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Detailed investigation of contact deformation in ZrN/Zr multiplayer—understanding the role of volume fraction, bilayer spacing, and morphology of interfaces

Published online by Cambridge University Press:  19 November 2013

Nisha Verma*
Affiliation:
Department of Materials Engineering, University of California Santa Barbara
Vikram Jayaram
Affiliation:
Department of Materials Engineering, Indian Institute of Science, Bangalore-560012, India
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

A systematic study was done to understand the influence of volume fractions and bilayer spacings for metal/nitride multilayer coating using finite element method (FEM). An axisymmetric model was chosen to model the real situation by incorporating metal and substrate plasticity. Combinations of volume fractions and bilayer spacings were chosen for FEM analysis consistent with experimental results. The model was able to predict trends in cracking with respect to layer spacing and volume fraction. Metal layer plasticity is seen to greatly influence the stress field inside nitride. It is seen that the thicker metal induces higher tensile stresses inside nitride and hence leads to lower cracking loads. Thin metal layers <10 nm were seen to have curved interfaces, and hence, the deformation mode was interfacial delamination in combination with edge cracking. There is an optimum seen with respect to volume fraction ∼13% and metal layer thickness ∼30 nm, which give maximum crack resistance.

Type
Articles
Copyright
Copyright © Materials Research Society 2013 

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References

REFERENCES

Huang, J.H., Ma, C.H., and Chen, H.: Effect of Ti interlayer on the residual stress and texture development of TiN thin films. Surf. Coat. Technol. 200, 5937 (2006).CrossRefGoogle Scholar
He, M. and Evans, A.: Crack deflection at an interface between dissimilar elastic materials: Role of residual stresses. Int. J. Solids. Struct. 31, 3443 (1994).CrossRefGoogle Scholar
Holleck, H. and Schulz, H.: Advanced layered material constitution. Thin Solid Films 153, 11 (1987).CrossRefGoogle Scholar
Holleck, H. and Schulz, H.: Preparation and behaviour of wear-resistant TiC/TiB2, TiN/TiB2 and TiC/TiN coatings with high amounts of phase boundaries. Surf. Coat. Technol. 36, 707 (1988).CrossRefGoogle Scholar
Gachon, Y., Ienny, P., Forner, A., Farger, G., Catherine, M.C.S., and Vannes, A.B.: Erosion by solid particles of W/W-N multilayer coatings obtained by PVD process. Surf. Coat. Technol. 113, 140 (1999).CrossRefGoogle Scholar
Quesnel, E., Pauleau, Y., Monge Cadet, P., and Brun, M.: Tungsten and tungsten-carbon PVD multilayered structures as erosion-resistant coatings. Surf. Coat. Technol. 62, 479 (1993).CrossRefGoogle Scholar
Chen, B., Pan, W., Hwang, J., Yu, G., and Huang, J.: On the corrosion behavior of TiN coated AISI D2 steel. Surf. Coat. Technol. 111, 16 (1999).CrossRefGoogle Scholar
Hubler, R., Schroer, A., Ensinger, W., Wolf, G., Stedile, F.C., Schreiner, W.H., and Baumvol, I.J.R.: Corrosion behavior of steel coated with thin film of TiN/Ti composites. J. Vac. Sci. Technol., A 11, 451 (1993).CrossRefGoogle Scholar
Cheng, Y., Browne, T., Heckerman, B., Bowman, C., and Gorokhovsky, E.V.: Mechanical and tribological properties of TiN/Ti multilayer coating. Surf. Coat. Technol. 205, 146 (2010).CrossRefGoogle Scholar
Xia, F.F., Wu, M.H., Wang, F., Jia, Z.Y., and Wang, A.L.: Nanocomposite Ni–TiN coatings prepared by ultrasonic electrodeposition. Curr. Appl. Phys. 9, 44 (2009).CrossRefGoogle Scholar
Xie, Z. H., Hoffman, M., Munroe, P., Bendavid, A., and Martin, P.: Deformation mechanisms of (TiN) multilayer coatings alternated by ductile or stiff interlayer’s. Acta Mater. 56, 852 (2008).CrossRefGoogle Scholar
Xie, Z.H., Hoffman, M., Munroe, P., Singh, R., Bendavid, A., and Martin, P.J.: Microstructural response of TiN monolithic and multilayer coatings during microscratch testing. J. Mater. Res. 22(8), 2312 (2007).CrossRefGoogle Scholar
Ma, K., Bloyce, A., and Bell, T.: Examination of mechanical properties and failure mechanisms of TiN and Ti-TiN multilayer coatings. Surf. Coat. Technol. 7677, 297 (1995).CrossRefGoogle Scholar
Chawla, N., Singh, D.R.P., Shen, Y., Tang, G., and Chawla, K.K.: Indentation mechanics and fracture behavior of metal/ceramic nanolaminate composites. J. Mater. Sci. 48, 4383 (2008).CrossRefGoogle Scholar
Bhattacharyya, D., Mara, N.A., Dickerson, P., Hoagland, R.G., and Misra, A.: A transmission electron microscopy study of the deformation behavior underneath nanoindents in nanoscale Al-TiN multilayered composites. Philos. Mag. 90, 1711 (2010).CrossRefGoogle Scholar
Dayal, P., Quadir, M.Z., Kong, C., Savvides, N., and Hoffman, M.: Transition from dislocation controlled plasticity to grain boundary mediated shear in nanolayered aluminum/palladium thin films. Thin Solid Films 519, 3213 (2011).CrossRefGoogle Scholar
Souza, R.M., Sinatora, A., Mustoe, G.G.W., and Moore, J.J.: Numerical and experimental study of the circular cracks observed at the contact edges of the indentations of coated systems with soft substrates. Wear 251, 1337 (2001).CrossRefGoogle Scholar
Ward, D.J. and Arnell, R.D.: Finite element modelling of stress development during deposition of ion assisted coatings. Thin Solid Films 420421, 269 (2002).CrossRefGoogle Scholar
Djabella, H. and Arnell, R.D.: Finite element analysis of the contact stresses in elastic coating/substrate under normal and tangential load. Thin Solid Films 223, 87 (1993).CrossRefGoogle Scholar
Gorishnyy, T., Olson, L.G., Oden, M., Aouadi, S.M., and Rohde, S.: Optimization of wear-resistant coating architectures using finite element analysis. J. Vac. Sci. Technol., A 21, 332 (2003).CrossRefGoogle Scholar
Tang, G., Shen, Y.L., Singh, D.R.P., and Chawla, N.: Analysis of indentation- derived effective elastic modulus of metal-ceramic multilayer’s. Int. J. Mech. Mater. Des. 4, 391 (2008).CrossRefGoogle Scholar
Zhao, X., Xie, Z., and Munroe, P.: Nanoindentation of hard multilayer coatings: Finite element modeling. Mater. Sci. Eng., A 528, 1111 (2011).CrossRefGoogle Scholar
Sakharova, A., Fernandes, J.V., Oliveira, M.C., and Antunes, J.M.: Influence of ductile interlayers on mechanical behaviour of hard coatings under depth-sensing indentation: A numerical study on TiAlN. J. Mater. Sci. 45, 3812 (2010).CrossRefGoogle Scholar
Tang, G., Singh, D.R.P., Shen, Y.L., and Chawla, N.: Elastic properties of metal/ceramic nanolaminates measured by nanoindentation. Mater. Sci. Eng., A 502, 79 (2009).CrossRefGoogle Scholar
Math, S., Jayaram, V., and Biswas, S.K.: Deformation and failure of a film/substrate system subjected to spherical indentation: Part I. Experimental validation of stresses and strains derived using Hankel transform technique in an elastic film/substrate system. J. Mater. Res. 21, 774 (2006).CrossRefGoogle Scholar
Verma, N. and Jayaram, V.: The influence of Zr layer thickness on contact deformation and fracture in a ZrN-Zr multilayer coating. J. Mater. Sci. 47, 1621 (2012).CrossRefGoogle Scholar
Tilbrook, M.T., Paton, D.J., Xie, Z., and Hoffman, M.: Microstructural effects on indentation failure mechanisms in TiN coatings: Finite element simulations. Acta Mater. 55, 2489 (2007).CrossRefGoogle Scholar
Wang, B.T., Zhang, P., Liu, H.Y., Li, W.D., and Zhang, P.: First-principals calculations of phase transition, elastic modulus, and superconductivity under pressure for zirconium. J. Appl. Phys. 109, 063514 (2011).CrossRefGoogle Scholar
Auger, M.A., Araiza, J.J., Falcony, C., Sanchez, O., and Albella, J.M.: Hardness and tribology measurements on ZrN coatings deposited by reactive sputtering technique. Vacuum 81, 1462 (2007).CrossRefGoogle Scholar
Singh, A., Kuppusami, P., Thirumurugesan, R., Ramaseshan, R., Kamruddin, M., Dash, S., Ganesan, V., and Mohandas, E.: Study of microstructure and nanomechanical properties of Zr films prepared by pulsed magnetron sputtering. Appl. Surf. Sci. 257, 9909 (2011).CrossRefGoogle Scholar
Meyers, M., Mishra, A., and Benson, D.: Mechanical properties of nanocrystalline materials. Prog. Mater. Sci. 51, 427 (2006).CrossRefGoogle Scholar
Giannuzzi, L. and Stevie, F.: A review of focused ion beam milling techniques for TEM specimen preparation. Micron 30, 197 (1999).CrossRefGoogle Scholar
Stevie, F.: Applications of focused ion beams in microelectronics production, de- sign and development. Surf. Interface Anal. 23, 61 (1995).CrossRefGoogle Scholar
Suresh, S.J., Math, S., Jayaram, V., and Biswas, S.K.: Toughening through multilayering in TiN-AlTiN films. Philos. Mag. 87, 2521 (2007).CrossRefGoogle Scholar
Bhowmick, S., Kale, A.N., Jayaram, V., and Biswas, S.K.: Contact damage in TiN coatings on steel. Thin Solid Films 436, 250 (2003).CrossRefGoogle Scholar
Hoek, E. and Bienawsky, Z.T.: Brittle fracture propagation in rocks under compression. Int. J. Fracture Mech. 1, 137 (1965).CrossRefGoogle Scholar