C., and Song, L.: Carbon-coated MoO2 dispersed in three-dimensional graphene aerogel for lithium-ion battery. Electrochim. Acta 174, 8 (2015).CrossRefGoogle Scholar
Hou, S., Zhang, G., Zeng, W., Zhu, J., Gong, F., Li, F., and Duan, H.: Hierarchical core–shell structure of ZnO Nanorod@NiO/MoO2 composite nanosheet arrays for high-performance supercapacitors. ACS Appl. Mater. Interfaces 6, 13564 (2014).Google Scholar
Hercule, K.M., Wei, Q., Khan, A.M., Zhao, Y., Tian, X., and Mai, L.: Synergistic effect of hierarchical nanostructured MoO2/Co(OH)2 with largely enhanced pseudocapacitor cyclability. Nano Lett. 13, 5685 (2013).Google Scholar
Bhaskar, A., Deepa, M., Rao, T.N., and Varadaraju, U.V.: Enhanced nanoscale conduction capability of a MoO2/graphene composite for high performance anodes in lithium ion batteries. J. Power Sources 216, 169 (2012).Google Scholar
Yang, L.C., Gao, Q.S., Tang, Y., Wu, Y.P., and Holze, R.: MoO2 synthesized by reduction of MoO3 with ethanol vapor as an anode material with good rate capability for the lithium ion battery. J. Power Sources 179, 357 (2008).Google Scholar
Xu, X., Liu, Y., Wang, M., Zhu, C., Lu, T., Zhao, R., and Pan, L.; Hierarchical hybrids with microporous carbon spheres decorated three-dimensional graphene frameworks for capacitive applications in supercapacitor and deionization. Electrochim. Acta 193, 88 (2016).Google Scholar
Jana, M., Saha, S., Samanta, P., Murmu, N.C., Kim, N.H., Kuila, T., and Lee, J.H.: Growth of Ni–Co binary hydroxide on a reduced graphene oxide surface by a successive ionic layer adsorption and reaction (SILAR) method for high performance asymmetric supercapacitor electrodes. J. Mater. Chem. A 4, 2188 (2016).Google Scholar
Ratha, S. and Rout, C.S.: Supercapacitor electrodes based on layered tungsten disulfide-reduced graphene oxide hybrids synthesized by a facile hydrothermal method. ACS Appl. Mater. Interfaces 5, 11427 (2013).Google Scholar
Yu, J., Wu, J., Wang, H., Zhou, A., Huang, C., Bai, H., and Li, L.: Metallic fabrics as the current collector for high-performance graphene-based flexible solid-state supercapacitor. ACS Appl. Mater. Interfaces 8, 4724 (2016).Google Scholar
Qian, L. and Lu, L.: Fabrication of three-dimensional porous graphene–manganese dioxide composites as electrode materials for supercapacitors. Colloids Surf., A 465, 32 (2015).Google Scholar
Kim, T., Ramadoss, A., Saravanakumar, B., Veerasubramani, G.K., and Kim, S.J.: Synthesis and characterization of NiCo2O4 nanoplates as efficient electrode materials for electrochemical supercapacitors. Appl. Surf. Sci. 370, 452 (2016).Google Scholar
Deng, J., Wang, X., Duan, X., and Liu, P.: Facile preparation of MnO2/graphene nanocomposites with spent battery powder for electrochemical energy storage. ACS Sustainable Chem. Eng. 3, 1330 (2015).Google Scholar
Zhang, J., Liu, F., Cheng, J.P., and Zhang, X.B.: Binary nickel–cobalt oxides electrode materials for high-performance supercapacitors: Influence of its composition and porous nature. ACS Appl. Mater. Interfaces 7, 17630 (2015).Google Scholar
Tao, H.C., Zhu, S.C., Yang, X.L., Zhang, L.L., and Ni, S.B.: Systematic investigation of reduced graphene oxide foams for high-performance supercapacitors. Electrochim. Acta 190, 168 (2016).Google Scholar
Karthika, P., Rajalakshmi, N., and Dhathathreyan, K.S.: Functionalized exfoliated graphene oxide as supercapacitor electrodes. Soft Nanosci. Lett. 2, 59 (2012).Google Scholar
Zhu, C., Liu, T., Qian, F., Han, T.Y., Duoss, E.B., Kuntz, J.D., Spadaccini, C.M., Worsley, M.A., and Li, Y.: Supercapacitors based on three-dimensional hierarchical graphene aerogels with periodic macropores. Nano lett. 16, 3448 (2016).Google Scholar
Zou, Y., Wang, Q., Xiang, C., She, Z., Chu, H., Qiu, S., Xu, F., Liu, S., Tang, C., and Sun, L.: One-pot synthesis of ternary polypyrrole–Prussian-blue–graphene-oxide hybrid composite as electrode material for high-performance supercapacitors. Electrochim. Acta 188, 126 (2016).Google Scholar