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Deformation of a hard coating on ductile substrate system during nanoindentation: Role of the coating microstructure

Published online by Cambridge University Press:  01 February 2006

Z-H. Xie ,
M. Hoffman ,
R.J. Moon  and
P.R. Munroe
Z-H. Xie*
Affiliation:
School of Materials Science and Engineering, University of New South Wales,Sydney, NSW 2052, Australia
M. Hoffman
Affiliation:
School of Materials Science and Engineering, University of New South Wales,Sydney, NSW 2052, Australia
R.J. Moon
Affiliation:
School of Materials Science and Engineering, University of New South Wales,Sydney, NSW 2052, Australia
P.R. Munroe
Affiliation:
School of Materials Science and Engineering, University of New South Wales,Sydney, NSW 2052, Australia
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

Deformation and fracture of a columnar-grained, ∼1.3-μm-thick TiN coating on a stainless steel substrate was investigated using a spherical tipped conical indenter of 5-μm nominal tip radius. Structural analysis, performed with the support of focused ion beam (FIB) milling and imaging techniques, revealed that the microstructure of the TiN coating had a strong influence on the deformation behavior of the coating. Intergranular sliding in the coating, as well as plastic flow in the ductile substrate, was found to be the predominant processes during the indentation. Neither plastic deformation, in the form of plastic flow, within the coating nor delamination of the interface was observed. Coating deformation was observed to be controlled by the intergranular shear cracking and thus by the interfacial columbic frictional stress between columnar grains. An indentation-energy based model was developed, which deconvolutes the coating behavior from that of the substrate, allowing quantification of the intergranular sliding stress.

Keywords

FilmMicrostructureNanostructure
Type
Articles
Information
Journal of Materials Research , Volume 21 , Issue 2 , February 2006 , pp. 437 - 447
Copyright
Copyright © Materials Research Society 2006

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References

REFERENCES

1.Fischer-Cripps, A.C.: Nanoindentation (Springer-Verlag, New York, 2002).CrossRefGoogle Scholar
2.Weppelmann, E. and Swain, M.V.: Investigation of the stresses and stress intensity factors responsible for fracture of thin protective films during ultra-micro indentation tests with spherical indenters. Thin Solid Films 286, 111 (1996).CrossRefGoogle Scholar
3.Andersson, R., Toth, G., Gan, L. and Swain, M.V.: Indentation response and cracking of sub-micro silica films on a polymeric substrate. Eng. Fract. Mech. 61, 93 (1998).CrossRefGoogle Scholar
4.Hainsworth, S.V., McGurk, M.R. and Page, T.F.: The effect of coating cracking on the indentation response of thin hard-coated systems. Surf. Coat. Technol. 102, 97 (1998).CrossRefGoogle Scholar
5.Swain, M.V. and Menčík, J.: Mechanical property characterization of thin films using spherical tipped indenters. Thin Solid Films 253, 204 (1994).CrossRefGoogle Scholar
6.Pang, M., Wilson, D.E. and Bahr, D.F. The strength and fracture of passive oxide films on metals, in Thin Films—Stresses and Mechanical Properties VIII, edited by Vinci, R., Kraft, O., Moody, N., Besser, P., and Shaffer, E. II (Mater. Res. Soc. Symp. Proc. 594, Warrendale, PA, 2000), pp. 501–506.Google Scholar
7.Bahr, D.F., Pang, M. and Rodriguez-Marek, D. Film fracture phenomena during indentation, in Fundamentals of Nanoindentation and Nanotribology II, edited by Baker, S.P., Cook, R.F., Corcoran, S.G., and Moody, N.R. (Mater. Res. Soc. Symp. Proc. 649, Warrendale, PA, 2001), pp. Q4.2.1–Q4.2.6.Google Scholar
8.Ma, L.W., Cairney, J.M., Hoffman, M. and Munroe, P.R.: Deformation mechanisms operating during nanoindentation of TiN coatings on steel substrates. Surf. Coat. Technol. 192, 11 (2005).CrossRefGoogle Scholar
9.Michler, J. and Blank, E.: Analysis of coating fracture and substrate plasticity induced by spherical indentors: Diamond and diamond-like carbon layers on steel substrates. Thin Solid Films 381, 119 (2001).CrossRefGoogle Scholar
10.Abdul-Baqi, A.J.J. Failure of brittle coatings on ductile metallic substrates. PhD. Thesis, Delft University of Technology, Delft, The Netherlands (Shaker Publishing, Maastricht, The Netherlands, 2002).Google Scholar
11.Tsui, T.Y., Vlassak, J. and Nix, W.D.: Indentation plastic displacement field: Part II. The case of hard films on soft substrates. J. Mater. Res. 14, 2204 (1999).CrossRefGoogle Scholar
12.Hainsworth, S.V. and Page, T.F. Mechanical property data for coated systems—the prospects for measuring “coating only” properties using nanoindentation, in Thin Films: Stresses and Mechanical Properties VI, edited by Gerberich, W.W., Gao, H., Sundgren, J-E., and Baker, S.P. (Mater. Res. Soc. Symp. Proc. 436 Pittsburgh, PA, 1997), pp. 171–176.Google Scholar
13.Mann, A.B. and Pethica, J.B. Dislocation nucleation and multiplication during nanoindentation testing, in Thin Films: Stresses and Mechanical Properties VI, edited by Gerberich, W.W., Gao, H., Sundgren, J-E., and Baker, S.P. (Mater. Res. Soc. Symp. Proc. 436 Pittsburgh, PA, 1997), pp. 153–158.Google Scholar
14.Sriram, K., Narasimhan, R. and Biswas, S.K.: A numerical fracture analysis of indentation into thin hard films on soft substrates. Eng. Fract. Mech. 70, 1323 (2003).CrossRefGoogle Scholar
15.Hainsworth, S.V. and Soh, W.C.: The effect of the substrate on the mechanical properties of TiN coatings. Surf. Coat. Technol. 163–164, 515 (2003).CrossRefGoogle Scholar
16.Loubet, J.L., Georges, J.M. and Kapsa, Ph. Measurement of thin films adhesion and mechanical properties with indentation curves, in Mechanics of Coatings, edited by Dowson, D., Taylor, C.M., and Godet, M. (Elsevier, Amsterdam, The Netherlands, 1990), pp. 429–434.Google Scholar
17.Knight, J.C. and Page, T.F.: Scratch induced subsurface deformation behaviour of thin ceramic coatings. Surf. Eng. 6, 263 (1990).CrossRefGoogle Scholar
18.Twigg, P.C, McGurk, M.R., Hainsworth, S.V. and Page, T.F. Apparent indentation plasticity in ceramic coated systems, in Plastic Deformation of Ceramics, edited by Bradt, R.C., Brookes, C.A., and Routbort, J.L. (Plenum Press, New York, 1995), pp. 219–229.CrossRefGoogle Scholar
19.Carvalho, N.J.M. and De Hosson, J.Th.M. Nano indentation studies of WC/C and TiN/(Ti,Al)N multilayer PVD coatings combined with cross-sectional electron microscopy observations, in Surface Engineering 2001—Fundamentals and Applications, edited by Meng, W.J., Kumar, A., Doll, G.L., Cheng, Y-T., Veprek, S., and Chung, Y-W., (Mater. Res. Soc. Symp. Proc. 697 Warrendale, PA, 2002), pp. P.1.5.1–P.1.5.6.Google Scholar
20.Xie, Z-H., Hoffman, M., Moon, R., Munroe, P. and Cheng, Y-B.: Scratch damage in ceramics: Role of microstructure. J. Am. Ceram. Soc. 86, 141 (2003).CrossRefGoogle Scholar
21.Steer, T.J., Möbus, G., Kraft, O., Wagner, T. and Inkson, B.J. 3D FIB and AFM mapping of nanoindentation zones, in Fundamentals of Nanoindentation and Nanotribology II, edited by Baker, S.P., Cook, R.F., Corcoran, S.G., and Moody, N.R. (Mater. Res. Soc. Symp. Proc. 649 Warrendale, PA, 2001), pp. Q3.7.1–Q3.7.6.Google Scholar
22.Saka, H. and Abe, S.: FIB/HVEM observation of the configuration of cracks and the defect structure near the cracks in Si. J. Electron Microsc. 46, 45 (1997).CrossRefGoogle Scholar
23.Ando, M., Katoh, Y., Tanigawa, H. and Kohyama, A.: Microstructural examination of Ni-ion irradiated Fe–Ni–Cr alloys followed to micro-zone deformation. J. Nucl. Mater. 271 & 272, 111 (1999).CrossRefGoogle Scholar
24.Bradby, J.E., Williams, J.S., Wong-Leung, J., Swain, M.V. and Munroe, P.: Mechanical deformation in silicon by micro-indentation. J. Mater. Res. 16, 1500 (2001).CrossRefGoogle Scholar
25.Bhowmick, S., Xie, Z-H., Hoffman, M., Jayaram, V. and Biswas, S.K.: The nature of contact deformation of TiN films on steel. J. Mater. Res. 19, 2616 (2004).CrossRefGoogle Scholar
26.Swain, M.V.: Mechanical property characterization of small volumes of brittle materials with spherical tipped indenters. Mater. Sci. Eng. A 253, 160 (1998).CrossRefGoogle Scholar
27.Xie, Z-H., Munroe, P., Moon, R.J. and Hoffman, M.: Characterization of surface contact-induced fracture in ceramics using a focused ion beam miller. Wear 255, 651 (2003).CrossRefGoogle Scholar
28.Xie, Z-H., Munroe, P., Hoffman, M., Moon, R.J. and Cheng, Y-B.: Application of focused ion beam miller in microstructure and fracture characterization. Key Eng. Mater. 247–247, 279 (2003).Google Scholar
29.Trtik, P., Reeves, C.M. and Bartos, P.J.M.: Use of focused ion beam (FIB) for advanced interpretation of microindentation test results applied to cementitious composites. Mater. Struct. 33, 189 (2000).CrossRefGoogle Scholar
30.Wang, Y-Z., Revie, R.W., Phaneuf, M.W. and Li, J.: Application of focused ion beam (FIB) microscopy to the study of crack profiles. Fatigue Fract. Eng. Mater. Struct. 22, 251 (1999).CrossRefGoogle Scholar
31.Giannuzzi, L.A. and Stevie, F.A.: A review of focused ion beam milling techniques for TEM specimen preparation. Micron. 30, 197 (1999).CrossRefGoogle Scholar
32.Cairney, J., Munroe, P.R. and Hoffman, M.: The application of focused ion beam technology to the characterisation of coatings. Surface Coat. Technol. 198((1–3)), 165 (2005).CrossRefGoogle Scholar
33.Johnson, K.L.: Contact Mechanics (Cambridge University Press, Cambridge, U.K., 1985).CrossRefGoogle Scholar
34.Hurley, D.C., Tewary, V.K. and Richards, A.J.: Thin-film elastic-property measurements with laser-ultrasonic SAW spectrometry. Thin Solid Films 398–399, 326 (2001).CrossRefGoogle Scholar
35.Menčík, J., Munz, D., Quandt, E., Weppelmann, E.R. and Swain, M.V.: Determination of elastic modulus of thin layers using nanoindentation. J. Mater. Res. 12, 2475 (1997).CrossRefGoogle Scholar
36.Lawn, B.: Fracture of Brittle Solids, 2nd ed. (Cambridge University Press, Cambridge, U.K., 1993), p. 253.CrossRefGoogle Scholar
37.Polakowski, N.H. and Ripling, E.J.: Strength and Structure of Engineering Materials (Prentice-Hall, Englewood Cliffs, NJ, 1966).Google Scholar
38.Bhowmick, S., Bhide, R., Hoffman, M., Jayaram, V. and Biswas, S.K.: Fracture mode transitions during indentation of columnar TiN coatings on metal. Philos. Mag. 85, 2927 (2005).CrossRefGoogle Scholar