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Effects of Zn content on microstructures and mechanical properties of as-cast Mg–4Y–xZn alloys

Published online by Cambridge University Press:  07 August 2017

Ruyou Fan
Affiliation:
College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, People’s Republic of China
Zili Liu*
Affiliation:
College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, People’s Republic of China
Xiqin Liu
Affiliation:
College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, People’s Republic of China
Yang Liu*
Affiliation:
College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, People’s Republic of China
Han Yin
Affiliation:
College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, People’s Republic of China
Jian Li*
Affiliation:
Jiangsu Favour Automotive New Stuff Sci-Tech Co, Ltd., Changshu 215542, People’s Republic of China
*
a) Address all correspondence to this author. e-mail: [email protected]
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Abstract

Effects of Zn content on microstructures and mechanical properties of as-cast Mg–4Y–xZn alloys (x = 1, 2, 3, 4) have been studied in the article. The results indicate that the X phase is formed firstly, and the X phase, X + W phases, and W phase precipitated in order when the Zn contents increased from 1 to 4 wt%. The secondary dendritic arm spacing of the tested alloys first decrease as the Zn content increases within the range of 1–2% and then it increases. The ultimate tensile strength (UTS) and elongation of the four experimental alloys increase until the addition of Zn reaches to 3%, with the maximum values of 213.6 MPa and 11.82%, respectively. Besides, the fracture behaviors of Mg–4Y–1Zn, Mg–4Y–2Zn, and Mg–4Y–3Zn were a quasi-cleavage fracture, while Mg–4Y–4Zn belonged to cleavage.

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Articles
Copyright
Copyright © Materials Research Society 2017 

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Footnotes

Contributing Editor: Jürgen Eckert

References

REFERENCES

Liu, Z.L., Liu, Y., Liu, X.Q., and Wang, M.M.: Effect of minor Zn additions on the mechanical and corrosion properties of solution-treated AM60–2% RE magnesium alloy. J. Mater. Eng. Perform. 25(7), 2855 (2016).CrossRefGoogle Scholar
Kim, J., Ko, W., Sandlöbes, S., Heidelmann, M., Grabowski, B., and Raabe, D.: The role of metastable LPSO building block clusters in phase transformations of an Mg–Y–Zn alloy. Acta Mater. 112, 171 (2016).CrossRefGoogle Scholar
Zhang, S., Liu, W., Gu, X., Lu, C., Yuan, G., and Ding, W.: Effect of solid solution and aging treatments on the microstructures evolution and mechanical properties of Mg–14Gd–3Y–1.8Zn–0.5Zr alloy. J. Alloys Compd. 557, 91 (2013).CrossRefGoogle Scholar
Itoi, T., Inazawa, T., Yamasaki, M., Kawamura, Y., and Hirohashi, M.: Microstructure and mechanical properties of Mg–Zn–Y alloy sheet prepared by hot-rolling. Mater. Sci. Eng., A 560, 216 (2013).CrossRefGoogle Scholar
Liu, K., Sun, C., Wang, Z., Li, S., Wang, Q., and Du, W.: Microstructure, texture and mechanical properties of Mg–Zn–Er alloys containing I-phase and W-phase simultaneously. J. Alloys Compd. 665, 76 (2016).CrossRefGoogle Scholar
Hirsch, J. and Al-Samman, T.: Superior light metals by texture engineering: Optimized aluminum and magnesium alloys for automotive applications. Acta Mater. 61(3), 818 (2013).CrossRefGoogle Scholar
Mirza, F.A. and Chen, D.L.: Fatigue of rare-earth containing magnesium alloys: A review. Fatigue Fract. Eng. Mater. Struct. 37(8), 831 (2014).CrossRefGoogle Scholar
Geng, J., Teng, X., Zhou, G., Zhao, D., and Leng, J.: Growth mechanism of an icosahedral quasicrystal and solute partitioning in a Mg-rich Mg–Zn–Y alloy. J. Mater. Res. 29(08), 942 (2014).CrossRefGoogle Scholar
Chen, T.J., Zhang, D.H., Wang, W., Ma, Y., and Hao, Y.: Effects of Zn content on microstructures and mechanical properties of Mg–Zn–RE–Sn–Zr–Ca alloys. Mater. Sci. Eng., A 607, 17 (2014).CrossRefGoogle Scholar
Zhu, Y.M., Morton, A.J., and Nie, J.F.: Growth and transformation mechanisms of 18R and 14H in Mg–Y–Zn alloys. Acta Mater. 60(19), 6562 (2012).CrossRefGoogle Scholar
Li, M., Zhang, K., Li, X.G., Yuan, J.W., Li, Y.J., Ma, M.L., Shi, G.L., Li, T., and Liu, J.B.: Effect of Zn on the microstructure and mechanical properties of as-cast Mg–7Gd–3Y–1Nd–0.5Zr alloy. Mater. Sci. Eng., A 638, 46 (2015).CrossRefGoogle Scholar
Leng, Z., Zhang, J., Zhu, T., Wu, R., Zhang, M., Liu, S., Sun, J., and Zhang, L.: Microstructure and mechanical properties of Mg–(6,9)RY–4Zn alloys by extrusion and aging. Mater. Des. 52, 713 (2013).CrossRefGoogle Scholar
Xu, C., Zheng, M.Y., Xu, S.W., Wu, K., Wang, E.D., Kamado, S., Wang, G.J., and Lv, X.Y.: Ultra high-strength Mg–Gd–Y–Zn–Zr alloy sheets processed by large-strain hot rolling and ageing. Mater. Sci. Eng., A 547, 93 (2012).CrossRefGoogle Scholar
Gröbner, J., Kozlov, A., Fang, X.Y., Geng, J., Nie, J.F., and Schmid-Fetzer, R.: Phase equilibria and transformations in ternary Mg-rich Mg–Y–Zn alloys. Acta Mater. 60(17), 5948 (2012).CrossRefGoogle Scholar
Egusa, D. and Abe, E.: The structure of long period stacking/order Mg–Zn–RE phases with extended non-stoichiometry ranges. Acta Mater. 60(1), 166 (2012).CrossRefGoogle Scholar
Tane, M., Kimizuka, H., Hagihara, K., Suzuki, S., Mayama, T., Sekino, T., and Nagai, Y.: Effects of stacking sequence and short-range ordering of solute atoms on elastic properties of Mg–Zn–Y alloys with long-period stacking ordered structures. Acta Mater. 96, 170 (2015).CrossRefGoogle Scholar
Zhu, J., Chen, J.B., Liu, T., Liu, J.X., Wang, W.Y., Liu, Z.K., and Hui, X.D.: High strength Mg94Zn2.4Y3.6 alloy with long period stacking ordered structure prepared by near-rapid solidification technology. Mater. Sci. Eng., A 679, 476 (2017).CrossRefGoogle Scholar
Wang, J., Wu, Z., Lu, R., Chen, Y., Huang, S., Qin, D., Yang, W., and Pan, F.: Mechanical properties and internal friction of Mg–Zn–Y alloys with a long-period stacking ordered structure at different Y/Zn atomic ratios. J. Mater. Res. 30(21), 3354 (2015).CrossRefGoogle Scholar
Chen, T.J., Wang, W., Zhang, D.H., Ma, Y., and Hao, Y.: Effects of heat treatment on microstructure and mechanical properties of ZW21 magnesium alloy. J. Alloys Compd. 546, 28 (2013).CrossRefGoogle Scholar
Geng, J., Teng, X., Zhou, G., and Zhao, D.: Microstructure transformations in the heat-treated Mg–Zn–Y alloy. J. Mater. Res. 577, 498 (2013).Google Scholar
Yang, K., Zhang, J., Zong, X., Wang, W., Xu, C., Cheng, W., and Nie, K.: Effect of microalloying with boron on the microstructure and mechanical properties of Mg–Zn–Y–Mn alloy. Mater. Sci. Eng., A 669, 340 (2016).CrossRefGoogle Scholar
Asgharzadeh, H., Yoon, E.Y., Chae, H.J., Kim, T.S., Lee, J.W., and Kim, H.S.: Microstructure and mechanical properties of a Mg–Zn–Y alloy produced by a powder metallurgy route. J. Alloys Compd. 586, S95 (2014).CrossRefGoogle Scholar
Wang, J., Song, P., Gao, S., Huang, X., Shi, Z., and Pan, F.: Effects of Zn on the microstructure, mechanical properties, and damping capacity of Mg–Zn–Y–Zr alloys. Mater. Sci. Eng., A 528(18), 5914 (2011).CrossRefGoogle Scholar
Zhang, Z., Liu, X., Hu, W., Li, J., Le, Q., Bao, L., Zhu, Z., and Cui, J.: Microstructures, mechanical properties and corrosion behaviors of Mg–Y–Zn–Zr alloys with specific Y/Zn mole ratios. J. Alloys Compd. 624, 116 (2015).CrossRefGoogle Scholar
Wang, J., Song, P., Gao, S., Wei, Y., and Pan, F.: Influence of Y on the phase composition and mechanical properties of as-extruded Mg–Zn–Y–Zr magnesium alloys. J. Mater. Sci. 47(4), 2005 (2012).CrossRefGoogle Scholar
Singh, A., Somekawa, H., and Mukai, T.: High temperature processing of Mg–Zn–Y alloys containing quasicrystal phase for high strength. Mater. Sci. Eng., A 528(21), 6647 (2011).CrossRefGoogle Scholar
Zhang, Z., Liu, X., Wang, Z., Le, Q., Hu, W., Bao, L., and Cui, J.: Effects of phase composition and content on the microstructures and mechanical properties of high strength Mg–Y–Zn–Zr alloys. Mater. Des. 88, 915 (2015).CrossRefGoogle Scholar
Wang, J., Gao, S., Song, P., Huang, X., Shi, Z., and Pan, F.: Effects of phase composition on the mechanical properties and damping capacities of as-extruded Mg–Zn–Y–Zr alloys. J. Alloys Compd. 509(34), 8567 (2011).CrossRefGoogle Scholar
Zhu, J., Chen, X.H., Wang, L., Wang, W.Y., Liu, Z.K., Liu, J.X., and Hui, X.D.: High strength Mg–Zn–Y alloys reinforced synergistically by Mg12ZnY phase and Mg3Zn3Y2 particle. J. Alloys Compd. 703, 508 (2017).CrossRefGoogle Scholar
Chen, T.J., Wang, W., Zhang, D.H., Ma, Y., and Hao, Y.: Development of a new magnesium alloy ZW21. Mater. Des. 44, 555 (2013).CrossRefGoogle Scholar
Zhang, L., Zhang, J., Leng, Z., Liu, S., Yang, Q., Wu, R., and Zhang, M.: Microstructure and mechanical properties of high-performance Mg–Y–Er–Zn extruded alloy. Mater. Des. 54, 256 (2014).CrossRefGoogle Scholar