Hostname: page-component-848d4c4894-tn8tq Total loading time: 0 Render date: 2024-07-03T05:09:50.907Z Has data issue: false hasContentIssue false
  • English
  • Français

Effect of furfuryl alcohol on the properties of hydrated cement mortar

Published online by Cambridge University Press:  31 January 2011

V. K. Singh ,
R. K. Singh  and
S. D. Khatri
V. K. Singh
Affiliation:
Department of Ceramic Engineering, Institute of Technology, Banaras Hindu University, Varanasi 221 005, India
R. K. Singh
Affiliation:
Department of Ceramic Engineering, Institute of Technology, Banaras Hindu University, Varanasi 221 005, India
S. D. Khatri
Affiliation:
Department of Chemistry, Faculty of Science, Banaras Hindu University, Varanasi 221 005, India
Get access

Abstract

The effect of furfuryl alcohol addition to ordinary cement on its properties, such as heat of hydration, setting time, compressive strength, and tensile strength was studied by adding 0.5–3.0% by weight of cement. Hardness was tested using the Vickers indentation method. Fracture toughness of cementitious bond and bending strength were determined using the three-point bending system. Corrosion resistance of resulting products was tested against 0.1 and 1.0 N HCI and H2SO4 and seawater, respectively. Water absorption/open porosity and microstructure were also determined. It was observed that strength, hardness, toughness, and corrosion resistance increase up to 3.0% addition of furfuryl alcohol in ordinary Portland cement. Polymeric phase was interspersed in cement, causing a decrease in water absorption/open porosity, and its interaction with hydrating cement caused additional bond formation, leading to the increase in strength.

Type
Articles
Information
Journal of Materials Research , Volume 18 , Issue 5 , May 2003 , pp. 1131 - 1140
Copyright
Copyright © Materials Research Society 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Rodger, S.A., Brooks, S.A., Sinclair, W., Grooves, G.W., and Double, D.D., J. Mater. Sci. 20, 2853 (1985).CrossRefGoogle Scholar
2.Chandra, S. and Flodin, P., Cem. Concr. Res. 17, 875 (1987).CrossRefGoogle Scholar
3.Popova, A., Geoffroy, G., Renou-Gonnord, M.F., Faucon, P., Gartner, E., J. Am. Ceram. Soc. 83, 2556 (2000).CrossRefGoogle Scholar
4.Pushpalal, G.K.D., J. Mater. Sci. 35, 981 (2000).CrossRefGoogle Scholar
5.Hu, S., 9th International Congress on Chemistry of Cement (National Council for Cement and Building Materials, New Delhi, 1992), Vol. III, p. 393.Google Scholar
6.Harsh, S., Naidu, Y.C., and Ghosh, S.N., 9th International Congress on Chemistry of Cement (National Council for Cement and Building Materials, New Delhi, 1992), Vol. III, p. 406.Google Scholar
7.Ohama, Y., Demura, K., and Miyake, M., in Semento Gijutsu Nempo 40 (The Cement Association of Japan, Tokyo, Japan, 1986), p. 87.Google Scholar
8.Chandra, S. and Ohama, Y., Polymers in Concrete—An Introduction (CRC Press, FL, 1994).Google Scholar
9.Peppler, R.B. and Rosskopf, P.A.: Fr.2, 152, 234 (cf. C 04b) 25 May 1973, US Appl. 179, 239, 9 Sep 1971, 17, Chem. Abstr., 79, 96275 (1973), p. 276.Google Scholar
10.Mamulov, F.G. and Tikhomirov, A.A., IZV. Vyssh. Uchebn. Zaved. Neft Gaz, edited by Rowlett, R.J., Jr. (1919), 23-28 (1976), Chem. Abstr., 86, 175928 (The American Chemical Society, Columbus, OH, 1977).Google Scholar
11.Grach’yan, A.N., Dovyborova, L.N., and Tavlinova, T.I., IZV. Vyssh. Uchebn. Zaved, Khim. Khim. Tekhnol., edited by Rowlett, R.J., Jr. 19(9) 1465-6 (1976), Chem Abst., 86, 46704 (The American Chemical Society, Columbus, OH, 1977).Google Scholar
12.Singh, N.K., Mishra, P.C., Singh, V.K., and Narang, K.K., Indian Journal of Chemical Technology (2002), Vol. 9, p. 112–117.Google Scholar
13.Singh, V.K., Khattri, S.D., and Singh, R.K., 11th ICCC, May 11–16, 2003.CrossRefGoogle Scholar
14.Singh, N.K., Mishra, P.C., Singh, V.K., and Narang, K.K., Cement Concrete Res. (in press).Google Scholar
15.Singh, V.K., Khattri, S.D., and Singh, R.K., Trans. Indian Ceram. Soc. 61, 152 (2002).CrossRefGoogle Scholar
16.Birchall, J.D., Phil. Trans. R. Soc. A 310, 31 (1983).Google Scholar
17.Sinclair, W. and Groves, G.W., J. Mater. Sci. 20, 2846 (1985).CrossRefGoogle Scholar
18.Rodger, A., Brooks, S.A., Sinclair, W., Groves, G.W., and Double, D.D., J. Mater. Sci. 20, 2853 (1985).CrossRefGoogle Scholar
19.IS:4032, Indian Standard Methods of Physical Tests for Hydraulic Cement (Indian Standards Institution, New Delhi, India, 1968).Google Scholar
20.Powder Diffraction File, Cards Nos. 10–373, 3-649, 4-733, 1-0038, 3-594, 3-1121, 10-374, 6-10 (1967); 24-217, 16-333, 29285, 19-286, 19-287 (1986) (Joint Committee on Powder Diffraction Standards, Swarthmore, PA, 1967 and 1986).Google Scholar
21.Brezny, R. and Green, D.J., J. Am. Ceram. Soc. 72, 1145 (1989).CrossRefGoogle Scholar
22.Brezny, R. and Green, D.J., Acta Metall. 38, 2517 (1990).CrossRefGoogle Scholar
23.Lea, F.M., The Chemistry of Cement and Concrete, 3rd ed. (Edward Arnold, London, U.K., 1970), p. 2195.Google Scholar
24.Singh, V.K., Singh, R.K., and Khattri, S.D., Trans. Indian Ceram. Soc. 57, 113 (1998).CrossRefGoogle Scholar
25.Bensted, J., Seventh International Congress of the Chemistry of Cement, Paris, France (1980) 377.Google Scholar
26.Bensted, J. and Varma, S.P., Cem. Tech. 5, 1256 (1974).Google Scholar
27.Puri, B.R. and Sharma, L.R., Principles of Physical Chemistry, 9th ed. (S. Nagain & Co., Jallaunder city-1, Punjab, India, 1974), p. 436.Google Scholar
28.Puri, B.R. and Sharma, L.R., Principles of Physical Chemistry, 21 ed. (S. Nagain & Co., Jallaunder city-1, Punjab, India, 1974), p. 463.Google Scholar
29.Singh, D.B., Brasad, G., Rupainwar, D.C., and Singh, V.N., Water, Air, and Soil Pollution 42, 373 (1988).Google Scholar
30.Bogue, R.H., The Chemistry of Portland Cement (Reinhold, New York, 1955), p. 467.Google Scholar
31.IS:269, Ordinary, Rapid Hardening and Low Heat Portland Cement (Indian Standards Institution, New Delhi, 1958).Google Scholar
32.Swamy, R. Narayan, J. Mater. Sci. 14, 1521 (1979).CrossRefGoogle Scholar
33.Birchall, J.D., Howard, A.J., and Kendall, K., Nature 289, 388 (1981).CrossRefGoogle Scholar
34.Birchall, J.D., Howard, A.J., Kendall, K., and Raistric, J.H., European Pat. Specification No. 0055035; B1 (1988).Google Scholar
35.Ben-Dor, L., Heitner-Wirguin, C., and Diab, H., Cem. Concr. Res. 15, 681 (1985).CrossRefGoogle Scholar