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Electrically active organic and polymeric materials for thin-film-transistor technologies

Published online by Cambridge University Press:  31 January 2011

Andrew J. Lovinger
Affiliation:
Bell Laboratories, Lucent Technologies, Murray Hill, New Jersey 07974
Lewis J. Rothberg
Affiliation:
Bell Laboratories, Lucent Technologies, Murray Hill, New Jersey 07974
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Abstract

Organic and polymeric materzials have seen a tremendous growth in research in the last five years as potential electroactive elements in thin-film-transistor (TFT) applications. These are driven by the increasing interest in flat-panel-display applications, for which organic and polymeric materials offer strong promise in terms of properties, processability, cost, and compatibility with eventual lightweight, flexible plastic displays. In this review we summarize the current status of our knowledge on the science of these organic and polymeric semiconducting materials. Most of these are based on linear thiophenes, especially a-hexathienyl, which has elicited by far the most attention. Mobility values in the 10−2–10−1 cm2/Vs and especially source-drain current on/off ratios of up to 106 make this a highly promising potential alternative to amorphous silicon. Other thienyl compounds are also discussed, as are polymeric analogues. A brief discussion of technological potential, limitations, and problems that need to be overcome is given at the end.

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Articles
Copyright
Copyright © Materials Research Society 1996

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References

REFERENCES

1.Wegner, G., Angew. Chem. Int. Ed. Engl. 20, 361 (1981).CrossRefGoogle Scholar
2.Baughman, R. H., Bredas, J. L., Chance, R. R., Elsenbaumer, R., and Schacklette, L. W., Chem. Rev. 82, 209 (1982).CrossRefGoogle Scholar
3.Greene, R. L. and Street, G. B., Science 226, 651 (1984).CrossRefGoogle Scholar
4.Jerome, D. and Schultz, H. J., Adv. Phys. 31, 299 (1982).CrossRefGoogle Scholar
5.Narita, M. and Pittman, C. U. Jr., Synthesis 489 (1976).CrossRefGoogle Scholar
6.Marks, T. J., Science 227, 881 (1985).CrossRefGoogle Scholar
7.Clarisse, C., Riou, M. T., Ganeau, M., and LeContellec, M., Electron. Lett. 24, 674 (1988).CrossRefGoogle Scholar
8.Tsukamoto, J., Ohigashi, H., Matsumura, K., and Akio, T., Synth. Metals 4, 177 (1982).CrossRefGoogle Scholar
9.Tsumura, A., Koezuka, H., and Ando, T., Synth. Metals 25, 11 (1988).CrossRefGoogle Scholar
10.Burroughes, J. H., Jones, C. A., and Friend, R. H., Nature (London) 335, 137 (1988).CrossRefGoogle Scholar
11.Horowitz, G., Fichou, D., Peng, X., Xu, Z., and Garnier, F., Solid State Commun. 72, 381 (1989).CrossRefGoogle Scholar
12.Fichou, D., Horowitz, G., Nishikitani, Y., and Garnier, F., Synth. Metals 28, C723 (1989).CrossRefGoogle Scholar
13.Fichou, D., Horowitz, G., Nishikitani, Y., and Garnier, F., Chemtronics 3, 176 (1988).Google Scholar
14.Horowitz, G., Fichou, D., and Garnier, F., Solid State Commun. 70, 385 (1989).CrossRefGoogle Scholar
15.Horowitz, G., Peng, X., Fichou, D., and Garnier, F., J. Appl. Phys. 67, 528 (1989).CrossRefGoogle Scholar
16.Dodabalapur, A., Torsi, L., and Katz, H. E., Science 268, 270 (1995).CrossRefGoogle Scholar
17.Fichou, D., Horowitz, G., and Garnier, F., French Pat. 8907610 (1989); Eur. Pat. 402269 (1990).Google Scholar
18.Katz, H. E., Dodabalapur, A., Torsi, L., Lovinger, A. J., and Ruel, R., Am. Chem. Soc. Polym. Mater. Sci. / Engr. 72, 467 (1995).Google Scholar
19.Garnier, F., Horowitz, G., Peng, X. Z., and Fichou, D., Synth. Met. 45, 163 (1991).CrossRefGoogle Scholar
20.Kagan, J. and Arora, S. K., Heterocycles 20, 1937 (1983).CrossRefGoogle Scholar
21.Katz, H. E., Dodabalapur, A., and Torsi, L., Chem. Mater. (in press).Google Scholar
22.Destri, S., Mascherpa, M., and Porzio, W., Adv. Mater. 5, 43 (1993).CrossRefGoogle Scholar
23.Knobloch, H., Fichou, D., Knoll, W., and Sasabe, H., Adv. Mater. 5, 570 (1993).CrossRefGoogle Scholar
24.Hamano, K., Kurata, T., Kubota, S., and Koezuka, H., Jpn. J. Appl. Phys. 33, L1031 (1994).CrossRefGoogle Scholar
25.Kagan, J. and Arora, S. K., Tetrahedron Lett. 24, 4043 (1983).CrossRefGoogle Scholar
26.Nakayama, J., Konishi, T., and Hoshino, M., Heterocycles 27, 1731 (1988).CrossRefGoogle Scholar
27.Servet, B., Ries, S., Trotel, M., Alnot, P., Horowitz, G., and Garnier, F., Adv. Mater. 5, 461 (1993).CrossRefGoogle Scholar
28.Brückner, S. and Porzio, W., Makromol. Chem. 189, 961 (1988).CrossRefGoogle Scholar
29.van Bolhuis, F., Wynberg, H., Havinga, E. E., Meijer, E. W., and Staring, E. G. J., Synth. Met. 30, 381 (1989).CrossRefGoogle Scholar
30.Hotta, S. and Waragai, K., J. Mater. Chem. 1, 835 (1991).CrossRefGoogle Scholar
31.Porzio, W., Destri, S., Mascherpa, M., Rossini, S., and Brückner, S. S., Synth. Met. 55–57, 408 (1993).CrossRefGoogle Scholar
32.Porzio, W., Destri, S., Mascherpa, M., and Brückner, S., Acta Polymer. 44, 266 (1993).CrossRefGoogle Scholar
33.Horowitz, G., Bachet, B., Yassar, A., Lang, P., Demanze, F., Fave, J-L., and Garnier, F., Chem. Mater. 7, 1337 (1995).CrossRefGoogle Scholar
34.Laudise, R. A., Bridenbaugh, P. M., Siegrist, T., Fleming, R. M., Katz, H. E., and Lovinger, A. J., J. Cryst. Growth 152, 241 (1995).CrossRefGoogle Scholar
35.Siegrist, T., Fleming, R. M., Haddon, R. C., Laudise, R. A., Lovinger, A. J., Katz, H. E., Bridenbaugh, P., and Davis, D. D., J. Mater. Res. 10, 2170 (1995).CrossRefGoogle Scholar
36.Servet, B., Horowitz, G., Ries, S., Lagorsse, O., Alnot, P., Yassar, A., Deloffre, F., Srivastava, P., Hajlaoui, R., Lang, P., and Garnier, F., Chem. Mater., 6, 1809 (1994).CrossRefGoogle Scholar
37.Lovinger, A. J., Davis, D. D., Ruel, R., Torsi, L., Dodabalapur, A., and Katz, H. E., J. Mater. Res. 10, 2958 (1995).CrossRefGoogle Scholar
38.Lovinger, A. J. (unpublished results).Google Scholar
39.Torsi, L., Dodabalapur, A., Lovinger, A. J., Katz, H. E., Ruel, R., Davis, D. D., and Baldwin, K. W., Chem. Mater. 7, 2247 (1995).CrossRefGoogle Scholar
40.Torsi, L., Dodabalapur, A., Katz, H. E., Lovinger, A. J., and Ruel, R., Proc. MRS Meeting, 377, San Francisco, April 1995.Google Scholar
41.Horowitz, G., Peng, X., Fichou, D., and Garnier, F., Appl. Phys. Lett. 67, 528 (1990).Google Scholar
42.Horowitz, G. and Delannoy, P., J. Appl. Phys. 70, 469 (1991).CrossRefGoogle Scholar
43.Torsi, L., Dodabalapur, A., and Katz, H. E., J. Appl. Phys. 78, 1088 (1995).CrossRefGoogle Scholar
44.Shur, M., Hack, M. and Shaw, J.G., J. Appl. Phys. 66, 3371 (1989).CrossRefGoogle Scholar
45.Peng, X., Horowitz, G., Fichou, D., and Garnier, F., Appl. Phys. Lett. 57, 2013 (1990).CrossRefGoogle Scholar
46.Garnier, F., Horowitz, G., Peng, X., and Fichou, D., Adv. Mater. 2, 592 (1990).CrossRefGoogle Scholar
47.Horowitz, G., Peng, X. Z., Fichou, D., and Garnier, F., Synth. Metals 51, 419 (1992).CrossRefGoogle Scholar
48.Horowitz, G., Deloffre, F., Garnier, F., Hajlaoui, R., Hmyene, M., and Yassar, A., Synth. Met. 3, 435 (1993).CrossRefGoogle Scholar
49.Dannetum, P., Lögdlund, M., Fahlman, M., Boman, M., Stafström, S., Salaneck, W. R., Lazzaroni, R., Fredrikkson, G., Bredas, J. L., Graham, S., Friend, R. H., Holmes, A. B., Zamboni, R., and Taliarri, C., Synth. Met. 55–57, 212 (1993).CrossRefGoogle Scholar
50.Garnier, F., Horowitz, G., Peng, X. Z., and Fichou, D., Synth. Met. 45, 163 (1991).CrossRefGoogle Scholar
51.Katz, H. E., Torsi, L., and Dodabalapur, A., Chem. Mater. (in press).Google Scholar
52.Lovinger, A. J. and Davis, D. D. (unpublished results).Google Scholar
53.Garnier, G., Yassar, A., Hajlaoui, R., Horowitz, G., Deloffre, F., Servet, B., Ries, S., and Alnot, P., J. Am. Chem. Soc. 115, 8716 (1993).CrossRefGoogle Scholar
54.Garnier, G., Deloffre, F., Horowitz, G., and Hajlaoui, R., Synth. Met. 55–57, 4747 (1993).CrossRefGoogle Scholar
55.Herrema, J. K., Wilderman, J., van Bolhius, F., and Hadziioannou, G., Synth. Met. 60, 239 (1993).CrossRefGoogle Scholar
56.Katz, H. E. and Dodabalapur, A. (private communication)Google Scholar
57.Hotta, S. and Waragai, K., J. Mater. Chem. 1, 835 (1991).CrossRefGoogle Scholar
58.Akimichi, H., Waragai, K., Hotta, S., Kano, H., and Sasaki, H., Appl. Phys. Lett. 58, 1500 (1991).CrossRefGoogle Scholar
59.Hotta, S. and Waragai, K., Adv. Mater. 5, 896 (1993).CrossRefGoogle Scholar
60.Kastner, J., Paloheimo, J., and Kuzmany, H., in Springer Series in Solid State Sciences, edited by Kuzmany, H., Mehring, M., and Fjink, J. (Springer, Berlin, 1993), Vol. 113, pp. 512515.Google Scholar
61.Haddon, R. C.et al., Appl. Phys. Lett. 67, 121 (1995).CrossRefGoogle Scholar
62.Dodabalapur, A., Baldwin, K., Torsi, L., Miller, T. M., and Kwok, E. (unpublished results).Google Scholar
63.Lovinger, A. J., Forrest, S. R., Kaplan, M. L., Smith, P. H., and Venkatesan, T., J. Appl. Phys. 55, 476 (1984).CrossRefGoogle Scholar
64.Dodabalapur, A., Katz, H. E., Torsi, L., and Haddon, R. C., Science 269, 1560 (1995).CrossRefGoogle Scholar
65.Pearson, C., Moore, A. J., Gibson, J. E., Bryce, M. R., and Petty, M. C., Thin Solid Films 244, 932 (1994).CrossRefGoogle Scholar
66.Tsumura, A., Koezuka, H., and Ando, T., Synth. Met. 25, 11 (1988).CrossRefGoogle Scholar
67.Koezuka, H., Tsumura, A., Fuchigami, H., and Kuramoto, K., Appl. Phys. Lett. 62, 1794 (1993).CrossRefGoogle Scholar
68.Assadi, A., Svensson, C., Willander, M., and Inganas, O., Appl. Phys. Lett. 53, 195 (1988).CrossRefGoogle Scholar
69.Ohmori, Y., Takahashi, H., Muro, K., Uchida, M., Kawai, T., and Yoshino, K., Jpn. J. Appl. Phys. 30, L610 (1991).CrossRefGoogle Scholar
70.Holland, E. R., Bloor, D., Monkman, A.P., Brown, A., DeLeeuw, D., Bouman, M. M., and Meijer, E. W., J. Appl. Phys. 75, 7954 (1994).CrossRefGoogle Scholar
71.Fuchigami, H., Tsumura, A., and Koezuka, H., Appl. Phys. Lett. 63, 1372 (1993).CrossRefGoogle Scholar
72.Murase, I., Ohnishi, T., Noguchi, T., and Hirooka, M., Polym. Comm. 28, 229 (1987).Google Scholar
73.Yang, Y., Heeger, A. J., Nature (London) 372, 344 (1994).CrossRefGoogle Scholar
74.Burroughs, J. J., Jones, C. A., and Friend, R. H., Nature (London) 335, 137 (1988).CrossRefGoogle Scholar
75.Oyama, N., Yoshimura, F., Ohsaka, T., Koezuka, H., and Ando, T., Jpn. J. Appl. Phys. 27, L448 (1988).CrossRefGoogle Scholar