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Effect of FeCl4– intercalation on the transport properties of a graphitized polyimide film

Published online by Cambridge University Press:  03 March 2011

B. Nysten ,
J-P. Issi ,
H. Shioyama ,
M. Crespin ,
R. Setton ,
F. Béguin  and
M. Inagaki
B. Nysten
Affiliation:
Unité de Physico-Chimie et de Physique des Matériaux, Université Catholique de Louvain, place Croix du Sud, 1, B-1348 Louvain-la-Neuve, Belgique
J-P. Issi*
Affiliation:
Unité de Physico-Chimie et de Physique des Matériaux, Université Catholique de Louvain, place Croix du Sud, 1, B-1348 Louvain-la-Neuve, Belgique
H. Shioyama
Affiliation:
Centre de Recherche sur la Matière Divisée, CNRS-Université d'Orléans, 1B, rue de la Férollerie, F-45071 Orléans Cedex 2, France
M. Crespin
Affiliation:
Centre de Recherche sur la Matière Divisée, CNRS-Université d'Orléans, 1B, rue de la Férollerie, F-45071 Orléans Cedex 2, France
R. Setton
Affiliation:
Centre de Recherche sur la Matière Divisée, CNRS-Université d'Orléans, 1B, rue de la Férollerie, F-45071 Orléans Cedex 2, France
F. Béguin
Affiliation:
Centre de Recherche sur la Matière Divisée, CNRS-Université d'Orléans, 1B, rue de la Férollerie, F-45071 Orléans Cedex 2, France
M. Inagaki
Affiliation:
Faculty of Engineering, Hokkaido University, Kita-ku, Sapporo, 060 Japan
*
a)Author to whom correspondence should be addressed.
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Abstract

The temperature variation of the thermal conductivity, the electrical resistivity, and the thermoelectric power of a graphitized polyimide film have been measured in the temperature range 2 < T < 300 K. The effect of the electrochemical intercalation with FeCl4− ions has also been studied. The thermal conductivity measurements confirm the high degree of graphitization that may be obtained with polyimide films. They show how intercalation increases the structural disorder and how the intercalate substantially contributes to the thermal conductivity at low temperatures. The electrical-resistivity and thermoelectric-power measurements reveal that the density of free carriers is about three times lower in stage-2 FeCl4− solvated intercalation compounds obtained by an electrochemical way than in stage-2 FeCl3 compounds obtained by a classical synthesis method.

Type
Articles
Information
Journal of Materials Research , Volume 8 , Issue 9 , September 1993 , pp. 2299 - 2304
Copyright
Copyright © Materials Research Society 1993

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References

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