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Effect of glass composition on silver-incorporation into aluminoborosilicate glasses through a staining process

Published online by Cambridge University Press:  31 January 2011

Tatsuya Suetsugu
Affiliation:
Division of Chemistry and Materials Technology, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan; and Isuzu Glass Co., Ltd., Nishinari-ku, Osaka 557-0063, Japan
Kohei Kadono*
Affiliation:
Division of Chemistry and Materials Technology, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

To fabricate graded-index optical elements by silver staining, we investigated the behavior of ion incorporation in aluminoborosilicate glasses, in which the contents of Al2O3 and Na2O were the same (in mol%). The amount of silver incorporated into the aluminoborosilicate glasses by the staining at 320 °C for 12 h was 5 to 10 times larger than that incorporated into the soda-lime silicate and borosilicate glasses. The diffusion depth of the incorporated silver ions was approximately 80 μm, which was also much deeper than that of the soda-lime silicate and borosilicate glasses. The coloration of the glasses was suppressed, particularly for the glass with the low content of Na2O. The concentration of the incorporated silver ions at the glass surface was 2 × 1021 atom/cm3 for the 37.5SiO2·25Al2O3·25Na2O·12.5B2O3 glass, corresponding to the replacement of sodium ions (20%). The refractive indices near the stained surfaces increased by 0.04 to 0.06. These values were comparable with those of the soda-lime silicate and borosilicate glasses.

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Articles
Copyright
Copyright © Materials Research Society 2010

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References

REFERENCES

1.Weyl, W.A.Coloured Glasses 2nd ed. (Dawson's of Pall Mall, London 1959)409419 433–435Google Scholar
2.Sakata, S., Ebata, Y.Staining of glass surface by heat treatment. II. On the colouration (Ruby) of borosilicate glass by means of copper staining. Osaka Kogyo-gijutsu-shikensho Kihou 6, 216 (1955)Google Scholar
3.Rawson, H.The calculation of transmission curves of glass stained by copper and silver compounds. Phys. Chem. Glasses 6, 81 (1965)Google Scholar
4.Jembrih-Simbürger, D., Neelmeijer, C., Schalm, O., Fredrickx, P., Schreiner, M., De Vis, K., Mäder, M., Schryvers, D., Caen, J.The colour of silver stained glass—Analytical investigations carried out with XRF, SEM/EDX, TEM, and IBA. J. Anal. At. Spectrom. 17, 321 (2002)CrossRefGoogle Scholar
5.Kadono, K., Suetsugu, T., Ohtani, T., Einishi, T., Tarumi, T.Optical waveguides fabricated by a classical staining process. Jpn. J. Appl. Phys. 45, 685 (2006)CrossRefGoogle Scholar
6.Bähr, J., Brenner, K-H., Sinzinger, S., Spick, T., Testorf, M.Index-distributed planar microlenses for three-dimensional micro-optics fabricated by silver-sodium ion exchange in BGG35 substrates. Appl. Opt. 33, 5919 (1994)CrossRefGoogle ScholarPubMed
7.Hakamata, K., Ishizu, J., Kunou, T., Ichikawa, T., Anma, Y.Effect of concentration-dependence on ion-exchanged channel waveguide profile. Jpn. J. Appl. Phys. 39, 1481 (2000)Google Scholar
8.Spierings, G.A.C.M.Optical absorption of Ag+ ions in 11(Na,Ag)2O·11B2O3·78SiO2 glass. J. Non-Cryst. Solids 94, (3)407 (1987)Google Scholar
9.Spierings, G.A.C.M., van Bommel, M.J.Ag+-Na+ ion exchange in boroaluminosilicate glasses. J. Non-Cryst. Solids 113, 37 (1989)CrossRefGoogle Scholar
10.Poßner, T., Schriter, G., Müller, R., Kaps, C., Kahnt, H.Special glass for integrated and microoptics. Glastech. Ber. 64, (7)185 (1991)Google Scholar
11.Kaps, C., Fliegel, W.Sodium/silver ion exchange between a non-bridging oxygen-free boroaluminosilicate glass and nitrate melts. Glastech. Ber. 64, (8)199 (1991)Google Scholar
12.Kaps, C.Thermodynamic behaviour of the non-bridging oxygen-free glass system XAg2O·(2-X)Na2O·2Al2O3·3SiO2·B2O3 in contact with nitrate melts. Glastech. Ber. 64, (9)235 (1991)Google Scholar
13.Inman, J.M., Houde-Walter, S.N., McIntyre, B.L., Lia, Z.M., Parker, R.S., Simmons, V.Chemical structure and the mixed mobile-ion effect in silver-for-sodium ion exchange in silicate glasses. J. Non-Cryst. Solids 194, 85 (1996)Google Scholar
14.Hornschuh, S., Messerschmidt, B., Possner, T., Possner, U., Rüssel, C.Silver ion exchange in glasses of the system Na2O/Al2O3/B2O3/SiO2. J. Non-Cryst. Solids 347, 121 (2004)CrossRefGoogle Scholar
15.Hornschuh, S., Messerschmidt, B., Possner, T., Possner, U., Rüssel, C.The effect of RO (R = Mg, Ca, Ba and Zn) on physical properties of Na2O/Al2O3/B2O3/SiO2 glasses for the preparation of gradient index micro lenses. J. Non-Cryst. Solids 352, 4076 (2006)CrossRefGoogle Scholar
16.Zhang, A.Y., Suetsugu, T., Kadono, K.Incorporation of silver into soda-lime silicate glass by a classical staining process. J. Non-Cryst. Solids 353, 44 (2007)Google Scholar
17.Zhang, A.Y., Suetsugu, T., Kadono, K.Incorporation of silver into borosilicate glasses by a classical staining process. J. Ceram. Soc. Jpn. 115, 47 (2007)Google Scholar
18.Suetsugu, T., Wakasugi, T., Kadono, K.Compositional dependence of silver ion incorporation into borosilicate glasses through staining process for fabrication of graded-index optical elements. Glass Tech. 50, 214 (2009)Google Scholar
19.Feldmann, T., Treinin, A.Inorganic radicals trapped in glasses at room temperature. IV. Silver radicals in metaphosphate glass. J. Chem. Phys. 47, (8)2754 (1967)CrossRefGoogle Scholar
20.Ozin, G.A., Hugues, F.Silver atoms and small silver clusters stabilized in zeolite Y: Optical spectroscopy. J. Phys. Chem. 87, 94 (1983)CrossRefGoogle Scholar
21.Brown, D., Kevan, L.Comparative electron spin resonance and optical absorption studies of silver-exchanged sodium Y zeolites: Silver centers formed on dehydration, oxidation, and subsequent γ-irradiation. J. Phys. Chem. 90, 1129 (1986)Google Scholar
22.Mulvaney, P., Henglein, A.Long-lived nonmetallic silver clusters in aqueous solution: A pulse radiolysis study of their formation. J. Phys. Chem. 94, 4182 (1990)Google Scholar
23.Paje, S.E., Llopis, J., Villegas, M.A., Fernández Navarro, J.M.Photoluminescence of a silver-doped glass. Appl. Phys. A 63, 431 (1996)Google Scholar
24.Villegas, M.A., Fernández Navarro, J.M., Paje, S.E., Llopis, J.Optical spectroscopy of a soda lime glass exchanged with silver. Phys. Chem. Glasses 37, 248 (1996)Google Scholar
25.Borsella, E., Gonella, F., Mazzoldi, P., Quaranta, A., Battaglin, G., Polloni, R.Spectroscopic investigation of silver in soda-lime glass. Chem. Phys. Lett. 284, 429 (1998)Google Scholar
26.Borsella, E., Battaglin, G., García, M.A., Gonella, F., Mazzoldi, P., Polloni, R., Quaranta, A.Structural incorporation of silver in soda-lime glass by the ion-exchange process: A photoluminescence spectroscopy study. Appl. Phys. A 71, 125 (2000)CrossRefGoogle Scholar
27.Paje, S.E., García, M.A., Villegas, M.A., Llopis, J.Optical properties of silver ion-exchanged antimony doped glass. J. Non-Cryst. Solids 278, 128 (2000)Google Scholar
28.Kreibig, U., Fragstein, C. v.The limitation of electron mean free path in small silver particles. Z. Phys. 224, 307 (1969)Google Scholar
29.Espiau de Lamaestre, R., Béa, H., Bernas, H., Belloni, J., Marignier, J.L.Irradiation-induced Ag nanocluster nucleation in silicate glasses: Analogy with photography. Phys. Rev. B 76, 205431 (2007)Google Scholar
30.Houde-Walter, S.N., Inman, J.M., Dent, A.J., Greaves, G.N.Sodium and silver environments and ion-exchange processes in silicate and aluminosilicate glasses. J. Phys. Chem. 97, 9330 (1993)CrossRefGoogle Scholar
31.Yano, T., Nagano, T., Lee, J., Shibata, S., Yamane, M.Cation site occupation by Ag+/Na+ ion-exchange in R2O–Al2O3–SiO2 glasses. J. Non-Cryst. Solids 270, 163 (2000)CrossRefGoogle Scholar
32.Wakabayashi, H.The relationship between composition and electrical conductivity in glasses containing network forming trivalent cations. Phys. Chem. Glasses 30, (2)51 (1989)Google Scholar
33.Poling, S.A., Houde-Walter, S.N.Structural factors in silver-induced relaxation in aluminosilicate glasses. J. Non-Cryst. Solids 293–295, 430 (2001)Google Scholar