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Effect of additional elements in the glass precursor on the growth of the Bi2Sr2Ca2Cu2Ox whiskers

Published online by Cambridge University Press:  03 March 2011

L. Dimesso ,
I. Matsubara ,
T. Ogura ,
R. Funahashi ,
H. Yamashita  and
A. Tampieri
L. Dimesso
Affiliation:
Osaka National Research Institute, Midorigaoka, Ikeda, Osaka 563, Japan
I. Matsubara
Affiliation:
Osaka National Research Institute, Midorigaoka, Ikeda, Osaka 563, Japan
T. Ogura
Affiliation:
Osaka National Research Institute, Midorigaoka, Ikeda, Osaka 563, Japan
R. Funahashi
Affiliation:
Osaka National Research Institute, Midorigaoka, Ikeda, Osaka 563, Japan
H. Yamashita
Affiliation:
Osaka National Research Institute, Midorigaoka, Ikeda, Osaka 563, Japan
A. Tampieri
Affiliation:
CNR/Research Institute Ceramics Technology, via Granarolo 64, 48018 Faenza (RA), Italy
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Abstract

The effect of the doping on the growth and superconducting properties of whiskers in the Bi–Sr–Ca–Cu–X–O system (where X = Na, B, Ga, and Pb, respectively), prepared by heating a glassy melt-quenched plate in flowing oxygen, is reported. The thermal behavior of the glassy samples (studied by DTA, XRD, and SEM techniques) was found to be dependent on the dopant as well as on its concentration. The Bi2Sr2CaCu2Ox (2212 phase) whiskers were grown only from the Ga-doped system annealed at 855 °C. The dependence of the mechanism of the whiskers' growth on the dopant is also discussed.

Type
Articles
Information
Journal of Materials Research , Volume 9 , Issue 10 , October 1994 , pp. 2501 - 2509
Copyright
Copyright © Materials Research Society 1994

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References

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